Kinetics and mechanisms of electrochemical reactions on platinum with solutions of iodine-sodium-iodide in dimethylsulphoxide
The kinetics and mechanisms of the iodine and tri-iodide ion reduction and iodide and tri-iodide ion oxidation on platinum have been determined, from a study of the electrochemical kinetic behaviour of DMSO solutions containing an iodine/sodium-iodide ratio greater than one. The likely mechanisms ar...
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Autores principales: | , , |
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Formato: | Articulo |
Lenguaje: | Inglés |
Publicado: |
1969
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Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/121762 |
Aporte de: |
id |
I19-R120-10915-121762 |
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record_format |
dspace |
institution |
Universidad Nacional de La Plata |
institution_str |
I-19 |
repository_str |
R-120 |
collection |
SEDICI (UNLP) |
language |
Inglés |
topic |
Ciencias Exactas Química Kinetics Platinum DMSO |
spellingShingle |
Ciencias Exactas Química Kinetics Platinum DMSO Arvia, Alejandro Jorge Giordano, M. C. Podestá, José J. Kinetics and mechanisms of electrochemical reactions on platinum with solutions of iodine-sodium-iodide in dimethylsulphoxide |
topic_facet |
Ciencias Exactas Química Kinetics Platinum DMSO |
description |
The kinetics and mechanisms of the iodine and tri-iodide ion reduction and iodide and tri-iodide ion oxidation on platinum have been determined, from a study of the electrochemical kinetic behaviour of DMSO solutions containing an iodine/sodium-iodide ratio greater than one. The likely mechanisms are the same as those recently discussed for the iodine—sodium-iodide solutions in acetonitrile, and all comprise consecutive reaction schemes involving, for the processes in the anodic direction, an ion-plus-atom reaction as rate-determining step, and the reverse reaction for the cathodic processes. |
format |
Articulo Articulo |
author |
Arvia, Alejandro Jorge Giordano, M. C. Podestá, José J. |
author_facet |
Arvia, Alejandro Jorge Giordano, M. C. Podestá, José J. |
author_sort |
Arvia, Alejandro Jorge |
title |
Kinetics and mechanisms of electrochemical reactions on platinum with solutions of iodine-sodium-iodide in dimethylsulphoxide |
title_short |
Kinetics and mechanisms of electrochemical reactions on platinum with solutions of iodine-sodium-iodide in dimethylsulphoxide |
title_full |
Kinetics and mechanisms of electrochemical reactions on platinum with solutions of iodine-sodium-iodide in dimethylsulphoxide |
title_fullStr |
Kinetics and mechanisms of electrochemical reactions on platinum with solutions of iodine-sodium-iodide in dimethylsulphoxide |
title_full_unstemmed |
Kinetics and mechanisms of electrochemical reactions on platinum with solutions of iodine-sodium-iodide in dimethylsulphoxide |
title_sort |
kinetics and mechanisms of electrochemical reactions on platinum with solutions of iodine-sodium-iodide in dimethylsulphoxide |
publishDate |
1969 |
url |
http://sedici.unlp.edu.ar/handle/10915/121762 |
work_keys_str_mv |
AT arviaalejandrojorge kineticsandmechanismsofelectrochemicalreactionsonplatinumwithsolutionsofiodinesodiumiodideindimethylsulphoxide AT giordanomc kineticsandmechanismsofelectrochemicalreactionsonplatinumwithsolutionsofiodinesodiumiodideindimethylsulphoxide AT podestajosej kineticsandmechanismsofelectrochemicalreactionsonplatinumwithsolutionsofiodinesodiumiodideindimethylsulphoxide |
bdutipo_str |
Repositorios |
_version_ |
1764820448821903360 |