Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest

The electro-oxidation of glucose and related compounds was studied in phosphate buffered media using a smooth platinum working electrode at different temperatures. A comparative analysis of the electrochemical behaviour of glucose and gluconic acid was made. Different electrochemical responses were...

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Autores principales: Fernández Lorenzo de Mele, Mónica Alicia, Videla, Héctor A., Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1982
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/118326
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id I19-R120-10915-118326
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
Glucose
Electrochemical behaviour
Electro-oxidation
spellingShingle Ciencias Exactas
Química
Glucose
Electrochemical behaviour
Electro-oxidation
Fernández Lorenzo de Mele, Mónica Alicia
Videla, Héctor A.
Arvia, Alejandro Jorge
Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest
topic_facet Ciencias Exactas
Química
Glucose
Electrochemical behaviour
Electro-oxidation
description The electro-oxidation of glucose and related compounds was studied in phosphate buffered media using a smooth platinum working electrode at different temperatures. A comparative analysis of the electrochemical behaviour of glucose and gluconic acid was made. Different electrochemical responses were found in the hydrogen adatom and in the PtO layer formation potential regions. Potentiostatic and potentiodynamic measurements with inositol, fructose, xylose, arabinose and glucose-1-phosphate were also performed in an attempt to find a relation between the electrochemical behaviour and the structural characteristics of these molecules. Our results suggest that the hemiacetalic group of the glucose molecule seems to play an important role in the electro-oxidation process. The electro-oxidation order of the different carbohydrates and derivatives resembles to some extent the electrochemical conversion order already established for other compounds.
format Articulo
Articulo
author Fernández Lorenzo de Mele, Mónica Alicia
Videla, Héctor A.
Arvia, Alejandro Jorge
author_facet Fernández Lorenzo de Mele, Mónica Alicia
Videla, Héctor A.
Arvia, Alejandro Jorge
author_sort Fernández Lorenzo de Mele, Mónica Alicia
title Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest
title_short Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest
title_full Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest
title_fullStr Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest
title_full_unstemmed Comparative study of the electrochemical behaviour of glucose and other compounds of biological interest
title_sort comparative study of the electrochemical behaviour of glucose and other compounds of biological interest
publishDate 1982
url http://sedici.unlp.edu.ar/handle/10915/118326
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AT arviaalejandrojorge comparativestudyoftheelectrochemicalbehaviourofglucoseandothercompoundsofbiologicalinterest
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