Evaluation of the polymer-solvent interaction parameter χ for the system cured polybutadiene rubber and toluene
One of the most popular cured rubbers used in industrial applications is polybutadiene rubber (BR) and frequently its network structure, in the cured state, is studied by means of swelling in a solvent. Normally, toluene is used as solvent in this test. In order to estimate the crosslink density fro...
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2010
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| LEADER | 11455caa a22011777a 4500 | ||
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| 001 | PAPER-8093 | ||
| 003 | AR-BaUEN | ||
| 005 | 20250910124740.0 | ||
| 008 | 190411s2010 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-72449166885 | |
| 030 | |a POTED | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Marzocca, Angel José | |
| 245 | 1 | 0 | |a Evaluation of the polymer-solvent interaction parameter χ for the system cured polybutadiene rubber and toluene |
| 260 | |c 2010 | ||
| 270 | 1 | 0 | |m Marzocca, A.J.; Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Física, LPMPyMC, Pabellón 1, Ciudad Universitaria Buenos Aires C1428EGA, Argentina; email: marzo@df.uba.ar |
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| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a One of the most popular cured rubbers used in industrial applications is polybutadiene rubber (BR) and frequently its network structure, in the cured state, is studied by means of swelling in a solvent. Normally, toluene is used as solvent in this test. In order to estimate the crosslink density from the equilibrium volume fraction of rubber in the swollen state, the correct evaluation of the Flory-Huggins interaction parameter χ is necessary. This work covers the swelling behaviour of two types of cured BR in toluene. The rubbers used have sulphur and accelerator in their composition and were vulcanized at 433 K at different times in order to obtain several network structures and crosslink densities. The crosslink densities were evaluated from uniaxial stress-strain data measured at room temperature and analysed in the frame of the conformational tube model. Using this information and the swelling measurements in the frame of the Flory-Rehner relationship, a relationship between χ and vr, the polymer volume fraction at equilibrium (maximum) degree of swelling was established for the cured BR/toluene system. It was found that χ is not a constant but depends on the crosslink density of the sample. © 2009 Elsevier Ltd. All rights reserved. |l eng | |
| 536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, PICT 1650/06 | ||
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires, X808 | ||
| 536 | |a Detalles de la financiación: This work was supported by the Universidad de Buenos Aires, Argentina (Research Project X808) and partially by the Agencia Nacional de Promoción Científica y Tecnológica (PICT 1650/06). The authors want to thank Lanxess S.A.(Argentina) for the polymers and Fate SAICI (Argentina) for the preparation of the samples. | ||
| 593 | |a Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Física, LPMPyMC, Pabellón 1, Ciudad Universitaria Buenos Aires C1428EGA, Argentina | ||
| 690 | 1 | 0 | |a CROSSLINKING |
| 690 | 1 | 0 | |a FLORY-HUGGINS INTERACTION PARAMETER |
| 690 | 1 | 0 | |a POLYBUTADIENE RUBBER |
| 690 | 1 | 0 | |a SWELLING |
| 690 | 1 | 0 | |a TOLUENE |
| 690 | 1 | 0 | |a CROSS-LINK DENSITIES |
| 690 | 1 | 0 | |a DEGREE OF SWELLING |
| 690 | 1 | 0 | |a FLORY-HUGGINS INTERACTION PARAMETER |
| 690 | 1 | 0 | |a NETWORK STRUCTURES |
| 690 | 1 | 0 | |a POLYBUTADIENE RUBBER |
| 690 | 1 | 0 | |a POLYBUTADIENE RUBBERS |
| 690 | 1 | 0 | |a POLYMER VOLUME FRACTION |
| 690 | 1 | 0 | |a POLYMER-SOLVENT INTERACTIONS |
| 690 | 1 | 0 | |a ROOM TEMPERATURE |
| 690 | 1 | 0 | |a SWELLING BEHAVIOUR |
| 690 | 1 | 0 | |a SWELLING MEASUREMENTS |
| 690 | 1 | 0 | |a TUBE MODEL |
| 690 | 1 | 0 | |a UNIAXIAL STRESS |
| 690 | 1 | 0 | |a CURING |
| 690 | 1 | 0 | |a INDUSTRIAL APPLICATIONS |
| 690 | 1 | 0 | |a POLYBUTADIENES |
| 690 | 1 | 0 | |a RUBBER |
| 690 | 1 | 0 | |a RUBBER APPLICATIONS |
| 690 | 1 | 0 | |a SOLVENTS |
| 690 | 1 | 0 | |a SULFUR |
| 690 | 1 | 0 | |a SWELLING |
| 690 | 1 | 0 | |a TITRATION |
| 690 | 1 | 0 | |a TOLUENE |
| 690 | 1 | 0 | |a ORGANIC SOLVENTS |
| 700 | 1 | |a Rodriguez Garraza, Ana Lucía | |
| 700 | 1 | |a Mansilla, Marcela Angela | |
| 773 | 0 | |d 2010 |g v. 29 |h pp. 119-126 |k n. 1 |p Polym Test |x 01429418 |w (AR-BaUEN)CENRE-6542 |t Polymer Testing | |
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| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_01429418_v29_n1_p119_Marzocca |y Handle |
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