Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions

Rapid galvanostatic and potentiostatic stationary E/I curves, E/time characteristics at current interruption and electrode capacitance measurements were made to investigate hydrogen-ion discharge on mercury in HCl-DMSO solutions, with and without the addition of LiCl as supporting electrolyte. Kinet...

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Detalles Bibliográficos
Autores principales: Posadas, Dionisio, Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1973
Materias:
Ciencias Exactas
Química
Temperature
Kinetics
Hydrogen evolution
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/121727
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-121727
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
Temperature
Kinetics
Hydrogen evolution
spellingShingle Ciencias Exactas
Química
Temperature
Kinetics
Hydrogen evolution
Posadas, Dionisio
Arvia, Alejandro Jorge
Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
topic_facet Ciencias Exactas
Química
Temperature
Kinetics
Hydrogen evolution
description Rapid galvanostatic and potentiostatic stationary E/I curves, E/time characteristics at current interruption and electrode capacitance measurements were made to investigate hydrogen-ion discharge on mercury in HCl-DMSO solutions, with and without the addition of LiCl as supporting electrolyte. Kinetic parameters and their temperature and concentration dependences are discussed in terms of the initial electron-trnsfer reaction as rate-determining.
format Articulo
Articulo
author Posadas, Dionisio
Arvia, Alejandro Jorge
author_facet Posadas, Dionisio
Arvia, Alejandro Jorge
author_sort Posadas, Dionisio
title Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
title_short Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
title_full Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
title_fullStr Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
title_full_unstemmed Kinetics and mechanism of the hydrogen-evolution reaction on mercury in HCl-dimethylsulphoxide solutions
title_sort kinetics and mechanism of the hydrogen-evolution reaction on mercury in hcl-dimethylsulphoxide solutions
publishDate 1973
url http://sedici.unlp.edu.ar/handle/10915/121727
work_keys_str_mv AT posadasdionisio kineticsandmechanismofthehydrogenevolutionreactiononmercuryinhcldimethylsulphoxidesolutions
AT arviaalejandrojorge kineticsandmechanismofthehydrogenevolutionreactiononmercuryinhcldimethylsulphoxidesolutions
bdutipo_str Repositorios
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