Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables
The use of soluble bio-based organic substances (SBO) obtained from urban wastes to expand the pH region where the photo-Fenton process can be applied has been investigated in this study. For this purpose, a mixture of six pollutants, namely acetaminophen, carbamazepine, amoxicillin, acetamiprid, cl...
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Autores principales: | , , , , , , , |
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Formato: | Articulo Preprint |
Lenguaje: | Inglés |
Publicado: |
2015
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Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/102273 https://ri.conicet.gov.ar/11336/11668 |
Aporte de: |
id |
I19-R120-10915-102273 |
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record_format |
dspace |
institution |
Universidad Nacional de La Plata |
institution_str |
I-19 |
repository_str |
R-120 |
collection |
SEDICI (UNLP) |
language |
Inglés |
topic |
Química Photo-Fenton Emerging pollutants pH Soluble organic matter SBO |
spellingShingle |
Química Photo-Fenton Emerging pollutants pH Soluble organic matter SBO Gomis, J. Carlos, Luciano Bianco Prevot, Alessandra Texeira, A. C. S. C. Mora, M. Amat, A. M. Vicente, R. Arques, A. Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables |
topic_facet |
Química Photo-Fenton Emerging pollutants pH Soluble organic matter SBO |
description |
The use of soluble bio-based organic substances (SBO) obtained from urban wastes to expand the pH region where the photo-Fenton process can be applied has been investigated in this study. For this purpose, a mixture of six pollutants, namely acetaminophen, carbamazepine, amoxicillin, acetamiprid, clofibric acid and caffeine, at an initial concentration of 5 mg L−1 each, has been employed. Surface response methodology, based on the Doehlert matrix, has shown to be a useful tool to determine the effect of pH (in the range 3–7), concentration of SBO (15–25 mg L−1) and iron (2–6 mg L−1) on the performance of the photodegradation of the studied pollutants, measured by their half-life. Results indicate that, at high SBO concentration, the optimum pH shifts in most cases to a higher value (between 3 and 4) and that a significant loss of efficiency of the process was only observed at pH values above 5. An iron concentration of 4–5 mg L−1 and an amount of SBO of 19–22 mg L−1 have been determined to be the optimal conditions for the degradation of most of the studied pollutants at pH = 5. |
format |
Articulo Preprint |
author |
Gomis, J. Carlos, Luciano Bianco Prevot, Alessandra Texeira, A. C. S. C. Mora, M. Amat, A. M. Vicente, R. Arques, A. |
author_facet |
Gomis, J. Carlos, Luciano Bianco Prevot, Alessandra Texeira, A. C. S. C. Mora, M. Amat, A. M. Vicente, R. Arques, A. |
author_sort |
Gomis, J. |
title |
Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables |
title_short |
Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables |
title_full |
Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables |
title_fullStr |
Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables |
title_full_unstemmed |
Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables |
title_sort |
bio-based substances from urban waste as auxiliaries for solar photo-fenton treatment under mild conditions: optimization of operational variables |
publishDate |
2015 |
url |
http://sedici.unlp.edu.ar/handle/10915/102273 https://ri.conicet.gov.ar/11336/11668 |
work_keys_str_mv |
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bdutipo_str |
Repositorios |
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1764820440929271810 |