Thermal decomposition of formaldehyde diperoxide in aqueous solution
Thermal decomposition of formaldehyde diperoxide (1,2,4,5-tetraoxane) in aqueous solution with an initial concentration of 6.22 × 10-3 M was studied in the temperatures range from 403 to 439 K. The reaction was found to follow first-order kinetic law, and formaldehyde was the major decomposition pro...
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2009
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| 024 | 7 | |2 scopus |a 2-s2.0-73149096974 | |
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| 100 | 1 | |a Cazut, S.A.I. | |
| 245 | 1 | 0 | |a Thermal decomposition of formaldehyde diperoxide in aqueous solution |
| 260 | |c 2009 | ||
| 270 | 1 | 0 | |m Cazut, S. A. I.; Área Fisicoquímica, Facultad de Ciencias Exactas y Naturales y Agrimensura, Campus Universitario, Av. Libertad 5400, Corrientes 3400, Argentina; email: lidianj@exa.unne.edu.ar |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Cafferata, L.F.R., Furlong, J.J., (1995) Advances in Oxygenated Processes, p. 81. , A.L. Baumstark (eds). JAI Greenwich, CT | ||
| 504 | |a Cafferata, L.F.R., Eyler, G.N., Mirífico, M.V., (1984) J. Org. Chem., 49, p. 2107. , 10.1021/jo00186a005 1:CAS:528:DyaL2cXktVKnsb8%3D | ||
| 504 | |a Jorge, N.L., (1997), Doctoral Thesis UNLP, ArgentinaJorge, N.L., Vara Gómez, M.E., Castro, E.A., Autino, J.C., Cafferata, L.F.R., (1999) J. Mol. Struct. (Theochem), 459, p. 29. , 10.1016/S0166-1280(98)00254-1 | ||
| 504 | |a Jorge, N.L., Peruchena, N.M., Castro, E.A., Cafferata, L.F.R., (1998) J. Mol. Struct. (Theochem), 433, p. 311. , 10.1016/S0166-1280(98)00036-0 1:CAS:528:DyaK1cXksFWrtbk%3D | ||
| 504 | |a McCullough, K.J., Morgan, A.R., Nonhebel, D.C., Pauson, P.L., (1980) J. Chem. Res., Synop., (2), p. 36 | ||
| 504 | |a McCullough, K.J., Morgan, A.R., Nonhebel, D.C., Pauson, P.L., White, C.J., (1980) J. Chem. Res., Synop., (2), p. 34 | ||
| 504 | |a Dubnikova, F., Kosloff, R., Almog, J., Zeiri, Y., Boese, R., Itzhaky, H., Alt, A., Keinan, E., Decomposition of triacetone triperoxide is an entropic explosion (2005) Journal of the American Chemical Society, 127 (4), pp. 1146-1159. , DOI 10.1021/ja0464903 | ||
| 504 | |a Van Duin, A.C., Zeiri, Y., Dubnikova, F., Kosloff, R., Goddard, W.A., (2005) J. Am. Chem. Soc., 127, p. 11. , 053 | ||
| 504 | |a Cañizo, A.I., Cafferata, L.F.R., (1992) Anal. Asoc. Quim. Argentina, 80 (4), p. 345 | ||
| 504 | |a Jorge, N.L., Leiva, L.C.A., Romero, J.M., Vara Gómez, M.E., (2002) Rev. Int. Inform. Tecnol., 13 (2), p. 23. , 1:CAS:528:DC%2BD38Xjs1Krtb8%3D | ||
| 504 | |a Jorge, N.L., http://www1.unne.edu.ar/cyt/2002/cyt.htm.e037Huyberechts, S., Halleux, A., Kruys, P., (1955) Bull. Soc. Chim. Belg., 64, p. 203. , 1:CAS:528:DyaG28XntFGq | ||
| 504 | |a Cafferata, L.F.R., Lombardo, J.D., (1994) Int. J. Chem. Kinet., 26, p. 503. , 10.1002/kin.550260503 1:CAS:528:DyaK2cXivFOrtLY%3D | ||
| 504 | |a Cafferata, L.F.R., Eyler, G.N., Svartman, E.L., Cañizo, A.I., Alvarez, E.E., (1991) J. Org. Chem., 56, p. 411. , 10.1021/jo00001a074 1:CAS:528:DyaK3MXktFylsQ%3D%3D | ||
| 504 | |a Leiva, L.C., Castellanos, M.G., Jorge, N.L., Cafferata, L.F.R., Vara Gómez, M.E., (1998) Rev. Soc. Quim. México, 42, p. 223. , 1:CAS:528:DyaK1MXkvVyqurs%3D | ||
| 504 | |a Leiva, L.C., Cafferata, L.F.R., Vara Gómez, M.E., (2000) Anal. Asoc. Quim. Argentina, 88 (1-2), p. 9. , 1:CAS:528:DC%2BD3MXhsVahsA%3D%3D | ||
| 504 | |a Schaleger, L.L., Long, F.A., Adv. Phys. Org. Chem | ||
| 520 | 3 | |a Thermal decomposition of formaldehyde diperoxide (1,2,4,5-tetraoxane) in aqueous solution with an initial concentration of 6.22 × 10-3 M was studied in the temperatures range from 403 to 439 K. The reaction was found to follow first-order kinetic law, and formaldehyde was the major decomposition product. The activation parameters of the initial step of the reaction (ΔH ≠ = 15.25 ± 0.5 kcal mol-1, ΔS ≠ =-47.78 ± 0.4 cal mol-1K-1, E a = 16.09 ± 0.5 kcal mol-1) support a mechanism involving homolytic rupture of one peroxide bond in the 1,2,4,5-tetraoxane molecule with participation of the solvent and formation of a diradical intermediate. © 2009 Pleiades Publishing, Ltd. |l eng | |
| 593 | |a Área Fisicoquímica, Facultad de Ciencias Exactas y Naturales y Agrimensura, Campus Universitario, Av. Libertad 5400, Corrientes 3400, Argentina | ||
| 593 | |a INIFTA, División Química Teórica, Facultad de Ciencias Exactas, Diagonal 113 y 64, Suc. 4, C.C. 16, La Plata, Buenos Aires 1900, Argentina | ||
| 700 | 1 | |a Ramírez Maisuls, E.H. | |
| 700 | 1 | |a Delfino, M.R. | |
| 700 | 1 | |a Romero, J.M. | |
| 700 | 1 | |a Jorge, N.L. | |
| 700 | 1 | |a Castro, E.A. | |
| 773 | 0 | |d 2009 |g v. 79 |h pp. 2187-2190 |k n. 10 |p Russ. J. Gen. Chem. |x 10703632 |w (AR-BaUEN)CENRE-6754 |t Russian Journal of General Chemistry | |
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| 856 | 4 | 0 | |u https://doi.org/10.1134/S107036320910017X |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_10703632_v79_n10_p2187_Cazut |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10703632_v79_n10_p2187_Cazut |y Registro en la Biblioteca Digital |
| 961 | |a paper_10703632_v79_n10_p2187_Cazut |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 69400 | ||