Three new thiosaccharin derivatives generated in a complex reaction system

The reaction between thiosaccharin and ethylamine showed to be relatively complex. The main product of this reaction is 3-ethylamino-1,2-benzisothiazole 1,1-dioxide (1), which could be clearly identified by NMR and IR spectroscopies. Ethylammonium thiosaccharinate (2) and 3-vinylamino-1,2-benzisothi...

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Detalles Bibliográficos
Autores principales:	Echeverría, Gustavo Alberto, Piro, Oscar Enrique, Zinczuk, Juan, Baran, Enrique José
Formato:	Articulo Comunicacion
Lenguaje:	Inglés
Publicado:	2017
Materias:	Química Thiosaccharin/ethylamine reaction 3-ethylamino-1,2-benzisothiazole 1,1 dioxide ethylammonium thiosaccharinate 3-vinylamino-1,2-benzisothiazole 1,1 dioxide crystal structures
Acceso en línea:	http://sedici.unlp.edu.ar/handle/10915/116579 https://www.aqa.org.ar/images/anales/pdf104-1/104-1-abstracts.pdf
Aporte de:	SEDICI (UNLP) de Universidad Nacional de La Plata

id	I19-R120-10915-116579
record_format	dspace
institution	Universidad Nacional de La Plata
institution_str	I-19
repository_str	R-120
collection	SEDICI (UNLP)
language	Inglés
topic	Química Thiosaccharin/ethylamine reaction 3-ethylamino-1,2-benzisothiazole 1,1 dioxide ethylammonium thiosaccharinate 3-vinylamino-1,2-benzisothiazole 1,1 dioxide crystal structures
spellingShingle	Química Thiosaccharin/ethylamine reaction 3-ethylamino-1,2-benzisothiazole 1,1 dioxide ethylammonium thiosaccharinate 3-vinylamino-1,2-benzisothiazole 1,1 dioxide crystal structures Echeverría, Gustavo Alberto Piro, Oscar Enrique Zinczuk, Juan Baran, Enrique José Three new thiosaccharin derivatives generated in a complex reaction system
topic_facet	Química Thiosaccharin/ethylamine reaction 3-ethylamino-1,2-benzisothiazole 1,1 dioxide ethylammonium thiosaccharinate 3-vinylamino-1,2-benzisothiazole 1,1 dioxide crystal structures
description	The reaction between thiosaccharin and ethylamine showed to be relatively complex. The main product of this reaction is 3-ethylamino-1,2-benzisothiazole 1,1-dioxide (1), which could be clearly identified by NMR and IR spectroscopies. Ethylammonium thiosaccharinate (2) and 3-vinylamino-1,2-benzisothiazole 1,1 dioxide (3) were generated as minor by products during this reaction and their structures were determined by X-ray diffraction methods. The (2) salt crystallizes in the monoclinic P21/c space group with a=13.1367(5), b=9.9721(4), c=8.8217(3) Å, β=99.125(4)°, and Z=4, whereas compound (3) belongs to the P21/m space group with a=7.1572(5), b=7.0242(7), c=9.5503(8) Å, β=95.008(7)°, and Z=2.
format	Articulo Comunicacion
author	Echeverría, Gustavo Alberto Piro, Oscar Enrique Zinczuk, Juan Baran, Enrique José
author_facet	Echeverría, Gustavo Alberto Piro, Oscar Enrique Zinczuk, Juan Baran, Enrique José
author_sort	Echeverría, Gustavo Alberto
title	Three new thiosaccharin derivatives generated in a complex reaction system
title_short	Three new thiosaccharin derivatives generated in a complex reaction system
title_full	Three new thiosaccharin derivatives generated in a complex reaction system
title_fullStr	Three new thiosaccharin derivatives generated in a complex reaction system
title_full_unstemmed	Three new thiosaccharin derivatives generated in a complex reaction system
title_sort	three new thiosaccharin derivatives generated in a complex reaction system
publishDate	2017
url	http://sedici.unlp.edu.ar/handle/10915/116579 https://www.aqa.org.ar/images/anales/pdf104-1/104-1-abstracts.pdf
work_keys_str_mv	AT echeverriagustavoalberto threenewthiosaccharinderivativesgeneratedinacomplexreactionsystem AT pirooscarenrique threenewthiosaccharinderivativesgeneratedinacomplexreactionsystem AT zinczukjuan threenewthiosaccharinderivativesgeneratedinacomplexreactionsystem AT baranenriquejose threenewthiosaccharinderivativesgeneratedinacomplexreactionsystem
bdutipo_str	Repositorios
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Three new thiosaccharin derivatives generated in a complex reaction system

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