Porphyrin biosynthesis in Rhodopseudomonas palustris-XI. Extraction and characterization of δ-aminolevulinate synthetase

1. 1. Although the levels of ALA-S in photosynthetic (Ph) are higher than in aerobic (A) cells, physical and kinetic properties are similar. Optimum reaction pH is 7.5; maximal product formation occurs at 37°C. 2. 2. The enzyme has an absolute requirement for glycine. The addition of cysteine (CySH)...

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Autor principal: Viale, A.A
Otros Autores: Wider, E.A, Del C. Batlle, A.M
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1987
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
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100 1 |a Viale, A.A. 
245 1 0 |a Porphyrin biosynthesis in Rhodopseudomonas palustris-XI. Extraction and characterization of δ-aminolevulinate synthetase 
260 |c 1987 
270 1 0 |m Viale, A.A. 
506 |2 openaire  |e Política editorial 
504 |a Algranati, Determination of initial rates in enzymic non-linear progress reactions (1963) Biochimica et Biophysica Acta (BBA) - Specialized Section on Enzymological Subjects, 73, pp. 152-155 
504 |a Bottomley, Smithee, Characterization and measurement of δ-amino laevulinate synthetase in bone marrow cell mitochondria (1968) Biochim. biophys. Acta, 159, pp. 27-37 
504 |a Dzelzkalns, Foley, Beale, δ-Aminolevulinic acid synthase of Euglena gracilis physical and kinetic properties (1982) Archives of Biochemistry and Biophysics, 21 b, pp. 196-203 
504 |a Ebert, Tschudy, Choudry, Chirigos, A simple micromethod for the direct determination of δ-amino [14C]levulinic acid production in murine spleen and liver homogenates (1970) Biochim. biophys. Acta, 208, pp. 236-250 
504 |a Elliot, The estimation of aminoacetone and δ-amino levulinic acid (1960) Biochem. J., 74, pp. 90-94 
504 |a Fanica-Gaignier, Clement-Metral, 5-Aminolevulinic acid synthetase of Rhodopseudomonas sphaeroides Y (1973) Purification and some properties, 40, pp. 13-18. , Eur. J. Biochem 
504 |a Harel, Meler, Rosenberg, Synthesis of 5-amino-levulinic acid-[14C] by cell-free preparations from greening maize leaves (1978) Phytochemistry, 17, pp. 1277-1280 
504 |a Juknat, Kotler, Batlle, (1987) Porphyrin biosynthesis in Rhodopseudomonas palustris—IV. Enzymic cyclotetramerization of porphobilinogen into uroporphyrimogens, , In preparation 
504 |a Koopmann, Batlle, Porphyrin biosynthesis in Rhodopseudomonas palustris—VI The effect of metals and various other reagents on uroporphyrinogen decarboxylase activity (1987) Int J Biochem, , in press 
504 |a Koopmann, Juknat, Batlle, (1987) Porphyrin biosynthesis in Rhodopseudomonas palustris—III. Evidence for aerobic and anaerobic coproporphyrinogenase activities, , In preparation 
504 |a Koopmann, Juknat, Batlle, Porphyrin biosynthesis in Rhodopseudomonas palustris—V. Purification of porphyrinogen decarboxylase and some unusual properties (1987) Int. J. Biochem., 18, pp. 935-944 
504 |a Kotler, Fumagalli, Juknat, Batlle, Porphyrin biosynthesis in Rhodopseudomonas palustris—VIII (1987) Purification and properties of deaminase, , Comp. Biochem. Physiol., Part B, in press 
504 |a Kotler, Fumagalli, Juknat, Batlle, Porphyrin biosynthesis in Rhodopseudomonas palustris—IX. Deaminase: kinetic studies (1987) Int. J. Biochem., , in press 
504 |a Marriot, Neuberger, Tait, Control of δ-aminolaevulinate synthetase activity in Rhodopseudomonas sphaeroides (1969) Biochem. J., 111, pp. 385-394 
504 |a Mauzerall, Granick, The occurence and determination of δ-aminolevulinic acid and porphobilinogen in urine (1955) J. biol. Chem., 219, pp. 435-446 
504 |a Tait, Aminolaevulinate synthetase of Paracoccus denitrificans (1972) Biochem J, 128, p. 32P 
504 |a Tait, Aminolaevulinate synthetase of Micrococcus denitrificans (1973) Biochem. J., 131, pp. 389-403 
