Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)

The infrared spectrum of gaseous chloryl fluoride has been investigated in the region between 2.5 and 25 μ at pressures from ca. 1 mm Hg to ca. 1 atm at room temperature. The strong bands located at 1265, 1104, 627 and 542 cm<sup>-1</sup> have been assigned to four of the six fundamental...

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Detalles Bibliográficos
Autores principales: Arvia, Alejandro Jorge, Aymonino, Pedro José
Formato: Articulo
Lenguaje:Español
Publicado: 1963
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/118208
Aporte de:
id I19-R120-10915-118208
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Español
topic Ciencias Exactas
Química
Chloryl fluoride
Infrared spectrum
spellingShingle Ciencias Exactas
Química
Chloryl fluoride
Infrared spectrum
Arvia, Alejandro Jorge
Aymonino, Pedro José
Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
topic_facet Ciencias Exactas
Química
Chloryl fluoride
Infrared spectrum
description The infrared spectrum of gaseous chloryl fluoride has been investigated in the region between 2.5 and 25 μ at pressures from ca. 1 mm Hg to ca. 1 atm at room temperature. The strong bands located at 1265, 1104, 627 and 542 cm<sup>-1</sup> have been assigned to four of the six fundamental vibrations expected for a pyramidal tetratomic molecule pertaining to the C<sub>8</sub> point group. The other two bands could not be detected but they were tcnt,atively located at 405 and 349 cm<sup>-1</sup>. A correlation of the chloryl fluoride spectrum with spectra of related molecules and ions has been useful to the assignment of the bands.
format Articulo
Articulo
author Arvia, Alejandro Jorge
Aymonino, Pedro José
author_facet Arvia, Alejandro Jorge
Aymonino, Pedro José
author_sort Arvia, Alejandro Jorge
title Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
title_short Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
title_full Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
title_fullStr Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
title_full_unstemmed Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
title_sort infra-red absorption spectrum of gaseous chloryl fluoride (fc1o<sub>2</sub>)
publishDate 1963
url http://sedici.unlp.edu.ar/handle/10915/118208
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