Synthesis of a new chiral bis-arsine ligand based on natural carbohydrates

Transition-metal-catalyzed asymmetric allylic substitutions have become one of the most powerful tools for asymmetric C−C bond formation.1 Chiral diphosphine ligands have been some of the largest classes of ligands used in asymmetric substitutions. Trost developed the chiral ligand, which played a...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Parajón Puenzoa, Sol C., Arata Badano, Joaquín, Lopez Vidal, Martin G., Varela, Oscar, Martín, Sandra E.
Formato: conferenceObject
Lenguaje:Inglés
Publicado: 2022
Materias:
Acceso en línea:http://hdl.handle.net/11086/29513
Aporte de:
id I10-R141-11086-29513
record_format dspace
institution Universidad Nacional de Córdoba
institution_str I-10
repository_str R-141
collection Repositorio Digital Universitario (UNC)
language Inglés
topic Asymmetric allylic substitutions
Transition-metal-catalyzed
Diphenylarsine
D-Glucosamine
spellingShingle Asymmetric allylic substitutions
Transition-metal-catalyzed
Diphenylarsine
D-Glucosamine
Parajón Puenzoa, Sol C.
Arata Badano, Joaquín
Lopez Vidal, Martin G.
Varela, Oscar
Martín, Sandra E.
Synthesis of a new chiral bis-arsine ligand based on natural carbohydrates
topic_facet Asymmetric allylic substitutions
Transition-metal-catalyzed
Diphenylarsine
D-Glucosamine
description Transition-metal-catalyzed asymmetric allylic substitutions have become one of the most powerful tools for asymmetric C−C bond formation.1 Chiral diphosphine ligands have been some of the largest classes of ligands used in asymmetric substitutions. Trost developed the chiral ligand, which played a crucial role in the improvement of Pdcatalyzed asymmetric substitutions.2 Based on the Trost modular ligand (TML) system 3 a family of ligands has been prepared. We recently reported the synthesis and application of the novel chiral bis-arsine ligand 2 derived from TML.
format conferenceObject
author Parajón Puenzoa, Sol C.
Arata Badano, Joaquín
Lopez Vidal, Martin G.
Varela, Oscar
Martín, Sandra E.
author_facet Parajón Puenzoa, Sol C.
Arata Badano, Joaquín
Lopez Vidal, Martin G.
Varela, Oscar
Martín, Sandra E.
author_sort Parajón Puenzoa, Sol C.
title Synthesis of a new chiral bis-arsine ligand based on natural carbohydrates
title_short Synthesis of a new chiral bis-arsine ligand based on natural carbohydrates
title_full Synthesis of a new chiral bis-arsine ligand based on natural carbohydrates
title_fullStr Synthesis of a new chiral bis-arsine ligand based on natural carbohydrates
title_full_unstemmed Synthesis of a new chiral bis-arsine ligand based on natural carbohydrates
title_sort synthesis of a new chiral bis-arsine ligand based on natural carbohydrates
publishDate 2022
url http://hdl.handle.net/11086/29513
work_keys_str_mv AT parajonpuenzoasolc synthesisofanewchiralbisarsineligandbasedonnaturalcarbohydrates
AT aratabadanojoaquin synthesisofanewchiralbisarsineligandbasedonnaturalcarbohydrates
AT lopezvidalmarting synthesisofanewchiralbisarsineligandbasedonnaturalcarbohydrates
AT varelaoscar synthesisofanewchiralbisarsineligandbasedonnaturalcarbohydrates
AT martinsandrae synthesisofanewchiralbisarsineligandbasedonnaturalcarbohydrates
bdutipo_str Repositorios
_version_ 1764820392259616771