504 |a Tuboi, Hayasaka, Control of δ-aminolevulinate synthetase activity in Rhodopseudomonoas sphaeroides—II. Requirement of a disulfide compound for the conversion of the inactive form of fraction I to the active form (1972) Archs Biochem. Biophys., 150, pp. 690-697 
504 |a Tuboi, Kim, Kikuchi, Occurence of a specific and reversible inhibitor of δ-aminolevulinate synthetase in extracts of Rhodopseudomonas sphaeroides (1969) Archs Biochem. Biophys., 130, pp. 92-100 
504 |a Vazquez, Buzaleh, Wider, Batlle, Rhodanese isolation purification and some properties (1987) Int J Biochem, , submitted 
504 |a Vazquez, Buzaleh, Wider, Batlle, Soluble and immobilized rhodanese—optimal conditions (1987) Eur. J. Biochem., , submitted for publication 
504 |a Viale, Wider, Batlle, Biosintesis de bacterioclorofile en Rhodopseudomonas palustris (1980) Rev. Arg. Microbiol., 12, pp. 1-9 
504 |a Viale, Wider, Batlle, Porphyrin biosynthesis in Rhodopseudomonas palustris—II. Evidence on the existence of a factor regulating aminolevulinate synthetase activity (1980) Int. J. Biochem., 12, pp. 729-733 
504 |a Viale, Wider, Batlle, Biosynthesis of porphyrins in Rhodopseudomonas palustris—XI δ-Amino levulinate synthetase switch-off/on regulation (1987) Int J Biochem, , in press 
504 |a Wider, Batlle, Tigier, δ-Aminolevulinate synthetase in extracts of cultured soybean cells (1971) Biochimica et Biophysica Acta (BBA) - Enzymology, 235, pp. 511-517 
504 |a Yubisui, Yoneyama, δ-Aminolevulinic acid synthetase of Rhodopseudomonas sphaeroides: purification and properties of the enzyme (1972) Archs Biochem. Biophys., 150, pp. 77-85 
520 3 |a 1. 1. Although the levels of ALA-S in photosynthetic (Ph) are higher than in aerobic (A) cells, physical and kinetic properties are similar. Optimum reaction pH is 7.5; maximal product formation occurs at 37°C. 2. 2. The enzyme has an absolute requirement for glycine. The addition of cysteine (CySH), glutathione (GSH), cystine or 2-mercaptoethanol to the reaction mixture does not greatly modify activity, instead it diminishes in the presence of ALA, indicating that the ALA-feedback inhibits its own synthesis. 3. 3. The enzyme is not stable when stored at -15°C; however, activity remains constant for at least 18 hr when different preparations are kept at 0-4°C. 4. 4. Evidence of the existence of one or two low molecular weight compounds which stimulate or stabilize ALA-S activity was found by dialysis of crude extracts. 5. 5. Km values for glycine, succinyl-CoA and pyridoxal phosphate were 1.5 x 10-2 M, 1 x 10-5 M and 1 x 10-6 M respectively. 6. 6. Molecular weight was estimated to be 61 65,000 and no indication of active higher molecular weight species or subunits was obtained. 7. 7. Activity of R. palustris ALA-S can be efficiently regulated within the cell by the formation of one or two low molecular weight factors, depending on growth conditions and also through the levels of both glycine and ALA. © 1987.  |l eng 
536 |a Detalles de la financiación: Universidad de Buenos Aires 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas 
536 |a Detalles de la financiación: Aeknowledgements--E. A. Wider and A. M. del C. Baffle hold the post of Scientific Researchers at the National Research CoLmciI of Argentina (CON ICET). This work was supported by grants from CONICET, SECNT, the University of Buenos Aires, the Ministerio de Sa[ud PSblica de la Nacidn and the Banco de la Naci6n Argentina. 
593 |a Cátedra de Microbiologia e Immunología y, Buenos Aires, Argentine 
593 |a Centro de Investigaciones sobre Porfirinas y Porfirias (CIPYP), Departamento de Quimíca Biológica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón II, 1428 Buenos Aires, Argentine 
700 1 |a Wider, E.A. 
700 1 |a Del C. Batlle, A.M. 
773 0 |d 1987  |g v. 87  |h pp. 607-613  |k n. 3  |x 03050491  |w (AR-BaUEN)CENRE-2752  |t Comparative Biochemistry and Physiology -- Part B: Biochemistry and 
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