Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables

The use of soluble bio-based organic substances (SBO) obtained from urban wastes to expand the pH region where the photo-Fenton process can be applied has been investigated in this study. For this purpose, a mixture of six pollutants, namely acetaminophen, carbamazepine, amoxicillin, acetamiprid, cl...

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Autores principales: Gomis, J., Carlos, Luciano, Bianco Prevot, Alessandra, Texeira, A. C. S. C., Mora, M., Amat, A. M., Vicente, R., Arques, A.
Formato: Articulo Preprint
Lenguaje:Inglés
Publicado: 2015
Materias:
pH
SBO
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/102273
https://ri.conicet.gov.ar/11336/11668
Aporte de:
id I19-R120-10915-102273
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Photo-Fenton
Emerging pollutants
pH
Soluble organic matter
SBO
spellingShingle Química
Photo-Fenton
Emerging pollutants
pH
Soluble organic matter
SBO
Gomis, J.
Carlos, Luciano
Bianco Prevot, Alessandra
Texeira, A. C. S. C.
Mora, M.
Amat, A. M.
Vicente, R.
Arques, A.
Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables
topic_facet Química
Photo-Fenton
Emerging pollutants
pH
Soluble organic matter
SBO
description The use of soluble bio-based organic substances (SBO) obtained from urban wastes to expand the pH region where the photo-Fenton process can be applied has been investigated in this study. For this purpose, a mixture of six pollutants, namely acetaminophen, carbamazepine, amoxicillin, acetamiprid, clofibric acid and caffeine, at an initial concentration of 5 mg L−1 each, has been employed. Surface response methodology, based on the Doehlert matrix, has shown to be a useful tool to determine the effect of pH (in the range 3–7), concentration of SBO (15–25 mg L−1) and iron (2–6 mg L−1) on the performance of the photodegradation of the studied pollutants, measured by their half-life. Results indicate that, at high SBO concentration, the optimum pH shifts in most cases to a higher value (between 3 and 4) and that a significant loss of efficiency of the process was only observed at pH values above 5. An iron concentration of 4–5 mg L−1 and an amount of SBO of 19–22 mg L−1 have been determined to be the optimal conditions for the degradation of most of the studied pollutants at pH = 5.
format Articulo
Preprint
author Gomis, J.
Carlos, Luciano
Bianco Prevot, Alessandra
Texeira, A. C. S. C.
Mora, M.
Amat, A. M.
Vicente, R.
Arques, A.
author_facet Gomis, J.
Carlos, Luciano
Bianco Prevot, Alessandra
Texeira, A. C. S. C.
Mora, M.
Amat, A. M.
Vicente, R.
Arques, A.
author_sort Gomis, J.
title Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables
title_short Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables
title_full Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables
title_fullStr Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables
title_full_unstemmed Bio-based substances from urban waste as auxiliaries for solar photo-Fenton treatment under mild conditions: optimization of operational variables
title_sort bio-based substances from urban waste as auxiliaries for solar photo-fenton treatment under mild conditions: optimization of operational variables
publishDate 2015
url http://sedici.unlp.edu.ar/handle/10915/102273
https://ri.conicet.gov.ar/11336/11668
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