Electrochemistry of fuming sulphuric acids : III. Mechanism of the cathodic reactions on platinum

The cathodic potential-decay process on platinum electrodes in oleums has been investigated by means of a rotating disk. The non-stady parameters are compared with those already reported under steady-state conditions. Both results are discussed in terms of a general reaction mechanism comprising var...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Arvia, Alejandro Jorge, Carrozza, Jesús Simón, Garrera, H. A.
Formato:	Articulo
Lenguaje:	Inglés
Publicado:	1971
Materias:	Ciencias Exactas Química Fuming sulphuric acids Cathodic reactions Platinum
Acceso en línea:	http://sedici.unlp.edu.ar/handle/10915/119938 https://www.sciencedirect.com/science/article/abs/pii/0013468671851290
Aporte de:	SEDICI (UNLP) de Universidad Nacional de La Plata

id	I19-R120-10915-119938
record_format	dspace
institution	Universidad Nacional de La Plata
institution_str	I-19
repository_str	R-120
collection	SEDICI (UNLP)
language	Inglés
topic	Ciencias Exactas Química Fuming sulphuric acids Cathodic reactions Platinum
spellingShingle	Ciencias Exactas Química Fuming sulphuric acids Cathodic reactions Platinum Arvia, Alejandro Jorge Carrozza, Jesús Simón Garrera, H. A. Electrochemistry of fuming sulphuric acids : III. Mechanism of the cathodic reactions on platinum
topic_facet	Ciencias Exactas Química Fuming sulphuric acids Cathodic reactions Platinum
description	The cathodic potential-decay process on platinum electrodes in oleums has been investigated by means of a rotating disk. The non-stady parameters are compared with those already reported under steady-state conditions. Both results are discussed in terms of a general reaction mechanism comprising various consecutive as well as alternative steps, considering that the main cathodic product is sulphur dioxide. The SO<sub>3</sub>-containing species acts as a depolarizer by reacting with hydrogen atoms adsorbed on the electrode surface.
format	Articulo Articulo
author	Arvia, Alejandro Jorge Carrozza, Jesús Simón Garrera, H. A.
author_facet	Arvia, Alejandro Jorge Carrozza, Jesús Simón Garrera, H. A.
author_sort	Arvia, Alejandro Jorge
title	Electrochemistry of fuming sulphuric acids : III. Mechanism of the cathodic reactions on platinum
title_short	Electrochemistry of fuming sulphuric acids : III. Mechanism of the cathodic reactions on platinum
title_full	Electrochemistry of fuming sulphuric acids : III. Mechanism of the cathodic reactions on platinum
title_fullStr	Electrochemistry of fuming sulphuric acids : III. Mechanism of the cathodic reactions on platinum
title_full_unstemmed	Electrochemistry of fuming sulphuric acids : III. Mechanism of the cathodic reactions on platinum
title_sort	electrochemistry of fuming sulphuric acids : iii. mechanism of the cathodic reactions on platinum
publishDate	1971
url	http://sedici.unlp.edu.ar/handle/10915/119938 https://www.sciencedirect.com/science/article/abs/pii/0013468671851290
work_keys_str_mv	AT arviaalejandrojorge electrochemistryoffumingsulphuricacidsiiimechanismofthecathodicreactionsonplatinum AT carrozzajesussimon electrochemistryoffumingsulphuricacidsiiimechanismofthecathodicreactionsonplatinum AT garreraha electrochemistryoffumingsulphuricacidsiiimechanismofthecathodicreactionsonplatinum
bdutipo_str	Repositorios
_version_	1764820449093484549

Electrochemistry of fuming sulphuric acids : III. Mechanism of the cathodic reactions on platinum

Ejemplares similares