Adsorption of Ar on planar surfaces studied with a density functional theory

The adsorption of Ar on planar structureless substrates of alkali metals, alkaline-earth metal Mg, CO2, and Au was analyzed by applying a density functional formalism which includes a recently proposed effective attractive pair potential conditioned to Ar. It is shown that this approach reproduces t...

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Autor principal: Sartarelli, Salvador Andrés
Otros Autores: Szybisz, L.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2009
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Acceso en línea:Registro en Scopus
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100 1 |a Sartarelli, Salvador Andrés 
245 1 0 |a Adsorption of Ar on planar surfaces studied with a density functional theory 
260 |c 2009 
270 1 0 |m Szybisz, L.; Laboratorio TANDAR, Departamento de Física, Comisión Nacional de Energía Atómica, Av. del Libertador 8250, RA-1429 Buenos Aires, Argentina; email: szybisz@tandar.cnea.gov.ar 
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506 |2 openaire  |e Política editorial 
520 3 |a The adsorption of Ar on planar structureless substrates of alkali metals, alkaline-earth metal Mg, CO2, and Au was analyzed by applying a density functional formalism which includes a recently proposed effective attractive pair potential conditioned to Ar. It is shown that this approach reproduces the experimental surface tension of the liquid-vapor interface over the entire bulk coexistence curve for temperatures T spanning from the triple point Tt up to the critical point Tc. The wetting properties were studied over the entire range temperatures Tt Tc. It was found that Ar wets all the investigated surfaces. The adsorption isotherms for alkali metals exhibit first-order phase transitions. Prewetting lines were resolved even for the less attractive surfaces. In the cases of Mg, CO2, and Au a continuous growth for T Tt was obtained. A comparison with experimental data and other microscopic calculations is reported. © 2009 The American Physical Society.  |l eng 
593 |a Instituto de Desarrollo Humano, Universidad Nacional de General Sarmiento, Gutierrez 1150, RA-1663 San Miguel, Argentina 
593 |a Laboratorio TANDAR, Departamento de Física, Comisión Nacional de Energía Atómica, Av. del Libertador 8250, RA-1429 Buenos Aires, Argentina 
593 |a Departamento de Física, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, RA-1428 Buenos Aires, Argentina 
593 |a Consejo Nacional de Investigaciones Científicas y Técnicas, Av. Rivadavia 1917, RA-1033 Buenos Aires, Argentina 
650 1 7 |2 spines  |a ARGON 
690 1 0 |a A-DENSITY 
690 1 0 |a ATTRACTIVE SURFACES 
690 1 0 |a COEXISTENCE CURVE 
690 1 0 |a CRITICAL POINTS 
690 1 0 |a EXPERIMENTAL DATA 
690 1 0 |a FIRST-ORDER PHASE TRANSITIONS 
690 1 0 |a LIQUID-VAPOR INTERFACE 
690 1 0 |a PAIR POTENTIAL 
690 1 0 |a PLANAR SURFACE 
690 1 0 |a PRE-WETTING 
690 1 0 |a TRIPLE POINTS 
690 1 0 |a WETTING PROPERTY 
690 1 0 |a ADSORPTION 
690 1 0 |a ADSORPTION ISOTHERMS 
690 1 0 |a ALKALI METALS 
690 1 0 |a ATMOSPHERIC TEMPERATURE 
690 1 0 |a EQUATIONS OF STATE 
690 1 0 |a PHASE INTERFACES 
690 1 0 |a PHASE TRANSITIONS 
690 1 0 |a SURFACE TENSION 
690 1 0 |a TECHNETIUM 
690 1 0 |a DENSITY FUNCTIONAL THEORY 
700 1 |a Szybisz, L. 
773 0 |d 2009  |g v. 80  |k n. 5  |p Phys. Rev. E Stat. Nonlinear Soft Matter Phys.  |x 15393755  |t Physical Review E - Statistical, Nonlinear, and Soft Matter Physics 
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