Self-assembled monolayers of thiolates on metals: A review article on sulfur-metal chemistry and surface structures

A review article on fundamental aspects of thiolate self-assembled monolayers (SAMs) on the (111) and (100) surfaces of the Cu and Ni groups is presented. In particular this work is focused on two important points that remain poorly understood in most of these metals: the chemistry of the S-metal in...

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Autores principales: Vericat, Carolina, Vela, María Elena, Corthey, Gastón, Pensa, Evangelina Laura, Cortés, Emiliano, Fonticelli, Mariano Hernán, Ibáñez, Francisco Javier, Benitez, Guillermo Alfredo, Carro, P., Salvarezza, Roberto Carlos
Formato: Articulo Preprint
Lenguaje:Inglés
Publicado: 2014
Materias:
Química
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/106650
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-106650
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
spellingShingle Química
Vericat, Carolina
Vela, María Elena
Corthey, Gastón
Pensa, Evangelina Laura
Cortés, Emiliano
Fonticelli, Mariano Hernán
Ibáñez, Francisco Javier
Benitez, Guillermo Alfredo
Carro, P.
Salvarezza, Roberto Carlos
Self-assembled monolayers of thiolates on metals: A review article on sulfur-metal chemistry and surface structures
topic_facet Química
description A review article on fundamental aspects of thiolate self-assembled monolayers (SAMs) on the (111) and (100) surfaces of the Cu and Ni groups is presented. In particular this work is focused on two important points that remain poorly understood in most of these metals: the chemistry of the S-metal interface, which strongly depends on the nature of the metallic surface, and the role of the interaction forces that not only guide the self-assembly process but also influence the surface structure of SAMs. In addition to recent experimental and theoretical data on these issues we present new density functional calculations including van der Waals forces for an important number of known thiolate surface structures as a function of the hydrocarbon chain length.
format Articulo
Preprint
author Vericat, Carolina
Vela, María Elena
Corthey, Gastón
Pensa, Evangelina Laura
Cortés, Emiliano
Fonticelli, Mariano Hernán
Ibáñez, Francisco Javier
Benitez, Guillermo Alfredo
Carro, P.
Salvarezza, Roberto Carlos
author_facet Vericat, Carolina
Vela, María Elena
Corthey, Gastón
Pensa, Evangelina Laura
Cortés, Emiliano
Fonticelli, Mariano Hernán
Ibáñez, Francisco Javier
Benitez, Guillermo Alfredo
Carro, P.
Salvarezza, Roberto Carlos
author_sort Vericat, Carolina
title Self-assembled monolayers of thiolates on metals: A review article on sulfur-metal chemistry and surface structures
title_short Self-assembled monolayers of thiolates on metals: A review article on sulfur-metal chemistry and surface structures
title_full Self-assembled monolayers of thiolates on metals: A review article on sulfur-metal chemistry and surface structures
title_fullStr Self-assembled monolayers of thiolates on metals: A review article on sulfur-metal chemistry and surface structures
title_full_unstemmed Self-assembled monolayers of thiolates on metals: A review article on sulfur-metal chemistry and surface structures
title_sort self-assembled monolayers of thiolates on metals: a review article on sulfur-metal chemistry and surface structures
publishDate 2014
url http://sedici.unlp.edu.ar/handle/10915/106650
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