Excitation-emission fluorescence-kinetic data obtained by Fenton degradation. Determination of heavy-polycyclic aromatic hydrocarbons by four-way parallel factor analysis

For the first time, a simple and environmentally friendly third-order/four-way calibration was applied for the simultaneous determination of five heavy-polycyclic aromatic hydrocarbons (PAHs) in interfering environments. The kinetic evolution of the Fenton degradation of benzo[a]pyrene, dibenz[a,h]a...

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Autores principales: Carabajal, Maira Daniela, Arancibia, Juan Alberto, Escandar, Graciela Mónica
Lenguaje:Inglés
Publicado: Elsevier 2019
Materias:
Excitation-emission fluorescence matrix-kinetic data
Third-order/four-way calibration
Third-order advantage
Fenton reaction
Heavy-polycyclic aromatic hydrocarbons
Acceso en línea:http://hdl.handle.net/2133/14424
http://hdl.handle.net/2133/14424
Aporte de:
Repositorio Hipermedial de la Universidad Nacional de Rosario (UNR) de Universidad Nacional de Rosario
id I15-R121-2133-14424
record_format dspace
institution Universidad Nacional de Rosario
institution_str I-15
repository_str R-121
collection Repositorio Hipermedial de la Universidad Nacional de Rosario (UNR)
language Inglés
orig_language_str_mv eng
topic Excitation-emission fluorescence matrix-kinetic data
Third-order/four-way calibration
Third-order advantage
Fenton reaction
Heavy-polycyclic aromatic hydrocarbons
spellingShingle Excitation-emission fluorescence matrix-kinetic data
Third-order/four-way calibration
Third-order advantage
Fenton reaction
Heavy-polycyclic aromatic hydrocarbons
Carabajal, Maira Daniela
Arancibia, Juan Alberto
Escandar, Graciela Mónica
Excitation-emission fluorescence-kinetic data obtained by Fenton degradation. Determination of heavy-polycyclic aromatic hydrocarbons by four-way parallel factor analysis
topic_facet Excitation-emission fluorescence matrix-kinetic data
Third-order/four-way calibration
Third-order advantage
Fenton reaction
Heavy-polycyclic aromatic hydrocarbons
description For the first time, a simple and environmentally friendly third-order/four-way calibration was applied for the simultaneous determination of five heavy-polycyclic aromatic hydrocarbons (PAHs) in interfering environments. The kinetic evolution of the Fenton degradation of benzo[a]pyrene, dibenz[a,h]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene and benz[a]anthracene was followed by recording full excitation-emission fluorescence matrices (EEFMs) of the samples at different reaction times, obtaining third-order EEFM-kinetic (EEFM-K) data. The sensitivity of the method was increased by carrying out the reaction in the presence of methyl-β-cyclodextrin. The four-way parallel factor (PARAFAC) algorithm, which was used for data processing, exploits the second-order advantage, allowing analyte concentrations to be estimated even in the presence of an uncalibrated fluorescent background. The clear superiority of the applied approach in comparison with second-order/three-way calibration performed with unreacting EEFMs is demonstrated, using two sets of samples with foreign compounds with particular spectral profiles. In one of the latter sets, the existence of a third-order advantage was explored and discussed. The feasibility to directly determine parts-per-trillion concentration levels of PAHs after a very simple solid-phase extraction with C18 membranes is established with natural water samples containing uncalibrated constituents.
author Carabajal, Maira Daniela
Arancibia, Juan Alberto
Escandar, Graciela Mónica
author_facet Carabajal, Maira Daniela
Arancibia, Juan Alberto
Escandar, Graciela Mónica
author_sort Carabajal, Maira Daniela
title Excitation-emission fluorescence-kinetic data obtained by Fenton degradation. Determination of heavy-polycyclic aromatic hydrocarbons by four-way parallel factor analysis
title_short Excitation-emission fluorescence-kinetic data obtained by Fenton degradation. Determination of heavy-polycyclic aromatic hydrocarbons by four-way parallel factor analysis
title_full Excitation-emission fluorescence-kinetic data obtained by Fenton degradation. Determination of heavy-polycyclic aromatic hydrocarbons by four-way parallel factor analysis
title_fullStr Excitation-emission fluorescence-kinetic data obtained by Fenton degradation. Determination of heavy-polycyclic aromatic hydrocarbons by four-way parallel factor analysis
title_full_unstemmed Excitation-emission fluorescence-kinetic data obtained by Fenton degradation. Determination of heavy-polycyclic aromatic hydrocarbons by four-way parallel factor analysis
title_sort excitation-emission fluorescence-kinetic data obtained by fenton degradation. determination of heavy-polycyclic aromatic hydrocarbons by four-way parallel factor analysis
publisher Elsevier
publishDate 2019
url http://hdl.handle.net/2133/14424
http://hdl.handle.net/2133/14424
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AT arancibiajuanalberto excitationemissionfluorescencekineticdataobtainedbyfentondegradationdeterminationofheavypolycyclicaromatichydrocarbonsbyfourwayparallelfactoranalysis
AT escandargracielamonica excitationemissionfluorescencekineticdataobtainedbyfentondegradationdeterminationofheavypolycyclicaromatichydrocarbonsbyfourwayparallelfactoranalysis
bdutipo_str Repositorios
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