Synthesis and preliminary biological screening of sterol analogues as new antifungal agents against plant pathogens

In this paperwereport the synthesis of anewfamily of sterol analogues that have two amidic bonds on the side chain. These azasterols were obtained by a straightforward procedure including an Ugi condensation that allows the facile attachment of a polyfunctionalized side chain into the steroidal fram...

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Autor principal: Alonso, F.
Otros Autores: Cirigliano, A.M, Cabrera, G.M, Ramírez, Javier Alberto
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2010
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
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LEADER 07163caa a22010697a 4500
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024 7 |2 scopus  |a 2-s2.0-77954315515 
024 7 |2 cas  |a Antifungal Agents; Azasteroids; Antifungal Agents; Azasteroids 
030 |a STEDA 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
100 1 |a Alonso, F. 
245 1 0 |a Synthesis and preliminary biological screening of sterol analogues as new antifungal agents against plant pathogens 
260 |c 2010 
270 1 0 |m Ramírez, J. A.; Departamento de Química Orgánica, UMYMFOR (CONICET - Facultad de Ciencias Exactas y Naturales), Ciudad Universitaria, Pabellón 2, Piso 3, C1428EGA Buenos Aires, Argentina; email: jar@qo.fcen.uba.ar 
504 |a Savary, S., Teng, P.S., Willocquet, L., Nutter Jr., F.W., Quantification and modeling of crop losses: A review of purposes (2006) Annu Rev Phytopathol, 44, pp. 89-112 
504 |a Knight, S.C., Anthony, V.M., Brady, A.M., Greenland, A.J., Heaney, S.P., Murray, D.C., Rationale and perspectives on the development of fungicides (1997) Annu Rev Phytopathol, 35, pp. 349-372 
504 |a Gros, L., Lorente, S.O., Jimenez, C., Yardley, V., Rattray, L., Wharton, H., Evaluation of azasterols as anti-parasitics (2006) J Med Chem, 49, pp. 6094-6103 
504 |a Brunel, J.M., Loncle, C., Vidal, N., Dherbomez, M., Letourneux, Y., Synthesis and antifungal activity of oxygenated cholesterol derivatives (2005) Steroids, 70, pp. 907-912 
504 |a Burbiel, J., Bracher, F., Azasteroids as antifungals (2003) Steroids, 68, pp. 587-594 
504 |a Zhu, J., Bienyamé, H., (2005) Multicomponet Reactions, , Wiley-VCH Verlag GmbH & Co. Weinheim 
504 |a Dömling, A., Recent developments in isocyanide based multicomponent reactions in applied chemistry (2006) Chem Rev, 106, pp. 17-89 
504 |a Alonso, F., Acebedo, S.L., Bruttomesso, A.C., Ramírez, J.A., Synthesis of 4-azasteroids by an intramolecular Ugi reaction (2008) Steroids, 73, pp. 1270-1276 
504 |a Bruttomesso, A.C., Eiras, J., Ramírez, J.A., Galagovsky, L.R., Highly stereoselective synthesis of steroidal 2,5-diketopiperazines based on isocyanide chemistry (2009) Tet Lett, 50, pp. 4022-4024 
504 |a Stauton, J., Eisenbaum, E.J., 3β-Acetoxyetienic acid (1962) Org Syn, 42, pp. 4-5 
504 |a Sato, Y., Sonoda, Y., Saito, H., Synthesis of [21-2H]- and [22-2H]-derivatives of 23, 24, 25, 26, 27-pentanorcholesterol and 23, 24, 25, 26, 27- pentanordihydrolanosterol and the stereochemical significance of the deuterium spin-lattice relaxation times (1980) Chem Pharm Bull, 28, pp. 1150-1156 
504 |a Sui, Q., Borchardt, D., Rabenstein, D.L., Kinetics and equilibria of cis/trans isomerization of backbone amide bonds in peptoids (2007) J Am Chem Soc, 129, pp. 12042-12048 
504 |a (2005) Antifungal Agents: Methods and Protocols, , E.J. Ernst, P.D. Rogers, 1st ed. Humana Press Inc. Totowa 
