Aminopropyl-modified mesoporous silica SBA-15 as recovery agents of Cu(II)-sulfate solutions: Adsorption efficiency, functional stability and reusability aspects
Hybrid mesoporous materials are potentially useful for metal ion scavenging and retrieval because of their high surface areas, controlled accessibility and tailored functionalization. Some aspects that are linked to the performance of HMM include pore accessibility, stability of the organic function...
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2012
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| LEADER | 16748caa a22019457a 4500 | ||
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| 001 | PAPER-9477 | ||
| 003 | AR-BaUEN | ||
| 005 | 20250908092602.0 | ||
| 008 | 190411s2012 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-84861457320 | |
| 024 | 7 | |2 cas |a copper sulfate, 7758-98-7, 7758-99-8; silicon dioxide, 10279-57-9, 14464-46-1, 14808-60-7, 15468-32-3, 60676-86-0, 7631-86-9; Copper Sulfate, 7758-98-7; Propylamines; SBA-15; Silicon Dioxide, 7631-86-9; Water Pollutants, Chemical | |
| 030 | |a JHMAD | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Lombardo, M.V. | |
| 245 | 1 | 0 | |a Aminopropyl-modified mesoporous silica SBA-15 as recovery agents of Cu(II)-sulfate solutions: Adsorption efficiency, functional stability and reusability aspects |
| 260 | |c 2012 | ||
| 270 | 1 | 0 | |m Soler-Illia, G.J.A.A.; Gerencia Química, Centro Atómico Constituyentes, CNEA, Av. General Paz 1499, B1650KNA, San Martín, Buenos Aires, Argentina; email: gsoler@cnea.gov.ar |
| 504 | |a Aguado, J., Arsuaga, J.M., Arencibia, A., Lindo, M., Gascón, V., Aqueous heavy metals removal by adsorption on amine-functionalized mesoporous silica (2009) J. Hazard. Mater., 163, pp. 213-221 | ||
| 504 | |a Babel, S., Kurniawan, T.A., Low-cost adsorbents for heavy metals uptake from contaminated water: a review (2003) J. Hazard. Mater., 97, pp. 219-243 | ||
| 504 | |a (2010) J. Mater. Chem., 20, pp. 4476ss. , See e.g. the themed issue on "Advanced Materials in Water Treatments" | ||
| 504 | |a Sayari, A., Hamoudi, S., Periodic mesoporous silica-based organic-inorganic nanocomposite materials (2001) Chem. Mater., 13, pp. 3151-3168 | ||
| 504 | |a Hoffmann, F., Cornelius, M., Morell, J., Fröba, M., Silica-based mesoporous organic-inorganic hybrid materials (2006) Angew. Chem. Int. Ed, 45, pp. 3216-3251 | ||
| 504 | |a Walcarius, A., Mercier, L., Mesoporous organosilica adsorbents: nanoengineered materials for removal of organic and inorganic pollutants (2010) J. Mater. Chem., 20, pp. 4478-4511 | ||
| 504 | |a Zhao, D., Feng, J., Huo, Q., Melosh, N., Fredrickson, G.H., Chmelka, B.F., Stucky, G.D., Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 Angstrom pores (1998) Science, 279, pp. 548-552 | ||
| 504 | |a Zhao, D., Huo, Q., Feng, J., Chmelka, B.F., Stucky, G.D., Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures (1998) J. Am. Chem. Soc., 120, pp. 6024-6036 | ||
| 504 | |a Soler-Illia, G.J.A.A., Sanchez, C., Lebeau, B., Patarin, J., Chemical strategies to design textured materials: from microporous and mesoporous oxides to nanonetworks and hierarchical structures (2002) Chem. Rev., 102, pp. 4093-4138 | ||
| 504 | |a Yoshitake, H., Design of functionalization and structural analysis of organically-modified siliceous oxides with periodic structures for the development of sorbents for hazardous substances (2010) J. Mater. Chem., 20, pp. 4537-4550 | ||
