Hydrolytic equilibria of metallic ions : III. The hydrolysis of NI(II) ion in NaCIO<sub>4</sub> solutions

The first acidic ionization constant of Ni(II) ion as nickelous perchlorate has been determined be a potentiometric titration at constant ionic strength in sodium perchlorate solutions at temperatures ranging from 25 to 50°C. Ni(II) ion concentrations from 2 to 20 × 10<sup>−3</sup> M hav...

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Autores principales: Bolzán, Agustín Eduardo, Jáuregui, Esteban A., Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1963
Materias:
Ciencias Exactas
Química
Acidic ionization
Hydrolysis reaction
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/121244
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-121244
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
Acidic ionization
Hydrolysis reaction
spellingShingle Ciencias Exactas
Química
Acidic ionization
Hydrolysis reaction
Bolzán, Agustín Eduardo
Jáuregui, Esteban A.
Arvia, Alejandro Jorge
Hydrolytic equilibria of metallic ions : III. The hydrolysis of NI(II) ion in NaCIO<sub>4</sub> solutions
topic_facet Ciencias Exactas
Química
Acidic ionization
Hydrolysis reaction
description The first acidic ionization constant of Ni(II) ion as nickelous perchlorate has been determined be a potentiometric titration at constant ionic strength in sodium perchlorate solutions at temperatures ranging from 25 to 50°C. Ni(II) ion concentrations from 2 to 20 × 10<sup>−3</sup> M have been employed. The assembled information indicates the first hydrolysis reaction of this ion is a mononuclear reaction where the complex NiOH+ is formed with ΔG29<sup>8′0</sup> = 13·25 ± 0·1 kcal/mole and ΔH29<sup>8′0</sup> = 7·76 ± 1·0 kcal/mole.
format Articulo
Articulo
author Bolzán, Agustín Eduardo
Jáuregui, Esteban A.
Arvia, Alejandro Jorge
author_facet Bolzán, Agustín Eduardo
Jáuregui, Esteban A.
Arvia, Alejandro Jorge
author_sort Bolzán, Agustín Eduardo
title Hydrolytic equilibria of metallic ions : III. The hydrolysis of NI(II) ion in NaCIO<sub>4</sub> solutions
title_short Hydrolytic equilibria of metallic ions : III. The hydrolysis of NI(II) ion in NaCIO<sub>4</sub> solutions
title_full Hydrolytic equilibria of metallic ions : III. The hydrolysis of NI(II) ion in NaCIO<sub>4</sub> solutions
title_fullStr Hydrolytic equilibria of metallic ions : III. The hydrolysis of NI(II) ion in NaCIO<sub>4</sub> solutions
title_full_unstemmed Hydrolytic equilibria of metallic ions : III. The hydrolysis of NI(II) ion in NaCIO<sub>4</sub> solutions
title_sort hydrolytic equilibria of metallic ions : iii. the hydrolysis of ni(ii) ion in nacio<sub>4</sub> solutions
publishDate 1963
url http://sedici.unlp.edu.ar/handle/10915/121244
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AT jaureguiestebana hydrolyticequilibriaofmetallicionsiiithehydrolysisofniiiioninnaciosub4subsolutions
AT arviaalejandrojorge hydrolyticequilibriaofmetallicionsiiithehydrolysisofniiiioninnaciosub4subsolutions
bdutipo_str Repositorios
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