Phenomenology related to the kinetics of Kolbe electrosynthesis
The Kolbe electrosynthesis on polycrystalline platinum in 1 M acetic acid/1 M potassium acetate electrolyte at 30 ° C was studied by using potentiostatic, low-frequency potentiodynamic and impedance techniques. Reaction products and their distribution as a function of potential were determined. Ther...
Guardado en:
| Autores principales: | , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
1984
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/122408 https://www.sciencedirect.com/science/article/abs/pii/0022072884801904?via%3Dihub |
| Aporte de: |
| Sumario: | The Kolbe electrosynthesis on polycrystalline platinum in 1 M acetic acid/1 M potassium acetate electrolyte at 30 ° C was studied by using potentiostatic, low-frequency potentiodynamic and impedance techniques. Reaction products and their distribution as a function of potential were determined. There is a good correspondence in the potential ranges where changes in both stationary and non-stationary kinetic data, electrode resistance, electrode capacitance and reaction products were found. Results confirm the existence of different electrochemical reactions and correspondingly different reaction intermediates in the various Tafel regions. |
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