Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest
The electro-oxidation of glucose and related compounds was studied in phosphate buffered media using a smooth platinum working electrode at different temperatures. A comparative analysis of the electrochemical behaviour of glucose and gluconic acid was made. Different electrochemical responses were...
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Autores principales: | , , |
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Formato: | Articulo |
Lenguaje: | Inglés |
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1982
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Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/118326 |
Aporte de: |
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I19-R120-10915-118326 |
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record_format |
dspace |
institution |
Universidad Nacional de La Plata |
institution_str |
I-19 |
repository_str |
R-120 |
collection |
SEDICI (UNLP) |
language |
Inglés |
topic |
Ciencias Exactas Química Glucose Electrochemical behaviour Electro-oxidation |
spellingShingle |
Ciencias Exactas Química Glucose Electrochemical behaviour Electro-oxidation Fernández Lorenzo de Mele, Mónica Alicia Videla, Héctor A. Arvia, Alejandro Jorge Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest |
topic_facet |
Ciencias Exactas Química Glucose Electrochemical behaviour Electro-oxidation |
description |
The electro-oxidation of glucose and related compounds was studied in phosphate buffered media using a smooth platinum working electrode at different temperatures. A comparative analysis of the electrochemical behaviour of glucose and gluconic acid was made. Different electrochemical responses were found in the hydrogen adatom and in the PtO layer formation potential regions. Potentiostatic and potentiodynamic measurements with inositol, fructose, xylose, arabinose and glucose-1-phosphate were also performed in an attempt to find a relation between the electrochemical behaviour and the structural characteristics of these molecules. Our results suggest that the hemiacetalic group of the glucose molecule seems to play an important role in the electro-oxidation process. The electro-oxidation order of the different carbohydrates and derivatives resembles to some extent the electrochemical conversion order already established for other compounds. |
format |
Articulo Articulo |
author |
Fernández Lorenzo de Mele, Mónica Alicia Videla, Héctor A. Arvia, Alejandro Jorge |
author_facet |
Fernández Lorenzo de Mele, Mónica Alicia Videla, Héctor A. Arvia, Alejandro Jorge |
author_sort |
Fernández Lorenzo de Mele, Mónica Alicia |
title |
Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest |
title_short |
Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest |
title_full |
Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest |
title_fullStr |
Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest |
title_full_unstemmed |
Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest |
title_sort |
comparative study of the electrochemical behaviour of glucose and other compounds of biological interest |
publishDate |
1982 |
url |
http://sedici.unlp.edu.ar/handle/10915/118326 |
work_keys_str_mv |
AT fernandezlorenzodemelemonicaalicia comparativestudyoftheelectrochemicalbehaviourofglucoseandothercompoundsofbiologicalinterest AT videlahectora comparativestudyoftheelectrochemicalbehaviourofglucoseandothercompoundsofbiologicalinterest AT arviaalejandrojorge comparativestudyoftheelectrochemicalbehaviourofglucoseandothercompoundsofbiologicalinterest |
bdutipo_str |
Repositorios |
_version_ |
1764820447754452992 |