504 |a Song, Z., Nes, D., Sterol biosynthesis inhibitors: Potential for transition state analogs and mechanism-based inactivators targeted at sterol methyltransferase (2007) Lipids, 42, pp. 15-33 
506 |2 openaire  |e Política editorial 
520 3 |a In this paperwereport the synthesis of anewfamily of sterol analogues that have two amidic bonds on the side chain. These azasterols were obtained by a straightforward procedure including an Ugi condensation that allows the facile attachment of a polyfunctionalized side chain into the steroidal framework. Some of the new compounds showed an interesting inhibitory effect on the growth of two pathogenic fungi involved in plant diseases. © 2010 Elsevier Inc. All rights reserved.  |l eng 
593 |a Departamento de Química Orgánica, UMYMFOR (CONICET - Facultad de Ciencias Exactas y Naturales), Ciudad Universitaria, Pabellón 2, Piso 3, C1428EGA Buenos Aires, Argentina 
690 1 0 |a ANTIFUNGAL 
690 1 0 |a AZASTEROLS 
690 1 0 |a PLANT PATHOGENS 
690 1 0 |a UGI REACTION 
690 1 0 |a ANTIFUNGAL AGENT 
690 1 0 |a AZASTEROL DERIVATIVE 
690 1 0 |a DIETHYL[[N BENZYL N[(3BETA HYDROXYPREGN 5 ENE 20 YL)CARBONYL]GLYCYL]AMINO]METHYLPHOSPHONATE 
690 1 0 |a N [(TERT BUTYLCARBAMOYL)METHYL)N BENZYL 3BETA HYDROXYANDROST 5 EN 17BETA CARBOXAMINE 
690 1 0 |a N BENZYL N[(3BETA HYDROXYPREGN 5 ENE 20 YL)CARBONYL]GLYCYLGLYCINE 
690 1 0 |a N[(CYCLOHEXYLCARBAMOYL)METHYL]N BENZYL 3BETA HYDROXYPREGN 5 ENE 20 CARBOXAMIDE 
690 1 0 |a N[(CYCLOHEXYLCARBAMOYL)METHYL]N(2 (1H INDOL 3 YL)ETHYL] 3BETA HYDROXYPREGN 5 ENE 20 CARBOXAMIDE 
690 1 0 |a N[(CYCLOHEXYLCARBAMOYL)METHYL]N(3,4 DIMETHOXYPHENETHYL) 3BETA HYDROXYANDROST 5 EN 17BETA CARBOXAMIDE 
690 1 0 |a N[(CYCLOHEXYLCARBAMOYL)METHYL]N[3 (4 NITROPHENYLAMINO)PROPYL] 3BETA HYDROXYPREGN 5 ENE 20 CARBOXAMIDE 
690 1 0 |a N[(TERT BUTYLCARBAMOYL)METHYL]N PHENYL 3BETA HYDROXYANDROST 5 EN 17BETA CARBOXAMIDE 
690 1 0 |a N[(TERT BUTYLCARBAMOYL)METHYL]N(3 HYDROXYPHENYL)3BETA HYDROXYANDROST 5 EN 17BETA CARBOXAMIDE 
690 1 0 |a N[(TERT-BUTYLCARBAMOYL)METHYL]N(4 CHLOROPHENYL) 3BETA HYDROXYANDROST 5 EN 17BETA CARBOXAMIDE 
690 1 0 |a N[(TERTBUTYLCARBAMOYL)METHYL]N PHENYL 3BETA HYDROXYPREGN 5 ENE 20 CARBOXAMIDE 
690 1 0 |a STEROL DERIVATIVE 
690 1 0 |a UNCLASSIFIED DRUG 
690 1 0 |a ANTIFUNGAL AGENT 
690 1 0 |a AZASTEROID 
690 1 0 |a ANTIFUNGAL ACTIVITY 
690 1 0 |a ARTICLE 
690 1 0 |a NONHUMAN 
690 1 0 |a PLANT DISEASE 
690 1 0 |a STEROL SYNTHESIS 
690 1 0 |a CHEMICAL STRUCTURE 
690 1 0 |a CHEMISTRY 
690 1 0 |a DRUG EFFECTS 
690 1 0 |a FUSARIUM 
690 1 0 |a MICROBIAL SENSITIVITY TEST 
690 1 0 |a NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY 
690 1 0 |a SYNTHESIS 
690 1 0 |a ANTIFUNGAL AGENTS 
690 1 0 |a AZASTEROIDS 
690 1 0 |a FUSARIUM 
690 1 0 |a MAGNETIC RESONANCE SPECTROSCOPY 
690 1 0 |a MICROBIAL SENSITIVITY TESTS 
690 1 0 |a MOLECULAR STRUCTURE 
690 1 0 |a FUNGI 
690 1 0 |a ANTIFUNGAL AGENTS 
690 1 0 |a AZASTEROIDS 
690 1 0 |a FUSARIUM 
690 1 0 |a MAGNETIC RESONANCE SPECTROSCOPY 
690 1 0 |a MICROBIAL SENSITIVITY TESTS 
690 1 0 |a MOLECULAR STRUCTURE 
700 1 |a Cirigliano, A.M. 
700 1 |a Cabrera, G.M. 
700 1 |a Ramírez, Javier Alberto 
773 0 |d 2010  |g v. 75  |h pp. 659-664  |k n. 10  |p Steroids  |x 0039128X  |w (AR-BaUEN)CENRE-577  |t Steroids 
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856 4 0 |u https://doi.org/10.1016/j.steroids.2010.04.002  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_0039128X_v75_n10_p659_Alonso  |y Handle 
856 4 0 |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0039128X_v75_n10_p659_Alonso  |y Registro en la Biblioteca Digital 
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