The electrochemical reduction of oxygen on polycrystalline copper in borax buffer
Oxygen reduction proceeds on copper electrodes in boric + borate buffer by the four electron pathway. Difference reflectance spectroscope shows that surface oxide species are formed during oxygen reduction on pre-reduced copper. The redox couple Cu2O/CuO plays an important role in the reduction sequ...
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1994
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| LEADER | 05933caa a22007217a 4500 | ||
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| 001 | PAPER-80 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518202928.0 | ||
| 008 | 190411s1994 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0001013833 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a JECHE | ||
| 100 | 1 | |a Vazquez, M.V. | |
| 245 | 1 | 4 | |a The electrochemical reduction of oxygen on polycrystalline copper in borax buffer |
| 260 | |c 1994 | ||
| 270 | 1 | 0 | |m Vazquez, M.V.; INTEMA, Facultad de Ingeniería, Universidad Nacional de Mar del Plata, 7600 Mar del Plata, Argentina |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Calvo, Schiffrin, (1988) J. Electroanal. Chem., 243, p. 171 | ||
| 504 | |a de Sanchez, Schiffrin, (1982) Corros. Sci., 6, p. 585 | ||
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| 504 | |a Spekmann, Lohrengel, Schultze, Strehblow, The Growth and Reduction of Duplex Oxide Films on Copper (1985) Berichte der Bunsengesellschaft für physikalische Chemie, 89, p. 392 | ||
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| 504 | |a M.V. Vazquez, S.R. de Sanchez, E.J. Calvo and D.J. Schiffrin J. Electroanal. Chem., 3342; Jovancicevic, Bockris, (1986) J. Electrochem. Soc., 133, p. 1797 | ||
| 504 | |a Kaska, Sarangapani, Giner, (1989) J. Electrochem. Soc., 136, p. 75 | ||
| 504 | |a N. Gentil and R. Fernandez Prini, private communication; Jovancicevic, Zelanay, Sharifker, (1987) Electrochim. Acta, 32, p. 1553 | ||
| 504 | |a Tiepel, Gubbins, (1973) Ind. Eng. Chem. Fundam., 12, p. 18 | ||
| 504 | |a Gubbins, Walker, The Solubility and Diffusivity of Oxygen in Electrolytic Solutions (1965) Journal of The Electrochemical Society, 112, p. 469 | ||
| 504 | |a Weast, (1971) CRC Handbook of Chemistry and Physics, , 52nd edn., Chemical Rubber Co, Cleveland, OH | ||
| 504 | |a de Sanchez, Berlouis, Schiffrin, (1991) J. Electroanal. Chem., 307, p. 73 | ||
| 504 | |a Levich, (1962) Physicochemical Hydrodynamics, , Prentice Hall, Englewood Cliffs, NJ | ||
| 504 | |a Vesovic, Annastasijevich, Adzic, (1987) J. Electroanal. Chem., 218, p. 53 | ||
| 504 | |a Pleskov, Filinovskii, (1976) The Rotating Disc Electrode, , Consultants Bureau, New York | ||
| 504 | |a M.R. Tarasevich, A. Sadkowski and E.B Yeager, in B.E. Conway, J.O'M. Bockris, E.B. Yeager, S. Khan and R. White (Eds.), Comprehensive Treatise of Electrochemistry, Vol. 7, Plenum Press, New York, Ch. 6, p. 301; Hardee, Bard, (1977) J. Electrochem. Soc., 124, p. 215 | ||
| 504 | |a Burke, Ahern, Ryan, (1990) J. Electrochem. Soc., 137, p. 553 | ||
| 520 | 3 | |a Oxygen reduction proceeds on copper electrodes in boric + borate buffer by the four electron pathway. Difference reflectance spectroscope shows that surface oxide species are formed during oxygen reduction on pre-reduced copper. The redox couple Cu2O/CuO plays an important role in the reduction sequence and a CE mechanism is proposed, although direct electron transfer to the oxygen molecule from oxide-free surfaces appears possible. In this case, the behaviour of copper is similar to that of the isoelectronic metal gold. © 1994. |l eng | |
| 536 | |a Detalles de la financiación: British Council | ||
| 536 | |a Detalles de la financiación: University of Liverpool | ||
| 536 | |a Detalles de la financiación: Financial support (MW) from the Consejo Na-cional de InvestigacioneCs ientificasy Tecnicas,C ON-ICET, Argentina, and from the British Council for travel grants between Mar de1 Plata and Liverpool under the ALAS programmei s gratefully acknowledged. | ||
| 593 | |a INTEMA, Facultad de Ingeniería, Universidad Nacional de Mar del Plata, 7600 Mar del Plata, Argentina | ||
| 593 | |a INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Buenos Aires, Pab. II, Ciudad Universitaria, 1428 Buenos Aires, Argentina | ||
| 593 | |a Chemistry Department, University of Liverpool, Liverpool, L69 3BX, United Kingdom | ||
| 700 | 1 | |a de Sanchez, S.R. | |
| 700 | 1 | |a Calvo, E.J. | |
| 700 | 1 | |a Schiffrin, D.J. | |
| 773 | 0 | |d 1994 |g v. 374 |h pp. 189-197 |k n. 1-2 |p J Electroanal Chem |x 00220728 |w (AR-BaUEN)CENRE-102 |t Journal of Electroanalytical Chemistry | |
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| 856 | 4 | 0 | |u https://doi.org/10.1016/0022-0728(94)03343-9 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00220728_v374_n1-2_p189_Vazquez |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00220728_v374_n1-2_p189_Vazquez |y Registro en la Biblioteca Digital |
| 961 | |a paper_00220728_v374_n1-2_p189_Vazquez |b paper |c PE | ||
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