Phenomenology related to the kinetics of Kolbe electrosynthesis

The Kolbe electrosynthesis on polycrystalline platinum in 1 M acetic acid/1 M potassium acetate electrolyte at 30 ° C was studied by using potentiostatic, low-frequency potentiodynamic and impedance techniques. Reaction products and their distribution as a function of potential were determined. Ther...

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Detalles Bibliográficos
Autores principales: Cerviño, R. M., Triaca, Walter Enrique, Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1984
Materias:
Ciencias Exactas
Química
Kolbe electrosynthesis
Kinetics
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/122408
https://www.sciencedirect.com/science/article/abs/pii/0022072884801904?via%3Dihub
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-122408
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
Kolbe electrosynthesis
Kinetics
spellingShingle Ciencias Exactas
Química
Kolbe electrosynthesis
Kinetics
Cerviño, R. M.
Triaca, Walter Enrique
Arvia, Alejandro Jorge
Phenomenology related to the kinetics of Kolbe electrosynthesis
topic_facet Ciencias Exactas
Química
Kolbe electrosynthesis
Kinetics
description The Kolbe electrosynthesis on polycrystalline platinum in 1 M acetic acid/1 M potassium acetate electrolyte at 30 ° C was studied by using potentiostatic, low-frequency potentiodynamic and impedance techniques. Reaction products and their distribution as a function of potential were determined. There is a good correspondence in the potential ranges where changes in both stationary and non-stationary kinetic data, electrode resistance, electrode capacitance and reaction products were found. Results confirm the existence of different electrochemical reactions and correspondingly different reaction intermediates in the various Tafel regions.
format Articulo
Articulo
author Cerviño, R. M.
Triaca, Walter Enrique
Arvia, Alejandro Jorge
author_facet Cerviño, R. M.
Triaca, Walter Enrique
Arvia, Alejandro Jorge
author_sort Cerviño, R. M.
title Phenomenology related to the kinetics of Kolbe electrosynthesis
title_short Phenomenology related to the kinetics of Kolbe electrosynthesis
title_full Phenomenology related to the kinetics of Kolbe electrosynthesis
title_fullStr Phenomenology related to the kinetics of Kolbe electrosynthesis
title_full_unstemmed Phenomenology related to the kinetics of Kolbe electrosynthesis
title_sort phenomenology related to the kinetics of kolbe electrosynthesis
publishDate 1984
url http://sedici.unlp.edu.ar/handle/10915/122408
https://www.sciencedirect.com/science/article/abs/pii/0022072884801904?via%3Dihub
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AT triacawalterenrique phenomenologyrelatedtothekineticsofkolbeelectrosynthesis
AT arviaalejandrojorge phenomenologyrelatedtothekineticsofkolbeelectrosynthesis
bdutipo_str Repositorios
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