Surface conductivity changes during the electrochemical adsorption of UPD layers on silver and gold

The surface conductivity changes for UPD and UPS of Cu, Ag, Tl, Cd, Pb and Bi on gold and of Tl, Cd, Pb and Bi on silver were measured. At low coverages the relative resistance change, ΔR R depends linearly upon the adatom coverage, θ, obeying Linde's rule for the surface. At intermediate cover...

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Autor principal: Romeo, F.M
Otros Autores: Tucceri, R.I, Posadas, D.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1988
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100 1 |a Romeo, F.M. 
245 1 0 |a Surface conductivity changes during the electrochemical adsorption of UPD layers on silver and gold 
260 |c 1988 
270 1 0 |m Romeo, F.M. 
506 |2 openaire  |e Política editorial 
504 |a Haissinsky, (1933) J. Chim. Phys., 30, p. 27 
504 |a Kolb, (1978) Advances in Electrochemistry and Electrochemical Engineering, 11. , H. Gerischer, C.W. Tobias, Wiley, New York 
504 |a Jüttner, Surface structural effects in electrocatalysis (1986) Electrochimica Acta, 31, p. 917 
504 |a Adzic, (1984) Advances in Electrochemistry and Electrochemical Engineering, 13. , H. Gerischer, C.W. Tobias, Wiley, New York 
504 |a Chauvineau, Pariset, (1973) Surface Sci., 36, p. 155 
504 |a Pariset, Chauvineau, (1975) Surface Sci., 47, p. 543 
504 |a Pariset, Chauvineau, (1976) Surface Sci., 57, p. 363 
504 |a Pariset, Chauvineau, (1978) Surface Sci., 78, p. 478 
504 |a Fujihira, Kuwana, Studies of electrochemical interfaces of thin PT film electrodes by surface conductance (1975) Electrochimica Acta, 20, p. 565 
504 |a Hansen, (1980) Surface Sci., 101, p. 109 
504 |a Rath, (1983) J. Electroanal. Chem., 150, p. 521 
504 |a Rath, (1980) PhD Thesis, Utah State University, Utah, USA, , Univ. Microfilms Int, Ann Arbor, MI 
504 |a Ganon, Clavilier, (1984) Surface Sci., 147, p. 583 
504 |a Tucceri, Posadas, (1983) Anal. Asoc. Quím. Arg., 71, p. 229 
504 |a F.M. Romeo, unpublished; Zei, Nakai, Lempfuhl, Kolb, (1983) J. Electroanal. Chem., 150, p. 201 
504 |a Fuchs, The conductivity of thin metallic films according to the electron theory of metals (1938) Mathematical Proceedings of the Cambridge Philosophical Society, 34, p. 100 
504 |a Sondheimer, The mean free path of electrons in metals (1952) Advances in Physics, 1, p. 1 
504 |a Wissmann, (1972) Thin Solid Films, 13, p. 189 
504 |a Tucceri, Posadas, (1982) J. Electroanal. Chem., 131, p. 377 
504 |a Tucceri, Posadas, (1981) J. Electrochem. Soc., 128, p. 1478 
504 |a Tucceri, Posadas, (1983) J. Electrochem. Soc., 130, p. 104 
504 |a Chao, Costa, (1981) Thin Solid Films, 82, p. 3 
504 |a Adzic, Yeager, Cahan, (1974) J. Electrochem. Soc., 121, p. 474 
504 |a Takamura, Kusu, Takamura, (1981) Denki Kagaku, 42, p. 562 
504 |a Kolb, Przanyski, Gerischer, (1974) J. Electroanal. Chem., 54, p. 25 
504 |a Schultze, Koppitz, (1976) Electrochim. Acta, 21, p. 327 
504 |a Tucceri, Posadas, (1985) J. Electroanal. Chem., 191, p. 387 
504 |a Parsons, Zobel, (1965) J. Electroanal. Chem., 9, p. 333 
504 |a Clavilier, Van Huong, (1971) Compt. Rend. (Paris) Ser. C, 273, p. 202 
504 |a Valette, (1987) J. Electroanal. Chem., 224, p. 285 
504 |a R.I. Tucceri, F.M. Romeo and D. Posadas, to be published; Lorenz, Hermann, Wüthrich, Hilbert, The Formation of Monolayer Metal Films on Electrodes (1974) Journal of The Electrochemical Society, 121, p. 1168 
504 |a Kittel, (1966) Introduction to Solid State Physics, , Wiley, New York 
504 |a Takayanagi, Kolb, Kambe, Lehmpfuhl, Deposition of monolayer and bulk lead on Ag(111) studied in vacuum and in an electrochemical cell (1980) Surface Science, 100, p. 407 
504 |a Geus, (1971) Chemisorption and Reactions on Metallic Films, 1, p. 350. , J.R. Anderson, Academic Press, London 
504 |a Ziman, Introduction to Solid State Physics (1972) Principles of the Theory of Solids, , Cambridge Univ. Press, London 
