Micro-spectroscopic analysis of pigments and carbonization layers on prehispanic rock art at the Oyola's caves, Argentina, using a stratigraphic approach

Samples of prehispanic rock art from Oyola's archaeological site, near the city of Catamarca, Argentina have been analyzed using micro-Raman spectroscopy, SEM-EDS and BSD, and optical microscopy. These samples are representative of diverse figures and non-painted surface of one of the caves at...

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Autores principales: Tascon, Marcos, Mastrangelo, Noemi Elisa, Gheco, Lucas Ignacio, Gastaldi, Marcos Roman, Quesada, Marcos Nicolás, Marte, Fernando Daniel
Formato: Artículo publishedVersion
Lenguaje:Inglés
Publicado: Elsevier Science 2016
Materias:
Acceso en línea:http://hdl.handle.net/11336/52418
http://suquia.ffyh.unc.edu.ar/handle/11336/52418
Aporte de:
id I10-R181-11336-52418
record_format dspace
institution Universidad Nacional de Córdoba
institution_str I-10
repository_str R-181
collection Suquía - Instituto de Antropología de Córdoba (IDACOR, CONICET y UNC)
language Inglés
topic CARBONIZATION LAYERS
MICRO-RAMAN SPECTROSCOPY
PIGMENT
ROCK ART
SCANNING ELECTRON MICROSCOPY
Arqueología
Historia y Arqueología
HUMANIDADES
spellingShingle CARBONIZATION LAYERS
MICRO-RAMAN SPECTROSCOPY
PIGMENT
ROCK ART
SCANNING ELECTRON MICROSCOPY
Arqueología
Historia y Arqueología
HUMANIDADES
Tascon, Marcos
Mastrangelo, Noemi Elisa
Gheco, Lucas Ignacio
Gastaldi, Marcos Roman
Quesada, Marcos Nicolás
Marte, Fernando Daniel
Micro-spectroscopic analysis of pigments and carbonization layers on prehispanic rock art at the Oyola's caves, Argentina, using a stratigraphic approach
topic_facet CARBONIZATION LAYERS
MICRO-RAMAN SPECTROSCOPY
PIGMENT
ROCK ART
SCANNING ELECTRON MICROSCOPY
Arqueología
Historia y Arqueología
HUMANIDADES
description Samples of prehispanic rock art from Oyola's archaeological site, near the city of Catamarca, Argentina have been analyzed using micro-Raman spectroscopy, SEM-EDS and BSD, and optical microscopy. These samples are representative of diverse figures and non-painted surface of one of the caves at the site: Oyola 7. The pigments employed in the rock art were fully characterized. The red colors are confirmed to be red ochre (hematite) and clay. White areas of the painting have been identified as gypsum whereas black pigment is attributed to graphite. In addition, it was demonstrated that all the samples analyzed, including underlying strata, contain large amounts of calcium oxalate as the mineral whewellite. Because of the distribution along the sample, it was conclude that the presence of this compound is due to biodeterioration produced by microorganisms, fungi, algae or lichens. Moreover, a methodology to differentiate black painting layers from carbon deposition layers from bonfires and to characterize them is presented. These results have a great impact in both chemical and archaeological sciences because allow an interdisciplinary approach bringing relevant information about relative and absolute dating. Finally, the information collected with this methodology establish a sound basis to develop complementary studies between the wall and painting stratigraphies with archaeological excavations resulting in a new and fundamental tool henceforth.
format Artículo
Artículo
publishedVersion
author Tascon, Marcos
Mastrangelo, Noemi Elisa
Gheco, Lucas Ignacio
Gastaldi, Marcos Roman
Quesada, Marcos Nicolás
Marte, Fernando Daniel
author_facet Tascon, Marcos
Mastrangelo, Noemi Elisa
Gheco, Lucas Ignacio
Gastaldi, Marcos Roman
Quesada, Marcos Nicolás
Marte, Fernando Daniel
author_sort Tascon, Marcos
title Micro-spectroscopic analysis of pigments and carbonization layers on prehispanic rock art at the Oyola's caves, Argentina, using a stratigraphic approach
title_short Micro-spectroscopic analysis of pigments and carbonization layers on prehispanic rock art at the Oyola's caves, Argentina, using a stratigraphic approach
title_full Micro-spectroscopic analysis of pigments and carbonization layers on prehispanic rock art at the Oyola's caves, Argentina, using a stratigraphic approach
title_fullStr Micro-spectroscopic analysis of pigments and carbonization layers on prehispanic rock art at the Oyola's caves, Argentina, using a stratigraphic approach
title_full_unstemmed Micro-spectroscopic analysis of pigments and carbonization layers on prehispanic rock art at the Oyola's caves, Argentina, using a stratigraphic approach
title_sort micro-spectroscopic analysis of pigments and carbonization layers on prehispanic rock art at the oyola's caves, argentina, using a stratigraphic approach
publisher Elsevier Science
publishDate 2016
url http://hdl.handle.net/11336/52418
http://suquia.ffyh.unc.edu.ar/handle/11336/52418
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