| 504 | |a Liu, J., Feng, X., Fryxell, G.E., Wang, L.-Q., Kim, A.Y., Gong, M., Hybrid mesoporous materials with functionalized monolayers (1998) Adv. Mater., 10, pp. 161-165 | ||
| 504 | |a Soler-Illia, G.J.A.A., Innocenzi, P., Mesoporous hybrid thin films: the physics and chemistry beneath (2006) Chem. Eur. J., 12, pp. 4478-4494 | ||
| 504 | |a Wu, Z., Zhao, D.Y., Ordered mesoporous materials as adsorbents (2011) Chem. Commun., 47, pp. 3332-3338 | ||
| 504 | |a Olkhovyk, O., Jaroniec, M., Chemically-modified mesoporous silicas and organosilicas for adsorption and detection of heavy metal ions (2007) Environmental Applications of Nanomaterials: Synthesis, Sorbents and Sensors, pp. 179-212. , Imperial College Press, London, (Chapter 8), G.E. Fryxell, G. Cao (Eds.) | ||
| 504 | |a Brühwiler, D., Postsynthetic functionalization of mesoporous silica (2010) Nanoscale, 2, pp. 887-892 | ||
| 504 | |a Chen, X., Lam, K.F., Zhang, Q., Pan, B., Arruebo, M., Yeung, K.L., Synthesis of highly selective magnetic mesoporous adsorbent (2009) J. Phys. Chem. C, 113, pp. 9804-9813 | ||
| 504 | |a Lui, M., Hidajat, K., Kawi, S., Zhao, D.Y., A new class of hybrid mesoporous materials with functionalized organic monolayers for selective adsorption of heavy metal ions (2000) Chem. Commun., pp. 1145-1146 | ||
| 504 | |a Lam, K.F., Yeung, K.L., McKay, G., A rational approach in the design of selective mesoporous adsorbents (2006) Langmuir, 22, pp. 9632-9641 | ||
| 504 | |a Ghoul, M., Bacquet, M., Morcellet, M., Uptake of heavy metals from synthetic aqueous solution using modified PEI-silica gels (2003) Water Res., 37, pp. 729-734 | ||
| 504 | |a Etienne, M., Walcarius, A., Analytical investigation of the chemical reactivity and stability of aminopropyl-grafted silica in aqueous medium (2003) Talanta, 59, pp. 1173-1188 | ||
| 504 | |a Da'na, E., Sayari, A., Adsorption of heavy metals on amine-functionalized SBA-15 prepared by co-condensation: applications to real water samples (2012) Desalination, 285, pp. 62-67 | ||
| 504 | |a Fryxell, G.E., The synthesis of functional mesoporous materials (2006) Inorg. Chem. Commun., 9, pp. 1141-1150 | ||
| 504 | |a Shi, J.L., Hua, Z.L., Zhang, L.X., Nanocomposites from ordered mesoporous materials (2004) J. Mater. Chem., 14, pp. 795-806 | ||
| 504 | |a Soler-Illia, G.J.A.A., Azzaroni, O., Multifunctional hybrids by combining ordered mesoporous materials and macromolecular building blocks (2011) Chem. Soc. Rev., 40, pp. 1107-1150 | ||
| 504 | |a http://www.esrf.eu/computing/scientific/FIT2D/aftp_fit2d.html, Software obtained from the following link:; Thommes, M., Köhn, R., Fröba, M., Sorption and pore condensation behavior of pure fluids in mesoporous MCM-48 silica, MCM-41 silica, SBA-15 silica and controlled-pore glass at temperatures above and below the bulk triple point (2002) Appl. Surf. Sci., 196, pp. 239-249 | ||
| 504 | |a Benhamou, A., Baudu, M., Derriche, Z., Basly, J.P., Aqueous heavy metals removal on amine-functionalized Si-MCM-41 and Si-MCM-48 (2009) J. Hazard. Mater., 171, pp. 1001-1008 | ||
| 504 | |a Da'na, E., De Silva, N., Sayari, A., Adsorption of copper on amine-functionalized SBA-15 prepared by co-condensation: kinetics properties (2011) Chem. Eng. J., 166, pp. 454-459 | ||
