Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl 2.4H 2 O as an easily accessible and efficient catalyst
Methoximes are important as a class of intermediates and products, among fine chemicals and specialties. The development of a new, facile and efficient method for their synthesis is reported. The methoximes were properly accessed from the corresponding aromatic aldehydes and ketones in good to excel...
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| Autores principales: | , , , |
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| Formato: | article artículo publishedVersion |
| Lenguaje: | Inglés |
| Publicado: |
The Royal Society
2022
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| Materias: | |
| Acceso en línea: | http://hdl.handle.net/2133/23091 http://hdl.handle.net/2133/23091 |
| Aporte de: |
| Sumario: | Methoximes are important as a class of intermediates and products, among fine chemicals and specialties. The development of a new, facile and efficient method for their synthesis is reported. The methoximes were properly accessed from the corresponding aromatic aldehydes and ketones in good to excellent yields, under mild conditions, employing the inexpensive and environmentally friendly MnCl2.4H2O as a catalyst (at low loading and without the addition of ligand), in EtOH at 50°C. The scope of the process was systematically assessed. |
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