Chromatographic Applications in the Multi-Way Calibration Field
In this review, recent advances and applications using multi-way calibration protocols based on the processing of multi-dimensional chromatographic data are discussed. We first describe the various modes in which multi-way chromatographic data sets can be generated, including some important characte...
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Autores principales: | , , , , |
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Formato: | article artículo |
Lenguaje: | Inglés |
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MDPI
2022
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Materias: | |
Acceso en línea: | http://hdl.handle.net/2133/22992 http://hdl.handle.net/2133/22992 |
Aporte de: |
id |
I15-R121-2133-22992 |
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record_format |
dspace |
institution |
Universidad Nacional de Rosario |
institution_str |
I-15 |
repository_str |
R-121 |
collection |
Repositorio Hipermedial de la Universidad Nacional de Rosario (UNR) |
language |
Inglés |
orig_language_str_mv |
eng |
topic |
Liquid and gas chromatography Multi-way chromatographic data generation Multi-way models and calibration Analytical figures of merit |
spellingShingle |
Liquid and gas chromatography Multi-way chromatographic data generation Multi-way models and calibration Analytical figures of merit Chiappini, Fabricio A. Alcaraz, Mirta R. Escandar, Graciela Mónica Goicoechea, Héctor Casimiro Olivieri, Alejandro César Chromatographic Applications in the Multi-Way Calibration Field |
topic_facet |
Liquid and gas chromatography Multi-way chromatographic data generation Multi-way models and calibration Analytical figures of merit |
description |
In this review, recent advances and applications using multi-way calibration protocols based on the processing of multi-dimensional chromatographic data are discussed. We first describe the various modes in which multi-way chromatographic data sets can be generated, including some important characteristics that should be taken into account for the selection of an adequate data processing model. We then discuss the different manners in which the collected instrumental data can be arranged, and the most usually applied models and algorithms for the decomposition of the data arrays. The latter activity leads to the estimation of surrogate variables (scores), useful for analyte quantitation in the presence of uncalibrated interferences, achieving the second-order advantage. Recent experimental reports based on multi-way liquid and gas chromatographic data are then reviewed. Finally, analytical figures of merit that should always accompany quantitative calibration reports are described. |
format |
article artículo |
author |
Chiappini, Fabricio A. Alcaraz, Mirta R. Escandar, Graciela Mónica Goicoechea, Héctor Casimiro Olivieri, Alejandro César |
author_facet |
Chiappini, Fabricio A. Alcaraz, Mirta R. Escandar, Graciela Mónica Goicoechea, Héctor Casimiro Olivieri, Alejandro César |
author_sort |
Chiappini, Fabricio A. |
title |
Chromatographic Applications in the Multi-Way Calibration Field |
title_short |
Chromatographic Applications in the Multi-Way Calibration Field |
title_full |
Chromatographic Applications in the Multi-Way Calibration Field |
title_fullStr |
Chromatographic Applications in the Multi-Way Calibration Field |
title_full_unstemmed |
Chromatographic Applications in the Multi-Way Calibration Field |
title_sort |
chromatographic applications in the multi-way calibration field |
publisher |
MDPI |
publishDate |
2022 |
url |
http://hdl.handle.net/2133/22992 http://hdl.handle.net/2133/22992 |
work_keys_str_mv |
AT chiappinifabricioa chromatographicapplicationsinthemultiwaycalibrationfield AT alcarazmirtar chromatographicapplicationsinthemultiwaycalibrationfield AT escandargracielamonica chromatographicapplicationsinthemultiwaycalibrationfield AT goicoecheahectorcasimiro chromatographicapplicationsinthemultiwaycalibrationfield AT olivierialejandrocesar chromatographicapplicationsinthemultiwaycalibrationfield |
bdutipo_str |
Repositorios |
_version_ |
1764820411491549185 |