Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction
Cerium-manganese mixed oxides with different composition were prepared by co-precipitation, characterized and evaluated for the water–gas shift (WGS) reaction. Base metal (5 wt.% Cu and 5 wt.% Ni) catalysts supported on Ce–Mn mixed oxides were also tested for the WGS reaction. The activity of the ba...
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| Autores principales: | , , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2014
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| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/121253 |
| Aporte de: |
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I19-R120-10915-121253 |
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| record_format |
dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Química Water–gas shift reaction Copper Nickel Cerium Manganese Fuel cells |
| spellingShingle |
Química Water–gas shift reaction Copper Nickel Cerium Manganese Fuel cells Poggio Fraccari, Eduardo D'Alessandro, Oriana Sambeth, Jorge Enrique Baronetti, Graciela T. Mariño, Fernando Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction |
| topic_facet |
Química Water–gas shift reaction Copper Nickel Cerium Manganese Fuel cells |
| description |
Cerium-manganese mixed oxides with different composition were prepared by co-precipitation, characterized and evaluated for the water–gas shift (WGS) reaction. Base metal (5 wt.% Cu and 5 wt.% Ni) catalysts supported on Ce–Mn mixed oxides were also tested for the WGS reaction. The activity of the bare supports is higher in the mixed samples than in pure ceria or manganese oxide. This result can be explained by a combination of greater reducibility and surface area in the mixed samples. Addition of base metals produces superior WGS catalysts. Particularly, nickel catalysts tested are able to reduce typical CO concentrations entering the WGS process to the CO levels tolerated by phosphoric acid fuel cells in a single unit operated at 400 °C. |
| format |
Articulo Articulo |
| author |
Poggio Fraccari, Eduardo D'Alessandro, Oriana Sambeth, Jorge Enrique Baronetti, Graciela T. Mariño, Fernando |
| author_facet |
Poggio Fraccari, Eduardo D'Alessandro, Oriana Sambeth, Jorge Enrique Baronetti, Graciela T. Mariño, Fernando |
| author_sort |
Poggio Fraccari, Eduardo |
| title |
Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction |
| title_short |
Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction |
| title_full |
Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction |
| title_fullStr |
Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction |
| title_full_unstemmed |
Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction |
| title_sort |
ce-mn mixed oxides as supports of copper- and nickel-based catalysts for water-gas shift reaction |
| publishDate |
2014 |
| url |
http://sedici.unlp.edu.ar/handle/10915/121253 |
| work_keys_str_mv |
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Repositorios |
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