The influence of temperature and the role of chromium in the passive layer in relation to pitting corrosion of 316 stainless steel in NaCl solution
The electrochemical behaviour of 316 stainless steel was studied in nearly neutral electrolytes containing NaCl in the - 3 to 50°C temperature range, using potentiostatic and potentiodynamic techniques. Special attention was paid to both the current fluctuations previous to the irreversible breakdow...
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1986
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 05591caa a22006497a 4500 | ||
|---|---|---|---|
| 001 | PAPER-958 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203018.0 | ||
| 008 | 190411s1986 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0022790110 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a ELCAA | ||
| 100 | 1 | |a Pallotta, C. | |
| 245 | 1 | 4 | |a The influence of temperature and the role of chromium in the passive layer in relation to pitting corrosion of 316 stainless steel in NaCl solution |
| 260 | |c 1986 | ||
| 270 | 1 | 0 | |m Pallotta, C. |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Galvele, (1978) Passivity of Metals, p. 285. , R.P. Frankental, J. Kruger, The Electrochem. Soc, Princeton, New Jersey | ||
| 504 | |a Bertocci, Yeng-Xiang, (1984) J. electrochem. Soc., 131, p. 1011 | ||
| 504 | |a M. Keddam, M. Krarti and C. Pallotta, submitted to Corrosion; Daufin, Pagetti, Labbe, Flaichel, (1985) Corrosion, 41, p. 533 | ||
| 504 | |a Murphy, Pou, Bockris, (1984) J. electrochem. Soc., 131, p. 2785 | ||
| 504 | |a Murphy, Bockris, Pou, (1983) J. electrochem. Soc., 130, p. 1792 | ||
| 504 | |a MacDougall, Graham, (1984) J. electrochem. Soc., 131, p. 727 | ||
| 504 | |a Heusler, Fischer, (1976) Werks. und Korr., 27, p. 551 | ||
| 504 | |a Szlarska-Smialovska, (1974) Localized Corrosion, p. 312. , Nace, Houston, Texas | ||
| 504 | |a Leckie, Uhlig, Environmental Factors Affecting the Critical Potential for Pitting in 18–8 Stainless Steel (1966) Journal of The Electrochemical Society, 113, p. 1261 | ||
| 504 | |a Forchhammer, Engell, Untersuchungen �ber den Lochfra� an passiven austenitischen Chrom-Nickel-St�hlen in neutralen Chloridl�sungen (1969) Materials and Corrosion/Werkstoffe und Korrosion, 20, p. 1 | ||
| 504 | |a Ord, Desmet, (1966) J. electrochem. Soc., 113, p. 1253 | ||
| 504 | |a J. Zerbino, J. R. Vilche and A. J. Arvia, Electrochim. Acta, in press; Ramasubramanian, Preocanin, Davison, (1985) J. electrochem. Soc., 132, p. 793 | ||
| 504 | |a Semino, Galvele, (1976) Corros. Sci., 16, p. 297 | ||
| 504 | |a Salvarezza, Videla, (1980) Corrosion, 36, p. 550 | ||
| 504 | |a Moll, Salvarezza, Videla, Arvia, The Pitting Corrosion of Nickel in Different Electrolyte Solutions Containing Chloride Ions (1985) Journal of The Electrochemical Society, 132, p. 754 | ||
| 504 | |a Saito, Shibata, Okamoto, (1979) Corros. Sci., p. 693 | ||
| 504 | |a Okamoto, (1973) Corros. Sci., 13, p. 471 | ||
| 504 | |a Tjong, Hoffman, Yeager, (1982) J. electrochem. Soc., 129, p. 1662 | ||
| 504 | |a E. Calvo and C. Pallotta, J. electroanal. Chem., in press; McCafferty, Murday, Bernett, (1985) Extended Abstracts of the 168 Electrochemical Society Meeting, Las Vegas, Nevada, 85–82, p. 245 | ||
| 520 | 3 | |a The electrochemical behaviour of 316 stainless steel was studied in nearly neutral electrolytes containing NaCl in the - 3 to 50°C temperature range, using potentiostatic and potentiodynamic techniques. Special attention was paid to both the current fluctuations previous to the irreversible breakdown of the passive film and to the breakdown potential. No pitting was observed at temperature lower than 0°C. In the 0-15°C range the breakdown potential shifts slightly in the negative direction. Between 15 and 25°C a remarkable decrease in the breakdown potential was observed whereas in the 25-50°C range it remained practically constant. The temperature dependence of the breakdown potential correlates closely with the temperature dependence of the Cr(III) to soluble Cr(VI) electrooxidation current. This suggests that the depletion of Cr(III) and surrounding water with increasing temperature decreases the capability of self-repair of the passive film. Conversely, the increase in temperature produces a thicker and more crystalline passive film which becomes more resistant to breakdown. As this effect is counterbalanced by the depletion of Cr(III) in the passive layer the breakdown potential in the 25-50°C range remains practically constant. © 1986. |l eng | |
| 593 | |a Facultad de Ciencias Exactas y Naturales, Departamento de Química Inorgánica, Analítica y Química Fisica, Ciudad Universitaria Pabellón II, 1428 Buenos Aires, Argentina | ||
| 593 | |a Instituto Nacional de Tecnología Industrial-INTI, Sector Electroquímica Aplicada, C.C. 157, (1650) San Martin, Argentina | ||
| 593 | |a Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas-INIFTA, Casilla de Correo 16, Sucursal 4, 1900 La Plata, Argentina | ||
| 690 | 1 | 0 | |a CHROMIUM PLATING |
| 690 | 1 | 0 | |a ELECTROCHEMISTRY |
| 690 | 1 | 0 | |a STEEL CORROSION - PITTING |
| 690 | 1 | 0 | |a PASSIVE LAYERS |
| 690 | 1 | 0 | |a STAINLESS STEEL |
| 700 | 1 | |a De Cristofano, N. | |
| 700 | 1 | |a Salvarezza, R.C. | |
| 700 | 1 | |a Arvia, A.J. | |
| 773 | 0 | |d 1986 |g v. 31 |h pp. 1265-1270 |k n. 10 |p Electrochim Acta |x 00134686 |w (AR-BaUEN)CENRE-12 |t Electrochimica Acta | |
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| 856 | 4 | 0 | |u https://doi.org/10.1016/0013-4686(86)80146-3 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00134686_v31_n10_p1265_Pallotta |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134686_v31_n10_p1265_Pallotta |y Registro en la Biblioteca Digital |
| 961 | |a paper_00134686_v31_n10_p1265_Pallotta |b paper |c PE | ||
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| 963 | |a VARI | ||
| 999 | |c 61911 | ||