Heterogeneous catalytic oxidation of R-(+)-limonene on Jacobsen type catalysts
The development of heterogeneous catalytic processes is highly desirable in order to overcome somedrawbacks of homogeneous catalysts, such as the separation and recycling of these catalysts. In this work,we report that Jacobsen type catalysts are efficient and selective for the oxidation of R-(+)-li...
Guardado en:
| Autores principales: | , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2014
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| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/104732 http://hdl.handle.net/11336/5559 |
| Aporte de: |
| id |
I19-R120-10915-104732 |
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| record_format |
dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Ingeniería Química Limonene Jacobsen catalyst Diepoxides Catalizadores tipo jacobsen Diepóxidos Recuperación del catalizador R-(+)-limoneno |
| spellingShingle |
Ingeniería Química Limonene Jacobsen catalyst Diepoxides Catalizadores tipo jacobsen Diepóxidos Recuperación del catalizador R-(+)-limoneno Cubillos Lobo, Jairo Antonio Paez Guevara, L. A. Romanelli, Gustavo Pablo Heterogeneous catalytic oxidation of R-(+)-limonene on Jacobsen type catalysts |
| topic_facet |
Ingeniería Química Limonene Jacobsen catalyst Diepoxides Catalizadores tipo jacobsen Diepóxidos Recuperación del catalizador R-(+)-limoneno |
| description |
The development of heterogeneous catalytic processes is highly desirable in order to overcome somedrawbacks of homogeneous catalysts, such as the separation and recycling of these catalysts. In this work,we report that Jacobsen type catalysts are efficient and selective for the oxidation of R-(+)-limonene to itscorresponding diepoxides using in situ generated dimethyldioxirane (DMD) as oxidant. It was demonstratedthat the solid NaHCO3 addition to the initial reaction mixture, improves the catalytic activity. Additionally,catalyst samples can be recovered and reused at least twice without significant loss of its initial catalyticactivity. |
| format |
Articulo Articulo |
| author |
Cubillos Lobo, Jairo Antonio Paez Guevara, L. A. Romanelli, Gustavo Pablo |
| author_facet |
Cubillos Lobo, Jairo Antonio Paez Guevara, L. A. Romanelli, Gustavo Pablo |
| author_sort |
Cubillos Lobo, Jairo Antonio |
| title |
Heterogeneous catalytic oxidation of R-(+)-limonene on Jacobsen type catalysts |
| title_short |
Heterogeneous catalytic oxidation of R-(+)-limonene on Jacobsen type catalysts |
| title_full |
Heterogeneous catalytic oxidation of R-(+)-limonene on Jacobsen type catalysts |
| title_fullStr |
Heterogeneous catalytic oxidation of R-(+)-limonene on Jacobsen type catalysts |
| title_full_unstemmed |
Heterogeneous catalytic oxidation of R-(+)-limonene on Jacobsen type catalysts |
| title_sort |
heterogeneous catalytic oxidation of r-(+)-limonene on jacobsen type catalysts |
| publishDate |
2014 |
| url |
http://sedici.unlp.edu.ar/handle/10915/104732 http://hdl.handle.net/11336/5559 |
| work_keys_str_mv |
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Repositorios |
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1764820442279837696 |