| 504 | |a Burke, A.M., Hanrahan, J.P., Healy, D.A., Sodeau, J.R., Holmes, J.D., Morris, M.A., Large pore bi-functionalised mesoporous silica for metal ion pollution treatment (2009) J. Hazard. Mater., 164, pp. 229-234 | ||
| 504 | |a Lowell, S., (2004) Characterization of Porous Solids and Powders: Surface Area, Pore Size, and Density, p. 120. , Springer | ||
| 504 | |a Innocenzi, P., Infrared spectroscopy of sol-gel derived silica-based films: a spectra-microstructure overview (2003) J. Non-Cryst. Solids, 316, pp. 309-319 | ||
| 504 | |a Socrates, G., (2001) Infrared Characteristic Group Frequencies, , John Wiley and Sons, Chichester | ||
| 504 | |a Brunel, D., Blanc, A.C., Garrone, E., Onida, B., Rocchia, M., Nagy, J.B., Macquarrie, D.J., Spectroscopic studies on aminopropyl-containing micelle templated silicas. Comparison of grafted and co-condensation routes (2002) Stud. Surf. Sci. Catal., 142, pp. 1395-1402 | ||
| 504 | |a Zhmud, B.V., Sonnefeld, J., Aminopolysiloxane gels: production and properties (1996) J. Non-Cryst. Solids, 195, pp. 16-27 | ||
| 504 | |a Calvo, A., Joselevich, M., Soler-Illia, G.J.A.A., Williams, F.J., Chemical reactivity of amino-functionalized mesoporous silica thin films obtained by co-condensation and post-grafting routes (2009) Microporous Mesoporous Mater., 121, p. 67 | ||
| 504 | |a Caravajal, G.S., Leyden, D.E., Quinting, G.R., Maciel, G.E., Structural characterization of (3-aminopropyl)triethoxysilane-modified silicas by silicon-29 and carbon-13 nuclear magnetic resonance (1988) Anal. Chem., 60, pp. 1776-1786 | ||
| 504 | |a Lam, K.F., Chen, X., McKay, G., Yeung, K.L., Anion effect on Cu 2+ adsorption on NH2-MCM-41 (2008) Ind. Eng. Chem. Res., 47, pp. 9376-9383 | ||
| 504 | |a Da'na, E., Sayari, A., Adsorption of copper on amine-functionalized SBA-15 prepared by co-condensation: equilibrium properties (2011) Chem. Eng. J., 166, pp. 445-453 | ||
| 504 | |a Fryxell, G.E., (2007) Environmental Applications of Nanomaterials. Synthesis, Sorbents and Sensors, p. 167. , Imperial College Press, London, G.E. Fryxell, G. Cao (Eds.) | ||
| 504 | |a Ho, Y.-S., Review of second-order models for adsorption systems (2006) J. Hazard. Mater., B136, pp. 681-689 | ||
| 504 | |a Edgell, M.J., Baer, D.R., Castle, J.E., Biased referencing experiments for the XPS analysis of non-conducting materials (1986) Appl. Surf. Sci., 26, pp. 129-149 | ||
| 504 | |a Calvo, A., Angelomé, P.C., Sanchez, V.M., Scherlis, D., Williams, F.J., Soler-Illia, G.J.A.A., Mesoporous aminopropyl-functionalized hybrid thin films with modulable surface and environment-responsive behavior (2008) Chem. Mater., 20, pp. 4661-4668 | ||
| 504 | |a Chusuei, C.C., Brookshier, M.A., Goodman, D.W., Correlation of relative XPS shakeup intensity with CuO particle size (1999) Langmuir, 15, pp. 2806-2808 | ||
| 504 | |a Lim, M.H., Stein, A., Comparative studies of grafting and direct syntheses of inorganic-organic hybrid mesoporous materials (1999) Chem. Mater., 11, pp. 3285-3295 | ||
| 504 | |a Angelomé, P.C., Soler-Illia, G.J.A.A., Organically modified transition-metal oxide mesoporous thin films and xerogels (2005) Chem. Mater., 17, pp. 322-331 | ||
| 504 | |a Wang, H., Harris, J.M., Surface diffusion of organosiloxane ligands covalently bound to silica (1994) J. Am. Chem. Soc., 116, pp. 5754-5761 | ||
| 504 | |a Kudryavtsev, G.V., Miltchenko, D.V., Yagov, V.V., Lopatkin, A.A., Ion sorption on modified silica surface (1990) J. Colloid Interface Sci., 140, pp. 114-122 | ||
