Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode

The concentration profiles of reacting species at the electrode—solution interface under a periodic square wave perturbing potential are calculated by solving the diffusion equation for the case of a fast reversible metal—metal ion reaction. This situation is particularly interesting in the electroc...

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Detalles Bibliográficos
Autores principales:	Marchiano, Susana Lucy, Rebollo Neira, L., Arvia, Alejandro Jorge
Formato:	Articulo
Lenguaje:	Inglés
Publicado:	1990
Materias:	Ciencias Exactas Química Electrochemical facetting of metals Pulsating diffusional boundary layers
Acceso en línea:	http://sedici.unlp.edu.ar/handle/10915/122107 https://www.sciencedirect.com/science/article/abs/pii/001346869087033X
Aporte de:	SEDICI (UNLP) de Universidad Nacional de La Plata

id	I19-R120-10915-122107
record_format	dspace
institution	Universidad Nacional de La Plata
institution_str	I-19
repository_str	R-120
collection	SEDICI (UNLP)
language	Inglés
topic	Ciencias Exactas Química Electrochemical facetting of metals Pulsating diffusional boundary layers
spellingShingle	Ciencias Exactas Química Electrochemical facetting of metals Pulsating diffusional boundary layers Marchiano, Susana Lucy Rebollo Neira, L. Arvia, Alejandro Jorge Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
topic_facet	Ciencias Exactas Química Electrochemical facetting of metals Pulsating diffusional boundary layers
description	The concentration profiles of reacting species at the electrode—solution interface under a periodic square wave perturbing potential are calculated by solving the diffusion equation for the case of a fast reversible metal—metal ion reaction. This situation is particularly interesting in the electrochemical facetting of metals. The model explains the dependence of current density and charge density on the frequency and number of cycles of the perturbing potential.
format	Articulo Articulo
author	Marchiano, Susana Lucy Rebollo Neira, L. Arvia, Alejandro Jorge
author_facet	Marchiano, Susana Lucy Rebollo Neira, L. Arvia, Alejandro Jorge
author_sort	Marchiano, Susana Lucy
title	Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
title_short	Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
title_full	Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
title_fullStr	Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
title_full_unstemmed	Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
title_sort	modelling of pulsating diffusional boundary layers : i. a reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode
publishDate	1990
url	http://sedici.unlp.edu.ar/handle/10915/122107 https://www.sciencedirect.com/science/article/abs/pii/001346869087033X
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bdutipo_str	Repositorios
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Modelling of pulsating diffusional boundary layers : I. A reversible metal—metal ion electrochemical reaction under symmetric square wave perturbing potentials at a plane electrode

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