The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride

The molecular structure of C7H7SO2CI was determined by X-ray diffraction and refined to R = 0.060 and Rw = 0.053 from 1170 unique reflections. The unit cell is triclinic, P1, with Z = 2, a = 8.528(5), b = 8.214(3), c = 6.306(2) A; a = 95.47(3), ß = 104.41(3), y = 93.08(4)°; V = 424.6(3) ų; u = 6.30...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Rigotti, Guillermo, Rivero, Blas Eduardo, Filgueira, Roberto Raúl
Formato: Articulo
Lenguaje:Inglés
Publicado: 1986
Materias:
Química
4-Methyl Benzenesulfonyl chloride
Molecular structure
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/120223
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-120223
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
4-Methyl Benzenesulfonyl chloride
Molecular structure
spellingShingle Química
4-Methyl Benzenesulfonyl chloride
Molecular structure
Rigotti, Guillermo
Rivero, Blas Eduardo
Filgueira, Roberto Raúl
The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride
topic_facet Química
4-Methyl Benzenesulfonyl chloride
Molecular structure
description The molecular structure of C7H7SO2CI was determined by X-ray diffraction and refined to R = 0.060 and Rw = 0.053 from 1170 unique reflections. The unit cell is triclinic, P1, with Z = 2, a = 8.528(5), b = 8.214(3), c = 6.306(2) A; a = 95.47(3), ß = 104.41(3), y = 93.08(4)°; V = 424.6(3) ų; u = 6.30 cm⁻¹; δcale = 1.49 Mg. m⁻³; F(000) = 196. The dihedral angle between the benzene ring and the CI-S-C(l) plane [84.3(1)°] is similar to those observed for benzenesulfonyl chlorides where molecular packing results from normal van der Waals interactions [1, 2], The compound has normal bond lengths and angles. Distortion of the benzene ring is in agreement with the predicted σ- and π-effects of substituent groups [3], No significantly short intermolecular distances were found.
format Articulo
Articulo
author Rigotti, Guillermo
Rivero, Blas Eduardo
Filgueira, Roberto Raúl
author_facet Rigotti, Guillermo
Rivero, Blas Eduardo
Filgueira, Roberto Raúl
author_sort Rigotti, Guillermo
title The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride
title_short The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride
title_full The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride
title_fullStr The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride
title_full_unstemmed The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride
title_sort molecular structure of 4-methyl benzenesulfonyl chloride
publishDate 1986
url http://sedici.unlp.edu.ar/handle/10915/120223
work_keys_str_mv AT rigottiguillermo themolecularstructureof4methylbenzenesulfonylchloride
AT riveroblaseduardo themolecularstructureof4methylbenzenesulfonylchloride
AT filgueirarobertoraul themolecularstructureof4methylbenzenesulfonylchloride
AT rigottiguillermo molecularstructureof4methylbenzenesulfonylchloride
AT riveroblaseduardo molecularstructureof4methylbenzenesulfonylchloride
AT filgueirarobertoraul molecularstructureof4methylbenzenesulfonylchloride
bdutipo_str Repositorios
_version_ 1764820449519206400

Ejemplares similares