Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production
The recovery of Zn and Mn from spent alkaline and Zn-C batteries with a biohydro-metallurgycal process was studied in a pilot plant that consists in an air lift bio-reactor with a sulfur packed bed where Acidithiobacillus thiooxidans produces an acid-reducing medium; a leaching reactor where the aci...
Guardado en:
| Autores principales: | , , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2014
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/104343 http://hdl.handle.net/11336/2692 |
| Aporte de: |
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I19-R120-10915-104343 |
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dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Ingeniería en Materiales Batteries Biohydrometallurgy Acidithiobacillus thiooxidans Metal recovery |
| spellingShingle |
Ingeniería en Materiales Batteries Biohydrometallurgy Acidithiobacillus thiooxidans Metal recovery Thomas, Horacio Jorge Falco, María Lorena Romina Di Nanno, María Pía Martínez, Analía Beatriz Luján Curutchet, Gustavo Andrés Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production |
| topic_facet |
Ingeniería en Materiales Batteries Biohydrometallurgy Acidithiobacillus thiooxidans Metal recovery |
| description |
The recovery of Zn and Mn from spent alkaline and Zn-C batteries with a biohydro-metallurgycal process was studied in a pilot plant that consists in an air lift bio-reactor with a sulfur packed bed where Acidithiobacillus thiooxidans produces an acid-reducing medium; a leaching reactor where the acid-reducing medium is mixed with the battery powder and a recovery reactor where metals are recovered from the leaching liquor by electroly-sis. Results shows that with a 350 mM in proton me-dium produced in 12 days by Acidithiobacillus thiooxidans in the bio-reactor, an extraction of the 100% of Zn and 67% of the Mn present in the bat-tery powder was reached. The presence of polithionates in the medium produced in the bio-reactor allows the dissolution of the manganese. The solid remaining after bioleaching is a manganese oxide. The electrolysis of the leaching liquor pro-duced a cathodic deposit of metallic Zn and an an-odic deposit of a high surphase manganese oxide in one step at room temperature. |
| format |
Articulo Articulo |
| author |
Thomas, Horacio Jorge Falco, María Lorena Romina Di Nanno, María Pía Martínez, Analía Beatriz Luján Curutchet, Gustavo Andrés |
| author_facet |
Thomas, Horacio Jorge Falco, María Lorena Romina Di Nanno, María Pía Martínez, Analía Beatriz Luján Curutchet, Gustavo Andrés |
| author_sort |
Thomas, Horacio Jorge |
| title |
Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production |
| title_short |
Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production |
| title_full |
Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production |
| title_fullStr |
Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production |
| title_full_unstemmed |
Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production |
| title_sort |
study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production |
| publishDate |
2014 |
| url |
http://sedici.unlp.edu.ar/handle/10915/104343 http://hdl.handle.net/11336/2692 |
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Repositorios |
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1764820442125697024 |