| 504 | |a Da'na, E., Sayari, A., Effect of regeneration conditions on the cyclic performance of amine-modified SBA-15 for removal of copper from aqueous solutions: composite surface design methodology (2011) Desalination, 277, pp. 54-60 | ||
| 504 | |a Boissière, C., Martines, M.U., Prouzet, E., Larbot, A., On the specific filtration mechanism of a mesoporous silica membrane, prepared with non-connecting parallel pores (2005) J. Membr. Sci., 251, pp. 17-28 | ||
| 504 | |a Boissière, C., Martines, M.A.U., Kooyman, P.J., de Kruijff, T.R., Larbot, A., Prouzet, E., Ultrafiltration membrane made with mesoporous MSU-X silica (2003) Chem. Mater., 15, pp. 460-463 | ||
| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a Hybrid mesoporous materials are potentially useful for metal ion scavenging and retrieval because of their high surface areas, controlled accessibility and tailored functionalization. Some aspects that are linked to the performance of HMM include pore accessibility, stability of the organic functions and reusability. Knowledge of these aspects is critical in the design of adsorption-desorption protocols. In this work we produce and characterize propylamino-substituted large pore silica (SBA-15-N), which is submitted to Cu(II) adsorption from copper sulfate solutions, followed by desorption in acid media and material regeneration. We find that the hybrid material is an efficient adsorbent (1.15-1.75mmolCu(II)g -1), although a fraction of the organic groups is lost during the adsorption process. An X-ray photoelectron spectroscopy (XPS) study demonstrates that the contents of amino groups are higher in the material surface, leading to different behaviors in Cu(II) complexation along the material. These materials can be regenerated by exposure to acidic media. Thermal processing of the hybrid materials leads to better durability in aqueous solutions during reprocessing, due to enhanced polycondensation of the inorganic framework. Thermally treated samples, once regenerated, are efficient adsorbents in a second step of Cu(II) adsorption. We discuss the materials processing factors involved in the improved adsorption of Cu(II), its quantitative release and reusability of the material. © 2012 Elsevier B.V. |l eng | |
| 536 | |a Detalles de la financiación: FSNANO 2010/007 | ||
| 536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, PME 00038, PAE 2004 22711, PICT 1848 | ||
| 536 | |a Detalles de la financiación: Authors thank ABTLUS for funding access to the LNLS synchrotron facility (proposals D11A-SAXS1-11060 and D04A-SXS-10808). Work funded by ANPCyT (grants PICT 1848 , PAE 2004 22711 , PME 00038 , FONARSEC FSNANO 2010/007 ). VL thanks CONICET and Rhein Chemie Argentina for a graduate student fellowship. GJAASI is a CONICET staff researcher. Authors thank Dr. M.C. Marchi for her assistance in electronic microscopy measurements, and Drs. H. Westfahl and M. Cardoso for their assistance in SAXS. Appendix A | ||
| 593 | |a Gerencia Química, Centro Atómico Constituyentes, CNEA, Av. General Paz 1499, B1650KNA, San Martín, Buenos Aires, Argentina | ||
| 593 | |a Rhein Chemie Argentina, Luis María Drago 1555, B1852LGS Burzaco, Buenos Aires, Argentina | ||
| 593 | |a INIFTA-CONICET, Universidad Nacional de La Plata, CC 16 Sucursal 4, 1900, La Plata, Argentina | ||
