Combined use of gas chromatography and HPLC-ESI-Q-TOF to assess the culinary uses of archaeological Santa María style ceramic vessels from El Colorado (Catamarca, Argentina)

In this paper, an interdisciplinary investigation was carried out to study if Santa María tricolor style vessels were used as culinary equipment in a 14th century AD domestic cooking space in El Colorado (Yocavil valley, Catamarca, Northwest Argentina) and to question the long-established idea that...

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Autores principales: Lantos, Irene Johanna, Careaga Quiroga, Valeria Pilar, Palamarczuk, Valeria, Aversente, Yanina, Bonifazi, Evelyn Lucia, Petrucci, Natalia Silvana, Maier, Marta Silvia
Formato: Artículo publishedVersion
Lenguaje:Inglés
Publicado: Springer 2020
Materias:
Acceso en línea:http://hdl.handle.net/11336/137800
http://suquia.ffyh.unc.edu.ar/handle/11336/137800
Aporte de:
id I10-R181-11336-137800
record_format dspace
institution Universidad Nacional de Córdoba
institution_str I-10
repository_str R-181
collection Suquía - Instituto de Antropología de Córdoba (IDACOR, CONICET y UNC)
language Inglés
topic LIPID RESIDUES
TAGS
GAS CHROMATOGRAPHY
HPLC-ESI-Q-TOF
SANTA MARÍA CERAMICS
https://purl.org/becyt/ford/6.1
https://purl.org/becyt/ford/6
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
spellingShingle LIPID RESIDUES
TAGS
GAS CHROMATOGRAPHY
HPLC-ESI-Q-TOF
SANTA MARÍA CERAMICS
https://purl.org/becyt/ford/6.1
https://purl.org/becyt/ford/6
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Lantos, Irene Johanna
Careaga Quiroga, Valeria Pilar
Palamarczuk, Valeria
Aversente, Yanina
Bonifazi, Evelyn Lucia
Petrucci, Natalia Silvana
Maier, Marta Silvia
Combined use of gas chromatography and HPLC-ESI-Q-TOF to assess the culinary uses of archaeological Santa María style ceramic vessels from El Colorado (Catamarca, Argentina)
topic_facet LIPID RESIDUES
TAGS
GAS CHROMATOGRAPHY
HPLC-ESI-Q-TOF
SANTA MARÍA CERAMICS
https://purl.org/becyt/ford/6.1
https://purl.org/becyt/ford/6
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
description In this paper, an interdisciplinary investigation was carried out to study if Santa María tricolor style vessels were used as culinary equipment in a 14th century AD domestic cooking space in El Colorado (Yocavil valley, Catamarca, Northwest Argentina) and to question the long-established idea that Santa María vessels were exclusively funerary objects. The combined use of gas chromatography (GC-FID), gas chromatography–mass spectrometry (GC-MS), and high-performance liquid chromatography coupled to electrospray ionization and quadrupole time-of-flight mass spectrometry (HPLC-ESI-Q-TOF) to study residual lipids from Santa María style vessels provided valuable information on their ancient use. Also, an ordinary striated style ceramic pot with distinct visible soot marks, as well as sediments from the cooking area, was studied for comparative purposes. Fatty acid, sterol, and acylglyceride profiles were characterized, and markers of food sources were searched in the complex mixtures. We identified intact triacylglycerides (TAGs) in the archaeological samples, even unsaturated, indicating exceptional preservation of lipids in the ceramic matrixes. Cholesterol or cholesterol oxidation products were observed in all ceramic containers, as well as plant sterols (stigmasterol, sitosterol) in two containers. Markers for ruminant lipids, such as TAGs that contain odd-chain fatty acids, were found, supported by the identification of odd-chain and branched-chain fatty acids with GC-FID and GC-MS. This evidence contributes to the hypothesis that Santa María vessels were used for culinary purposes in this archaeological domestic cooking space
format Artículo
Artículo
publishedVersion
author Lantos, Irene Johanna
Careaga Quiroga, Valeria Pilar
Palamarczuk, Valeria
Aversente, Yanina
Bonifazi, Evelyn Lucia
Petrucci, Natalia Silvana
Maier, Marta Silvia
author_facet Lantos, Irene Johanna
Careaga Quiroga, Valeria Pilar
Palamarczuk, Valeria
Aversente, Yanina
Bonifazi, Evelyn Lucia
Petrucci, Natalia Silvana
Maier, Marta Silvia
author_sort Lantos, Irene Johanna
title Combined use of gas chromatography and HPLC-ESI-Q-TOF to assess the culinary uses of archaeological Santa María style ceramic vessels from El Colorado (Catamarca, Argentina)
title_short Combined use of gas chromatography and HPLC-ESI-Q-TOF to assess the culinary uses of archaeological Santa María style ceramic vessels from El Colorado (Catamarca, Argentina)
title_full Combined use of gas chromatography and HPLC-ESI-Q-TOF to assess the culinary uses of archaeological Santa María style ceramic vessels from El Colorado (Catamarca, Argentina)
title_fullStr Combined use of gas chromatography and HPLC-ESI-Q-TOF to assess the culinary uses of archaeological Santa María style ceramic vessels from El Colorado (Catamarca, Argentina)
title_full_unstemmed Combined use of gas chromatography and HPLC-ESI-Q-TOF to assess the culinary uses of archaeological Santa María style ceramic vessels from El Colorado (Catamarca, Argentina)
title_sort combined use of gas chromatography and hplc-esi-q-tof to assess the culinary uses of archaeological santa maría style ceramic vessels from el colorado (catamarca, argentina)
publisher Springer
publishDate 2020
url http://hdl.handle.net/11336/137800
http://suquia.ffyh.unc.edu.ar/handle/11336/137800
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