Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems.

The dielectric behavior of polar non polar liquid systems is treated as the result of associations through changes in the model proposed by Mechetti and Barón for very dilute solutions. The existence of a 1:1 interaction product (or complex) is assumed and the equilibrium constant (K) of complex for...

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Detalles Bibliográficos
Autor principal: Rebollo Paz, M.B
Otros Autores: Buep, Adrián Hugo, Barón, Máximo
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1988
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
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245 1 0 |a Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems. 
260 |c 1988 
270 1 0 |m Rebollo Paz, M.B.; Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon I. Ciudad Universitaria, 1428 Buenos Aires, Argentina 
504 |a (1982) An. Asoc. Quím. Argent., 70, p. 61. , See parts 4, 5 and 7 respectively 
504 |a Dielectric properties of binary mixtures. 5. Dilute alcohol/nonpolar solvent systems (1982) The Journal of Physical Chemistry, 86, p. 3464 
504 |a c J. Phys. Chem. In press; Ibbitson, Moore, (1976) J. Chem. Soc. B, 76, p. 83 
504 |a Pimentel, Mc Clellan, (1960) The Hydrogen Bond, , W.H. Freeman and Company, San Francisco 
504 |a Stokes, French, (1980) J. Chem. Soc. Faraday I, 76, p. 537 
504 |a Stokes, Marsh, (1976) J. Chem. Thermodynamics, 8, p. 709 
504 |a Paraskevopoulos, Missen, (1962) Trans. Faraday Soc., 58, p. 869 
504 |a Otterstedt, Missen, (1962) Trans. Faraday Soc., 58, p. 879 
504 |a Mc Keigue, Gulari, Light-scattering measurements of diffusion in binary solutions containing an associating component (1984) The Journal of Physical Chemistry, 88, p. 3472 
504 |a Nagata, Ogasawara, (1982) Thermochim. Acta, 52, p. 155 
504 |a Nagata, Inaguma, (1986) Thermochim. Acta, 97, p. 51 
504 |a Nagata, (1986) Thermochim. Acta, 107, p. 199 
504 |a Nagata, Tamura, (1982) Thermochim. Acta, 57, p. 331 
504 |a Nagata, Tamura, (1984) Thermochim. Acta, 77, p. 281 
504 |a Nagata, Tamura, (1985) Thermochim. Acta, 87, p. 129 
506 |2 openaire  |e Política editorial 
520 3 |a The dielectric behavior of polar non polar liquid systems is treated as the result of associations through changes in the model proposed by Mechetti and Barón for very dilute solutions. The existence of a 1:1 interaction product (or complex) is assumed and the equilibrium constant (K) of complex formation is introduced. As a result the range of validity of the model extends into the non-dilute region and up to the limit where complexes other than 1:1 appear. These changes allow also to calculate the equilibrium constant (K) for the 1:1 complex from dielectric measurements in the dilute region. The values are in good agreement with those found in the literature. © 1988.  |l eng 
593 |a Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon I. Ciudad Universitaria, 1428 Buenos Aires, Argentina 
700 1 |a Buep, Adrián Hugo 
700 1 |a Barón, Máximo 
773 0 |d 1988  |g v. 38  |h pp. 225-232  |k n. 3-4  |p J Mol Liq  |x 01677322  |w (AR-BaUEN)CENRE-591  |t Journal of Molecular Liquids 
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