DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol
On-line mass spectroscopy (DEMS) and in-situ Fourier transform IR spectroscope (FTIRS) have been employed to study the electro-oxidation and the electroreduction products of allyl alcohol on Pt electrodes in acids. The electroreduction products were propanol and a mixture of propylene, propane and e...
Guardado en:
Autores principales: | , , , , , |
---|---|
Formato: | Articulo |
Lenguaje: | Inglés |
Publicado: |
1993
|
Materias: | |
Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/119264 |
Aporte de: |
id |
I19-R120-10915-119264 |
---|---|
record_format |
dspace |
institution |
Universidad Nacional de La Plata |
institution_str |
I-19 |
repository_str |
R-120 |
collection |
SEDICI (UNLP) |
language |
Inglés |
topic |
Ciencias Exactas Química Mass spectroscopy Fourier transform IR spectroscope Allyl alcohol |
spellingShingle |
Ciencias Exactas Química Mass spectroscopy Fourier transform IR spectroscope Allyl alcohol Pastor, E. Wasmus, S. Iwasita, T. Arévalo, M. C. González, S. Arvia, Alejandro Jorge DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol |
topic_facet |
Ciencias Exactas Química Mass spectroscopy Fourier transform IR spectroscope Allyl alcohol |
description |
On-line mass spectroscopy (DEMS) and in-situ Fourier transform IR spectroscope (FTIRS) have been employed to study the electro-oxidation and the electroreduction products of allyl alcohol on Pt electrodes in acids. The electroreduction products were propanol and a mixture of propylene, propane and ethane. The main oxidation products were CO<sub>2</sub> and acrolein. Results are interpreted and possible mechanisms are suggested with the participation of adsorbates having different chain lengths and structures. |
format |
Articulo Articulo |
author |
Pastor, E. Wasmus, S. Iwasita, T. Arévalo, M. C. González, S. Arvia, Alejandro Jorge |
author_facet |
Pastor, E. Wasmus, S. Iwasita, T. Arévalo, M. C. González, S. Arvia, Alejandro Jorge |
author_sort |
Pastor, E. |
title |
DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol |
title_short |
DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol |
title_full |
DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol |
title_fullStr |
DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol |
title_full_unstemmed |
DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol |
title_sort |
dems and in-situ ftir investigations of c<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : part ii. allyl alcohol |
publishDate |
1993 |
url |
http://sedici.unlp.edu.ar/handle/10915/119264 |
work_keys_str_mv |
AT pastore demsandinsituftirinvestigationsofcsub3subprimaryalcoholsonplatinumelectrodesinacidsolutionspartiiallylalcohol AT wasmuss demsandinsituftirinvestigationsofcsub3subprimaryalcoholsonplatinumelectrodesinacidsolutionspartiiallylalcohol AT iwasitat demsandinsituftirinvestigationsofcsub3subprimaryalcoholsonplatinumelectrodesinacidsolutionspartiiallylalcohol AT arevalomc demsandinsituftirinvestigationsofcsub3subprimaryalcoholsonplatinumelectrodesinacidsolutionspartiiallylalcohol AT gonzalezs demsandinsituftirinvestigationsofcsub3subprimaryalcoholsonplatinumelectrodesinacidsolutionspartiiallylalcohol AT arviaalejandrojorge demsandinsituftirinvestigationsofcsub3subprimaryalcoholsonplatinumelectrodesinacidsolutionspartiiallylalcohol |
bdutipo_str |
Repositorios |
_version_ |
1764820448114114560 |