Synthesis of new chiral 1,3-aminoalcohols derived from levoglucosenone and their application in asymmetric alkylations

We have developed a simple procedure for the preparation of chiral 1,3-aminoalcohols using the biomass derivative levoglucosenone, as the chiral starting material. 1,3-aminoalcohols, bearing primary and tertiary amino groups, were tested as chiral catalysts in the asymmetric addition of diethyl zinc...

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Autores principales: Zanardi, María Marta, Suárez, Alejandra Graciela
Formato: article artículo publishedVersion
Lenguaje:Inglés
Publicado: Elsevier 2018
Materias:
Levoglucosenone
1,3-Aminoalcohols
Chiral ligands
Asymmetric induction
Acceso en línea:http://hdl.handle.net/2133/13535
http://hdl.handle.net/2133/13535
Aporte de:
Repositorio Hipermedial de la Universidad Nacional de Rosario (UNR) de Universidad Nacional de Rosario
id I15-R121-2133-13535
record_format dspace
institution Universidad Nacional de Rosario
institution_str I-15
repository_str R-121
collection Repositorio Hipermedial de la Universidad Nacional de Rosario (UNR)
language Inglés
topic Levoglucosenone
1,3-Aminoalcohols
Chiral ligands
Asymmetric induction
spellingShingle Levoglucosenone
1,3-Aminoalcohols
Chiral ligands
Asymmetric induction
Zanardi, María Marta
Suárez, Alejandra Graciela
Synthesis of new chiral 1,3-aminoalcohols derived from levoglucosenone and their application in asymmetric alkylations
topic_facet Levoglucosenone
1,3-Aminoalcohols
Chiral ligands
Asymmetric induction
description We have developed a simple procedure for the preparation of chiral 1,3-aminoalcohols using the biomass derivative levoglucosenone, as the chiral starting material. 1,3-aminoalcohols, bearing primary and tertiary amino groups, were tested as chiral catalysts in the asymmetric addition of diethyl zinc to benzaldehyde.
format article
artículo
publishedVersion
author Zanardi, María Marta
Suárez, Alejandra Graciela
author_facet Zanardi, María Marta
Suárez, Alejandra Graciela
author_sort Zanardi, María Marta
title Synthesis of new chiral 1,3-aminoalcohols derived from levoglucosenone and their application in asymmetric alkylations
title_short Synthesis of new chiral 1,3-aminoalcohols derived from levoglucosenone and their application in asymmetric alkylations
title_full Synthesis of new chiral 1,3-aminoalcohols derived from levoglucosenone and their application in asymmetric alkylations
title_fullStr Synthesis of new chiral 1,3-aminoalcohols derived from levoglucosenone and their application in asymmetric alkylations
title_full_unstemmed Synthesis of new chiral 1,3-aminoalcohols derived from levoglucosenone and their application in asymmetric alkylations
title_sort synthesis of new chiral 1,3-aminoalcohols derived from levoglucosenone and their application in asymmetric alkylations
publisher Elsevier
publishDate 2018
url http://hdl.handle.net/2133/13535
http://hdl.handle.net/2133/13535
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bdutipo_str Repositorios
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