Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl 2.4H 2 O as an easily accessible and efficient catalyst

Methoximes are important as a class of intermediates and products, among fine chemicals and specialties. The development of a new, facile and efficient method for their synthesis is reported. The methoximes were properly accessed from the corresponding aromatic aldehydes and ketones in good to excel...

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Autores principales: Ontivero, Melina C., Kaufman, Teodoro Saúl, Cortés, Iván, Bracca, Andrea Beatriz Juana
Formato: article artículo publishedVersion
Lenguaje:Inglés
Publicado: The Royal Society 2022
Materias:
Eco-conscious reaction
Methoximation of aldehydes and ketones
MnCl2-catalysed transformation
Acceso en línea:http://hdl.handle.net/2133/23091
http://hdl.handle.net/2133/23091
Aporte de:
Repositorio Hipermedial de la Universidad Nacional de Rosario (UNR) de Universidad Nacional de Rosario
id I15-R121-2133-23091
record_format dspace
institution Universidad Nacional de Rosario
institution_str I-15
repository_str R-121
collection Repositorio Hipermedial de la Universidad Nacional de Rosario (UNR)
language Inglés
orig_language_str_mv eng
topic Eco-conscious reaction
Methoximation of aldehydes and ketones
MnCl2-catalysed transformation
spellingShingle Eco-conscious reaction
Methoximation of aldehydes and ketones
MnCl2-catalysed transformation
Ontivero, Melina C.
Kaufman, Teodoro Saúl
Cortés, Iván
Bracca, Andrea Beatriz Juana
Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl 2.4H 2 O as an easily accessible and efficient catalyst
topic_facet Eco-conscious reaction
Methoximation of aldehydes and ketones
MnCl2-catalysed transformation
description Methoximes are important as a class of intermediates and products, among fine chemicals and specialties. The development of a new, facile and efficient method for their synthesis is reported. The methoximes were properly accessed from the corresponding aromatic aldehydes and ketones in good to excellent yields, under mild conditions, employing the inexpensive and environmentally friendly MnCl2.4H2O as a catalyst (at low loading and without the addition of ligand), in EtOH at 50°C. The scope of the process was systematically assessed.
format article
artículo
publishedVersion
author Ontivero, Melina C.
Kaufman, Teodoro Saúl
Cortés, Iván
Bracca, Andrea Beatriz Juana
author_facet Ontivero, Melina C.
Kaufman, Teodoro Saúl
Cortés, Iván
Bracca, Andrea Beatriz Juana
author_sort Ontivero, Melina C.
title Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl 2.4H 2 O as an easily accessible and efficient catalyst
title_short Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl 2.4H 2 O as an easily accessible and efficient catalyst
title_full Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl 2.4H 2 O as an easily accessible and efficient catalyst
title_fullStr Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl 2.4H 2 O as an easily accessible and efficient catalyst
title_full_unstemmed Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl 2.4H 2 O as an easily accessible and efficient catalyst
title_sort eco-friendly methoximation of aromatic aldehydes and ketones using mncl 2.4h 2 o as an easily accessible and efficient catalyst
publisher The Royal Society
publishDate 2022
url http://hdl.handle.net/2133/23091
http://hdl.handle.net/2133/23091
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AT cortesivan ecofriendlymethoximationofaromaticaldehydesandketonesusingmncl24h2oasaneasilyaccessibleandefficientcatalyst
AT braccaandreabeatrizjuana ecofriendlymethoximationofaromaticaldehydesandketonesusingmncl24h2oasaneasilyaccessibleandefficientcatalyst
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