504 |a Van Hove, (1979) The Nature of the Surface Chemical Bond, p. 295. , T.N. Rodin, G. Ertl, North Holland, Amsterdam, ch. 4 
504 |a Rodin, Adams, (1976) Treatise on Solid State Chemistry, 6 A, p. 381. , N.Bruce Hannay, Plenum, New York, Surfaces I 
504 |a Schmidt, Gomer, Adsorption of Potassium on Tungsten: Measurements on Single-Crystal Planes (1966) The Journal of Chemical Physics, 45, p. 1605 
504 |a Cetronio, Jones, (1974) Surface Sci., 44, p. 109 
504 |a Bauer, Poppa, Todd, Bonczek, (1974) J. Appl. Phys., 45, p. 5164 
504 |a Polanski, Zidorsky, Adsorption of copper on tungsten; measurements on single crystal planes (1973) Surface Science, 40, p. 282 
504 |a Beckmann, Gerischer, Kolb, Lehmpfuhl, (1977) Faraday Symp. Chem. Soc., 12, p. 51 
504 |a Ganon, Van Huong, Calvilier, (1979) Surface Sci., 79, p. 245 
504 |a Geus, (1971) Chemisorption and Reactions on Metallic Films, 1, pp. 365-368. , J.R. Anderson, Academic Press, London 
504 |a Geus, (1971) Chemisorption and Reactions on Metallic Films, 1, pp. 388-393. , J.R. Anderson, Academic Press, London 
504 |a Takayanagi, (1981) Surface Sci., 104, p. 527 
504 |a Delaware, Rhead, First stages of the deposition of bismuth on copper examined by LEED (1973) Surface Science, 35, p. 172 
504 |a Perdereau, Biberian, Rhead, (1974) J. Phys. F (Metal Phys.), 4, p. 798 
504 |a Sepulveda, Rhead, (1975) Surface Sci., 49, p. 669 
504 |a Sepulveda, Rhead, (1977) Surface Sci., 66, p. 436 
504 |a Barthès, Rhead, Adsorption of lead on gold (320) and (311) surfaces (1979) Surface Science, 85, p. L211 
504 |a Hamelin, (1979) J. Electroanal. Chem., 101, p. 285 
504 |a Hamelin, Katayama, (1981) J. Electroanal. Chem., 117, p. 221 
504 |a Smoluchowski, (1941) Phys. Rev., 60, p. 661 
504 |a Valette, Hamelin, (1973) J. Electroanal. Chem., 45, p. 301 
504 |a Lecour, Hamelin, (1974) Compt. Rend. (Paris) Ser. C, 279, p. 1081 
504 |a Lecour, Andro, Parsons, The behaviour of water at stepped surfaces of single crystal gold electrodes (1982) Surface Science, 114, p. 320 
504 |a Hamelin, Vitanov, Sebastianov, Popov, (1983) J. Electroanal. Chem., 145, p. 225 
504 |a Trassatti, (1978) Advances in Electrochemistry and Electrochemical Engineering, 12. , H. Gerischer, C.W. Tobias, Wiley, New York 
520 3 |a The surface conductivity changes for UPD and UPS of Cu, Ag, Tl, Cd, Pb and Bi on gold and of Tl, Cd, Pb and Bi on silver were measured. At low coverages the relative resistance change, ΔR R depends linearly upon the adatom coverage, θ, obeying Linde's rule for the surface. At intermediate coverages ΔR R goes through a maximum and then decreases. The values of ΔR R at the maximum and at θ≅1 follows the sequence of the atomic radius of the adsorbate. The change of the specularity parameter, Δp, at θ≅1 indicates that the more dense the surface adlayer is, the more specularly the electrons are reflected. The shape of the ΔR R versus θ curve is explained qualitatively in terms of the structure of the adlayer and the distance between the adatoms. © 1988.  |l eng 
536 |a Detalles de la financiación: Universidad Nacional del Centro de la Provincia de Buenos Aires 
536 |a Detalles de la financiación: This work was financially supported by the Consejo National de Investiga-ciones Cientificas y Tecnicas and the Comisibn de Investigaciones Cientificas de la Provincia de Buenos Aires. 
593 |a Departamento de Química Inorgánica, Analítica y Química Fisica, Facultad de Ciencias Exactas] y Naturales, Universidad de Buenos Aires, Pabellón II, Ciudad Universitaria, Nuñez, Buenos Aires, Argentina 
593 |a Division Electroquímica, Institute de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Casilla de Correo 16, Sucursal 4, 1900 La Plata, Argentina 
700 1 |a Tucceri, R.I. 
700 1 |a Posadas, D. 
773 0 |d 1988  |g v. 203  |h pp. 186-200  |k n. 1-2  |p Surf Sci  |x 00396028  |w (AR-BaUEN)CENRE-53  |t Surface Science 
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