Nanocomposites with shape memory behavior based on a segmented polyurethane and magnetic nanostructures

Shape-memory composites based on a commercial segmented polyurethane and magnetite (Fe⁠3O⁠4) nanoparticles(NPs) were prepared by a simple suspension casting method. The properties of the resulting nanocomposites,containing 1 to 10 nominal wt.% magnetic particles, were evaluated by thermogravimetric...

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Autores principales: Soto, Guillermo Daniel, Meiorin, Cintia, Actis, Daniel Guillermo, Mendoza Zélis, Pedro, Mosiewicki, Mirna Alejandra, Marcovich, Norma Esther
Formato: Articulo Preprint
Lenguaje:Inglés
Publicado: 2018
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/101695
https://ri.conicet.gov.ar/11336/44117
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id I19-R120-10915-101695
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Física
Polymeric nanocomposites
Shape memory behavior
Magnetic nanostructures
Indirect triggering method
spellingShingle Física
Polymeric nanocomposites
Shape memory behavior
Magnetic nanostructures
Indirect triggering method
Soto, Guillermo Daniel
Meiorin, Cintia
Actis, Daniel Guillermo
Mendoza Zélis, Pedro
Mosiewicki, Mirna Alejandra
Marcovich, Norma Esther
Nanocomposites with shape memory behavior based on a segmented polyurethane and magnetic nanostructures
topic_facet Física
Polymeric nanocomposites
Shape memory behavior
Magnetic nanostructures
Indirect triggering method
description Shape-memory composites based on a commercial segmented polyurethane and magnetite (Fe⁠3O⁠4) nanoparticles(NPs) were prepared by a simple suspension casting method. The properties of the resulting nanocomposites,containing 1 to 10 nominal wt.% magnetic particles, were evaluated by thermogravimetric tests, contact anglemeasurements, differential scanning calorimetry, infrared and X-ray spectroscopy, static and thermal cyclic tensiletests, dynamic mechanical analysis and experiments of alternating-magnetic-field heating. It was found thatmost of the suspended NPs could be successfully incorporated into the polyurethane matrix, and thus compositesamples with up to 7 wt.% actual concentration were obtained. On the other hand, the incorporation of magnetitenanoparticles to the shape memory polyurethane did not significantly affect most of the matrix properties,including its shape memory behavior, while added magnetic response to the nanocomposites. Thus, nanocompositeswere able to increase their temperature when exposed to an alternating magnetic field, which allowedthem to recover their original shape quickly by an indirect triggering method.
format Articulo
Preprint
author Soto, Guillermo Daniel
Meiorin, Cintia
Actis, Daniel Guillermo
Mendoza Zélis, Pedro
Mosiewicki, Mirna Alejandra
Marcovich, Norma Esther
author_facet Soto, Guillermo Daniel
Meiorin, Cintia
Actis, Daniel Guillermo
Mendoza Zélis, Pedro
Mosiewicki, Mirna Alejandra
Marcovich, Norma Esther
author_sort Soto, Guillermo Daniel
title Nanocomposites with shape memory behavior based on a segmented polyurethane and magnetic nanostructures
title_short Nanocomposites with shape memory behavior based on a segmented polyurethane and magnetic nanostructures
title_full Nanocomposites with shape memory behavior based on a segmented polyurethane and magnetic nanostructures
title_fullStr Nanocomposites with shape memory behavior based on a segmented polyurethane and magnetic nanostructures
title_full_unstemmed Nanocomposites with shape memory behavior based on a segmented polyurethane and magnetic nanostructures
title_sort nanocomposites with shape memory behavior based on a segmented polyurethane and magnetic nanostructures
publishDate 2018
url http://sedici.unlp.edu.ar/handle/10915/101695
https://ri.conicet.gov.ar/11336/44117
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