Additive synthesis by sol-gel method for its use as antimicrobial
The antimicrobial activity of silver nanoparticles makes this chemical element attractive for their incorporation in different materials. Additionally, heteropolyacids (HPAs) have advantages as catalysts which make them environmentally very interesting. The objective of this work is to incorporate i...
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Formato: | Articulo |
Lenguaje: | Inglés |
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2015
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Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/104356 http://hdl.handle.net/11336/39575 |
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I19-R120-10915-104356 |
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institution |
Universidad Nacional de La Plata |
institution_str |
I-19 |
repository_str |
R-120 |
collection |
SEDICI (UNLP) |
language |
Inglés |
topic |
Ingeniería en Materiales Sol-gel Additives Heteropolyacids Ag |
spellingShingle |
Ingeniería en Materiales Sol-gel Additives Heteropolyacids Ag Arreche, Romina Andrea Hernández, María Florencia Blanco, Mirta Noemí Vázquez, Patricia Graciela Additive synthesis by sol-gel method for its use as antimicrobial |
topic_facet |
Ingeniería en Materiales Sol-gel Additives Heteropolyacids Ag |
description |
The antimicrobial activity of silver nanoparticles makes this chemical element attractive for their incorporation in different materials. Additionally, heteropolyacids (HPAs) have advantages as catalysts which make them environmentally very interesting. The objective of this work is to incorporate in a silica matrix obtained by sol-gel an HPA together with Ag, for their use as fillers in paints or adhesives. Six samples were synthesized, using tetraethoxysilane, methyltrimethoxysilane, acetic acid, molybdophosphoric acid and silver acetate. The silicas were characterized by potentiometric titration, XRD, SEM, TEM, SBET and FT-IR. When HPA is used instead of acetic acid, a variation on the final acidity is produced. The specific surface area decreases when HPA is incorporated into the silica synthesized using tetraethoxysilane as precursor, noticing a slight increase when Ag is added because a different distribution of HPA in the matrix. By SEM, it was observed that the particle size is bigger when the silicas are synthesized with TEOS-HPA, but it still shows the characteristic morphology of bulk silica. Additionally, preliminary test to evaluate the antimicrobial properties of the solids were carried out with fungi as <i>Chaetomium globosum</i> and <i>Alternaria alternate</i>, isolated from contaminated paints, and the first results are encouraging to continue with the development of these materials. |
format |
Articulo Articulo |
author |
Arreche, Romina Andrea Hernández, María Florencia Blanco, Mirta Noemí Vázquez, Patricia Graciela |
author_facet |
Arreche, Romina Andrea Hernández, María Florencia Blanco, Mirta Noemí Vázquez, Patricia Graciela |
author_sort |
Arreche, Romina Andrea |
title |
Additive synthesis by sol-gel method for its use as antimicrobial |
title_short |
Additive synthesis by sol-gel method for its use as antimicrobial |
title_full |
Additive synthesis by sol-gel method for its use as antimicrobial |
title_fullStr |
Additive synthesis by sol-gel method for its use as antimicrobial |
title_full_unstemmed |
Additive synthesis by sol-gel method for its use as antimicrobial |
title_sort |
additive synthesis by sol-gel method for its use as antimicrobial |
publishDate |
2015 |
url |
http://sedici.unlp.edu.ar/handle/10915/104356 http://hdl.handle.net/11336/39575 |
work_keys_str_mv |
AT arrecherominaandrea additivesynthesisbysolgelmethodforitsuseasantimicrobial AT hernandezmariaflorencia additivesynthesisbysolgelmethodforitsuseasantimicrobial AT blancomirtanoemi additivesynthesisbysolgelmethodforitsuseasantimicrobial AT vazquezpatriciagraciela additivesynthesisbysolgelmethodforitsuseasantimicrobial |
bdutipo_str |
Repositorios |
_version_ |
1764820442142474242 |