| 593 | |a DQIAyQF, FCEN, Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, C1428EHA, Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a AMINOPROPYL FUNCTION |
| 690 | 1 | 0 | |a HYBRID ADSORBENTS |
| 690 | 1 | 0 | |a ION SCAVENGING |
| 690 | 1 | 0 | |a MESOPOROUS MATERIALS |
| 690 | 1 | 0 | |a REUSABLE ADSORBENT |
| 690 | 1 | 0 | |a SOL-GEL |
| 690 | 1 | 0 | |a WATER TREATMENT |
| 690 | 1 | 0 | |a ACID MEDIA |
| 690 | 1 | 0 | |a ACIDIC MEDIA |
| 690 | 1 | 0 | |a ADSORPTION DESORPTION |
| 690 | 1 | 0 | |a ADSORPTION EFFICIENCY |
| 690 | 1 | 0 | |a ADSORPTION PROCESS |
| 690 | 1 | 0 | |a AMINO GROUP |
| 690 | 1 | 0 | |a AMINOPROPYL |
| 690 | 1 | 0 | |a COPPER SULFATE |
| 690 | 1 | 0 | |a CU ADSORPTION |
| 690 | 1 | 0 | |a FUNCTIONALIZATIONS |
| 690 | 1 | 0 | |a HIGH SURFACE AREA |
| 690 | 1 | 0 | |a HYBRID ADSORBENTS |
| 690 | 1 | 0 | |a LARGE PORES |
| 690 | 1 | 0 | |a MATERIAL SURFACE |
| 690 | 1 | 0 | |a MATERIALS PROCESSING |
| 690 | 1 | 0 | |a MESOPOROUS SILICA |
| 690 | 1 | 0 | |a ORGANIC FUNCTION |
| 690 | 1 | 0 | |a ORGANIC GROUP |
| 690 | 1 | 0 | |a SULFATE SOLUTIONS |
| 690 | 1 | 0 | |a X-RAY PHOTOELECTRON SPECTROSCOPY STUDIES |
| 690 | 1 | 0 | |a ADSORBENTS |
| 690 | 1 | 0 | |a ADSORPTION |
| 690 | 1 | 0 | |a DESORPTION |
| 690 | 1 | 0 | |a HYBRID MATERIALS |
| 690 | 1 | 0 | |a MATERIALS PROPERTIES |
| 690 | 1 | 0 | |a METAL IONS |
| 690 | 1 | 0 | |a PHOTOELECTRONS |
| 690 | 1 | 0 | |a POLYCONDENSATION |
| 690 | 1 | 0 | |a REUSABILITY |
| 690 | 1 | 0 | |a SILICA |
| 690 | 1 | 0 | |a SOL-GELS |
| 690 | 1 | 0 | |a WATER TREATMENT |
| 690 | 1 | 0 | |a X RAY PHOTOELECTRON SPECTROSCOPY |
| 690 | 1 | 0 | |a MESOPOROUS MATERIALS |
| 690 | 1 | 0 | |a COPPER SULFATE |
| 690 | 1 | 0 | |a SBA 15 N |
| 690 | 1 | 0 | |a SILICON DIOXIDE |
| 690 | 1 | 0 | |a UNCLASSIFIED DRUG |
| 690 | 1 | 0 | |a ADSORPTION |
| 690 | 1 | 0 | |a CATION |
| 690 | 1 | 0 | |a COMPLEXATION |
| 690 | 1 | 0 | |a COPPER COMPOUND |
| 690 | 1 | 0 | |a DESORPTION |
| 690 | 1 | 0 | |a RECYCLING |
| 690 | 1 | 0 | |a SCAVENGING (CHEMISTRY) |
| 690 | 1 | 0 | |a SILICA |
| 690 | 1 | 0 | |a SULFATE |
| 690 | 1 | 0 | |a WASTEWATER |
| 690 | 1 | 0 | |a WATER TREATMENT |
| 690 | 1 | 0 | |a X-RAY SPECTROSCOPY |
| 690 | 1 | 0 | |a ADSORPTION |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a COMPLEX FORMATION |
| 690 | 1 | 0 | |a MOLECULAR STABILITY |
| 690 | 1 | 0 | |a POLYMERIZATION |
| 690 | 1 | 0 | |a POROSITY |
| 690 | 1 | 0 | |a SUBSTITUTION REACTION |
| 690 | 1 | 0 | |a SYNTHESIS |
| 690 | 1 | 0 | |a X RAY PHOTOELECTRON SPECTROSCOPY |
| 690 | 1 | 0 | |a ADSORPTION |
| 690 | 1 | 0 | |a COPPER SULFATE |
| 690 | 1 | 0 | |a MICROSCOPY, ELECTRON, SCANNING |
| 690 | 1 | 0 | |a PHOTOELECTRON SPECTROSCOPY |
| 690 | 1 | 0 | |a POROSITY |
| 690 | 1 | 0 | |a PROPYLAMINES |
| 690 | 1 | 0 | |a RECYCLING |
| 690 | 1 | 0 | |a SILICON DIOXIDE |
| 690 | 1 | 0 | |a SPECTROSCOPY, FOURIER TRANSFORM INFRARED |
| 690 | 1 | 0 | |a SURFACE PROPERTIES |
| 690 | 1 | 0 | |a WATER POLLUTANTS, CHEMICAL |
| 690 | 1 | 0 | |a WATER PURIFICATION |
| 700 | 1 | |a Videla, M. | |
| 700 | 1 | |a Calvo, A. | |
| 700 | 1 | |a Requejo, Félix Gregorio | |
| 700 | 1 | |a Soler-Illia, G.J.A.A. | |
| 773 | 0 | |d 2012 |g v. 223-224 |h pp. 53-62 |p J. Hazard. Mater. |x 03043894 |w (AR-BaUEN)CENRE-5603 |t Journal of Hazardous Materials | |
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