Pyrophosphate-bridged CuII chain magnet: {[Na 3Cu(P2O7)(NO3)]•3H 2O}n

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A CuII⋯CuII pyrophosphate-bridged compound of formula {[Na3Cu(P2O7)(NO3)] •3H2O}n (1) has been characterized. X-ray diffraction measurements show that it crystallizes in the monoclinic space group P2 1/m, with unit cell dimensions a = 7.2492(5) Å, b = 8.2446(6) Å, c = 9.9050(7) Å, β = 107.123(1)°, a...

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Detalles Bibliográficos
Autor principal: Sartoris, R.P
Otros Autores: Santana, R.C, Baggio, R.F, Peña, O., Perec, M., Calvo, Rafael A.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2010
Acceso en línea:Registro en Scopus
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024 7 |2 scopus  |a 2-s2.0-77953603816 
024 7 |2 cas  |a copper, 15158-11-9, 7440-50-8; pyrophosphate, 14000-31-8, 7722-88-5, 7758-16-9; Copper, 7440-50-8; Diphosphates; Organometallic Compounds 
030 |a INOCA 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
100 1 |a Sartoris, R.P. 
245 1 0 |a Pyrophosphate-bridged CuII chain magnet: {[Na 3Cu(P2O7)(NO3)]•3H 2O}n 
260 |c 2010 
270 1 0 |m Perec, M.; Facultad de Ciencias Exactas y Naturales, INQUIMAE, Universidad de Buenos Aires, C1428EHA Buenos Aires, Argentina; email: perec@qi.fcen.uba.ar 
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506 |2 openaire  |e Política editorial 
520 3 |a A CuII⋯CuII pyrophosphate-bridged compound of formula {[Na3Cu(P2O7)(NO3)] •3H2O}n (1) has been characterized. X-ray diffraction measurements show that it crystallizes in the monoclinic space group P2 1/m, with unit cell dimensions a = 7.2492(5) Å, b = 8.2446(6) Å, c = 9.9050(7) Å, β = 107.123(1)°, and Z = 2. The structure consists of chains of CuII cations at inversion symmetry sites bound to four equatorial oxygen atoms provided by two pyrophosphate anions halved by a symmetry plane and two axial oxygen atoms of nitrate anions. The molar magnetic susceptibility ξ0 of a powdered sample was measured in the temperature range 2 K < T < 273 K, and an isothermal magnetization curve, M(B0,T), was obtained at T = 30 K, with the magnetic field B0 between 0 and 5 T. Fitting a spin-chain model to the susceptibility data, we evaluate an antiferromagnetic exchange coupling 2J = -24.3(1) cm-1 (defined as ℋex = -2JS iSj) between CuII neighbors. For any orientation of B0, single-crystal electron paramagnetic resonance (EPR) spectra obtained at 9.8 and 33.9 GHz at 300 K display a single signal having a g matrix with orthorhombic symmetry, arising from the merger produced by the exchange interaction of the resonances corresponding to the two rotated CuII sites. The g matrices of the individual molecules calculated assuming axial symmetry yielded principal values g∥ = 2.367(1) and g⊥ = 2.074(1) at both frequencies, indicating a d x 2-y2 ground-state orbital for the Cu II ions. The angular variation of the EPR line width suggests exchange narrowing in a system with one-dimensional spin dynamics, as expected from the structure and susceptibility data. The results, discussed in terms of the crystal and electronic structures and of the spin dynamics of the compound, are compared with those obtained in other materials. © 2010 American Chemical Society.  |l eng 
593 |a Facultad de Bioquímica y Ciencias Biológicas, Universidad Nacional Del Litoral and INTEC (CONICET-UNL), Güemes 3450, 3000 Santa Fe, Argentina 
593 |a Universidade Federal de Goiás, Campus Samambaia, CP 131, 74001-970 Goiânia, Brazil 
593 |a Comisión Nacional de Energía Atómica, Avenida Gral Paz 1499, 1650 San Martín, Buenos Aires, Argentina 
593 |a Sciences Chimiques de Rennes, UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes, France 
593 |a Facultad de Ciencias Exactas y Naturales, INQUIMAE, Universidad de Buenos Aires, C1428EHA Buenos Aires, Argentina 
690 1 0 |a COPPER 
690 1 0 |a ORGANOMETALLIC COMPOUND 
690 1 0 |a PYROPHOSPHATE 
690 1 0 |a ARTICLE 
690 1 0 |a CHEMICAL STRUCTURE 
690 1 0 |a CHEMISTRY 
690 1 0 |a MAGNETISM 
690 1 0 |a SYNTHESIS 
690 1 0 |a TEMPERATURE 
690 1 0 |a X RAY CRYSTALLOGRAPHY 
690 1 0 |a COPPER 
690 1 0 |a CRYSTALLOGRAPHY, X-RAY 
690 1 0 |a DIPHOSPHATES 
690 1 0 |a MAGNETICS 
690 1 0 |a MODELS, MOLECULAR 
690 1 0 |a ORGANOMETALLIC COMPOUNDS 
690 1 0 |a TEMPERATURE 
700 1 |a Santana, R.C. 
700 1 |a Baggio, R.F. 
700 1 |a Peña, O. 
700 1 |a Perec, M. 
700 1 |a Calvo, Rafael A. 
773 0 |d 2010  |g v. 49  |h pp. 5650-5657  |k n. 12  |p Inorg. Chem.  |x 00201669  |w (AR-BaUEN)CENRE-60  |t Inorganic Chemistry 
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