Valorization of Different Wastes and Their Use for the Design of Multifunctional Eco-catalysts

The desire to protect the environment for future generations has led to the reutilization of all recoverable and recyclable wastes. Consequently, different residues from various sources were collected to make mixed compounds to be used as catalyst supports. Such wastes included sand and cement from...

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Detalles Bibliográficos
Autores principales: Palermo, Valeria, Igal, Katerine, Colombo Migliorero, María Belén, Sathicq, Ángel Gabriel, Quaranta, Nancy, Vázquez, Patricia Graciela, Romanelli, Gustavo Pablo
Formato: Articulo
Lenguaje:Inglés
Publicado: 2017
Materias:
Química
Waste valorization
Catalysts
Heteropolyacids
3,4-Dihydropyrimidinones
Sulfide oxidation
Green Chemistry
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/108512
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-108512
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Waste valorization
Catalysts
Heteropolyacids
3,4-Dihydropyrimidinones
Sulfide oxidation
Green Chemistry
spellingShingle Química
Waste valorization
Catalysts
Heteropolyacids
3,4-Dihydropyrimidinones
Sulfide oxidation
Green Chemistry
Palermo, Valeria
Igal, Katerine
Colombo Migliorero, María Belén
Sathicq, Ángel Gabriel
Quaranta, Nancy
Vázquez, Patricia Graciela
Romanelli, Gustavo Pablo
Valorization of Different Wastes and Their Use for the Design of Multifunctional Eco-catalysts
topic_facet Química
Waste valorization
Catalysts
Heteropolyacids
3,4-Dihydropyrimidinones
Sulfide oxidation
Green Chemistry
description The desire to protect the environment for future generations has led to the reutilization of all recoverable and recyclable wastes. Consequently, different residues from various sources were collected to make mixed compounds to be used as catalyst supports. Such wastes included sand and cement from the building industry, nonreturnable glass bottles, and used tires. The synthesized supports were impregnated with molybdophosphoric acid, a heteropolyacid with Keggin structure, and characterized by potentiometric titration, optical microscopy, SEM–EDS, and textural property analyses. The bifunctional properties of the new catalysts were evaluated in two relevant transformations in green conditions: (i) the selective oxidation of sulfides to sulfoxides using a green oxidant such as tertbutyl hydroperoxide, and (ii) the multicomponent synthesis of 3,4-dihydropyrimidinones (Biginelli reaction, catalyzed in acid media).
format Articulo
Articulo
author Palermo, Valeria
Igal, Katerine
Colombo Migliorero, María Belén
Sathicq, Ángel Gabriel
Quaranta, Nancy
Vázquez, Patricia Graciela
Romanelli, Gustavo Pablo
author_facet Palermo, Valeria
Igal, Katerine
Colombo Migliorero, María Belén
Sathicq, Ángel Gabriel
Quaranta, Nancy
Vázquez, Patricia Graciela
Romanelli, Gustavo Pablo
author_sort Palermo, Valeria
title Valorization of Different Wastes and Their Use for the Design of Multifunctional Eco-catalysts
title_short Valorization of Different Wastes and Their Use for the Design of Multifunctional Eco-catalysts
title_full Valorization of Different Wastes and Their Use for the Design of Multifunctional Eco-catalysts
title_fullStr Valorization of Different Wastes and Their Use for the Design of Multifunctional Eco-catalysts
title_full_unstemmed Valorization of Different Wastes and Their Use for the Design of Multifunctional Eco-catalysts
title_sort valorization of different wastes and their use for the design of multifunctional eco-catalysts
publishDate 2017
url http://sedici.unlp.edu.ar/handle/10915/108512
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bdutipo_str Repositorios
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