Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
The infrared spectrum of gaseous chloryl fluoride has been investigated in the region between 2.5 and 25 μ at pressures from ca. 1 mm Hg to ca. 1 atm at room temperature. The strong bands located at 1265, 1104, 627 and 542 cm<sup>-1</sup> have been assigned to four of the six fundamental...
Guardado en:
| Autores principales: | , |
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| Formato: | Articulo |
| Lenguaje: | Español |
| Publicado: |
1963
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/118208 |
| Aporte de: |
| Sumario: | The infrared spectrum of gaseous chloryl fluoride has been investigated in the region between 2.5 and 25 μ at pressures from ca. 1 mm Hg to ca. 1 atm at room temperature. The strong bands located at 1265, 1104, 627 and 542 cm<sup>-1</sup> have been assigned to four of the six fundamental vibrations expected for a pyramidal tetratomic molecule pertaining to the C<sub>8</sub> point group. The other two bands could not be detected but they were tcnt,atively located at 405 and 349 cm<sup>-1</sup>. A correlation of the chloryl fluoride spectrum with spectra of related molecules and ions has been useful to the assignment of the bands. |
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