Discrimination of Annona muricata and Rollinia mucosa extracts by using multivariate curve resolution and partial least-squares regression of liquid chromatography-diode array data

Species of the Annonaceae family are used in traditional medicine, and several antitumor acetogenins have been isolated from the leaves of Annona muricata and Rollinia mucosa. Leaves samples (self-shaded and sun-exposed) of these species were collected during winter and summer seasons. Extraction...

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Autores principales: Afonso, Sabrina, Pisano, Pablo Luis, Silva, Fabiano, Scaminio, Ieda, Olivieri, Alejandro César
Lenguaje:Inglés
Publicado: Brazilian Chemical Society 2019
Materias:
Annona muricata
Rollinia mucosa
High-performance liquid chromatographydiode array detection
Multivariate curve resolution-alternating least-squares
Discriminant-unfolded partial least-squares
Acceso en línea:http://hdl.handle.net/2133/13920
http://hdl.handle.net/2133/13920
Aporte de:
Repositorio Hipermedial de la Universidad Nacional de Rosario (UNR) de Universidad Nacional de Rosario
id I15-R121-2133-13920
record_format dspace
institution Universidad Nacional de Rosario
institution_str I-15
repository_str R-121
collection Repositorio Hipermedial de la Universidad Nacional de Rosario (UNR)
language Inglés
orig_language_str_mv eng
topic Annona muricata
Rollinia mucosa
High-performance liquid chromatographydiode array detection
Multivariate curve resolution-alternating least-squares
Discriminant-unfolded partial least-squares
spellingShingle Annona muricata
Rollinia mucosa
High-performance liquid chromatographydiode array detection
Multivariate curve resolution-alternating least-squares
Discriminant-unfolded partial least-squares
Afonso, Sabrina
Pisano, Pablo Luis
Silva, Fabiano
Scaminio, Ieda
Olivieri, Alejandro César
Discrimination of Annona muricata and Rollinia mucosa extracts by using multivariate curve resolution and partial least-squares regression of liquid chromatography-diode array data
topic_facet Annona muricata
Rollinia mucosa
High-performance liquid chromatographydiode array detection
Multivariate curve resolution-alternating least-squares
Discriminant-unfolded partial least-squares
description Species of the Annonaceae family are used in traditional medicine, and several antitumor acetogenins have been isolated from the leaves of Annona muricata and Rollinia mucosa. Leaves samples (self-shaded and sun-exposed) of these species were collected during winter and summer seasons. Extraction media were prepared from mixtures of five solvents according to a simplex centroid design. Plant extracts were analysed by injection into a high-performance liquid chromatography with diode array detection (HPLC-DAD) and evaluated after applying by multivariate curve resolution-alternating least-squares (MCR-ALS) and discriminant-unfolded partial least-squares (D-UPLS). The objective was to check whether the chemometric resolution of chromatographic profiles could help in the discrimination of samples according to taxonomic classification, sun exposition and/or harvest season. The results indicate that extraction media containing ethanol as main solvent achieved discrimination of self-shaded versus sun-exposed plants and harvest season of Annona muricata. Also, D-UPLS analysis allowed taxonomic discrimination between Annona muricata and Rollinia mucosa extract samples.
author Afonso, Sabrina
Pisano, Pablo Luis
Silva, Fabiano
Scaminio, Ieda
Olivieri, Alejandro César
author_facet Afonso, Sabrina
Pisano, Pablo Luis
Silva, Fabiano
Scaminio, Ieda
Olivieri, Alejandro César
author_sort Afonso, Sabrina
title Discrimination of Annona muricata and Rollinia mucosa extracts by using multivariate curve resolution and partial least-squares regression of liquid chromatography-diode array data
title_short Discrimination of Annona muricata and Rollinia mucosa extracts by using multivariate curve resolution and partial least-squares regression of liquid chromatography-diode array data
title_full Discrimination of Annona muricata and Rollinia mucosa extracts by using multivariate curve resolution and partial least-squares regression of liquid chromatography-diode array data
title_fullStr Discrimination of Annona muricata and Rollinia mucosa extracts by using multivariate curve resolution and partial least-squares regression of liquid chromatography-diode array data
title_full_unstemmed Discrimination of Annona muricata and Rollinia mucosa extracts by using multivariate curve resolution and partial least-squares regression of liquid chromatography-diode array data
title_sort discrimination of annona muricata and rollinia mucosa extracts by using multivariate curve resolution and partial least-squares regression of liquid chromatography-diode array data
publisher Brazilian Chemical Society
publishDate 2019
url http://hdl.handle.net/2133/13920
http://hdl.handle.net/2133/13920
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