Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: Thermal and photochemical initiation

Mostrar otras versiones (2)

The classical radical-based hydrosilylation reaction of organic compounds bearing C-C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. Thermal and photochemical initiations are used to accomplish the radical-...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autor principal: Calandra, J.
Otros Autores: Postigo, A., Russo, Diana, Nudelman, N.S, Tereñas, J.J
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2010
Acceso en línea:Registro en Scopus
DOI
Handle
Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
Biblioteca Central Dr. Luis F. Leloir (FCEN) de Universidad de Buenos Aires
LEADER 06446caa a22009137a 4500
001 PAPER-7625
003 AR-BaUEN
005 20250925103950.0
008 190411s2010 xx ||||fo|||| 00| 0 eng|d
024 7 |2 scopus  |a 2-s2.0-78649651811 
030 |a JPOCE 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
100 1 |a Calandra, J. 
245 1 0 |a Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: Thermal and photochemical initiation 
260 |c 2010 
270 1 0 |m Postigo, A.; Faculty of Science, University of Belgrano, Villanueva 1324, CP 1426 Buenos Aires, Argentina; email: alberto.postigo@ub.edu.ar 
504 |a Langner, A., Panarello, A., Rivilio, S., Vassylyev, O., Khinast, J.G., Chabal, Y.J., (2005) J. Am. Chem. Soc., 127, p. 12798 
504 |a Schmeltzer, J.M., Porter Jr., L., Stewart, M.P., Buriak, J.M., (2002) Langmuir, 18, p. 2971 
504 |a Stewart, M.P., Buriak, J.M., (2001) J. Am. Chem. Soc., 123, p. 7821 
504 |a Yasuda, H., Uenoyama, Y., Nobutta, O., Kobayashi, S., Ryu, I., (2008) Tetrahedron Lett., 49, p. 367 
504 |a Marcinec, B., (1992) Comprehensive Handbook on Hydrosilylation, , Pergamon Press, Oxford 
504 |a Marciniec, B., (2002) Silicon Chem., 1, pp. 155-165 
504 |a Ojima, I., Li, Z., Zu, J., (1998) The Chemistry of Organic Silicon Compounds, 2. , (Eds.: Z. Rappoport, Y. Apeloig,) Wiley, Chichester 
504 |a Chatgilialoglu, C., (2004) Organosilanes in Radical Chemistry, , Wiley, Chicheter 
504 |a Amreim, S., Timmermann, A., Studer, A., (2001) Org. Lett., 3, p. 2357 
504 |a Postigo, A., Ferreri, C., Navacchia, M.L., Chatgilialoglu, C., (2005) Synlett, 2854 
504 |a Postigo, A., Kopsov, S., Ferreri, C., Chatgilialoglu, C., (2007) Org. Lett., 9, p. 5159 
504 |a Postigo, A., Kopsov, S., Zlotsky, S., Ferreri, C., Chatgilialoglu, C., (2009) Orga-nometallics, 28 (11), p. 3282 
504 |a Kopping, B., Chatgililaloglu, C., Zehnder, M., Giese, B., (1992) J. Org. Chem., 57, p. 3994 
504 |a Ballestri, M., Chatgilialoglu, C., Clark, K.B., Griller, D., Giese, B., Kopping, B., (1991) J. Org. Chem., 56, p. 578 
504 |a Trost, B.M., Ball, Z.T., Laemmhold, K.M., (2005) J. Am. Chem. Soc., 127, p. 10028 
504 |a Studer, A., Steen, H., (1999) Chem. Eur. J., 5 (2), p. 759 
504 |a Liu, Y., Yamazaki, S., Yamabe, S., (2005) J. Org. Chem., 70, p. 556 
504 |a Liu, Y., Yamazaki, S., Yamabe, S., Nakato, Y., (2005) J. Mater. Chem., 15, p. 4906 
504 |a Liu, Y., Yamazaki, S., Izuhara, S., (2006) J. Organomet. Chem., 691, p. 5821 
504 |a Wang, J., Zhu, Z., Huang, W., Deng, M., Zhou, X., (2008) J. Organomet. Chem., 693, p. 2188 
504 |a Postigo, A., Nudelman, N.S., J. Phys. Org. Chem., , DOI:10.1002/poc.1703 
504 |a Calandra, J., Russo, D., Tereñ, J.J., (2009), Thesis, Facultad de Ciencias Exactas y Naturales, Unversidad de Belgrano, Buenos Aires, Argentina; Miura, K., Oshima, K., Utimoto, K., (1993) Bull. Chem. Soc. Jpn., 66, p. 2356 
504 |a Postigo, A., (2009) Curr. Org. Chem., 13 (17), p. 1683 
504 |a Postigo, A., Photochemical generation of silicon-centered radicals and their reactions (2008) Progress in Photochemistry Nova Science, pp. 193-226. , ISBN 978-1-60456-568-3. Chapter VI Publications, Hauppauge, New York 
504 |a Odedra, A., Geyer, K., Gustafsson, T., Gilmour, R., Seeberger, P.H., (2008) Chem. Commun., 3025 
506 |2 openaire  |e Política editorial 
520 3 |a The classical radical-based hydrosilylation reaction of organic compounds bearing C-C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. Thermal and photochemical initiations are used to accomplish the radical-induced hydrosilylation reaction of C-C multiple bonds in water with tris(trimethylsilyl)silane ((Me3Si)3SiH). Photochemical radical initiation in the absence of a chemical radical precursor other than the silane is found to be a very efficient and convenient method to induce the hydrosilylation reaction of C-C multiple bonds of organic compounds with (Me3Si)3SiH in water. This new alternate radical-based methodology studied in water is confronted with the classical radical thermal initiation of hydrosilylation reactions triggered through the thermal decomposition of azo compounds. Copyright © 2010 John Wiley and Sons, Ltd.  |l eng 
593 |a Faculty of Science, University of Belgrano, Villanueva 1324, CP 1426 Buenos Aires, Argentina 
593 |a Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 3er piso, CP1428, Buenos Aires, Argentina 
690 1 0 |a PHOTOCHEMICAL INITIATION 
690 1 0 |a RADICAL REACTIONS IN WATER 
690 1 0 |a SILYL RADICALS 
690 1 0 |a AZO COMPOUND 
690 1 0 |a CHEMICAL RADICALS 
690 1 0 |a HYDROPHOBIC AND HYDROPHILIC 
690 1 0 |a HYDROSILYLATION REACTION 
690 1 0 |a MULTIPLE BONDS 
690 1 0 |a PHOTOCHEMICAL INITIATION 
690 1 0 |a RADICAL INITIATIONS 
690 1 0 |a RADICAL REACTIONS 
690 1 0 |a SILYL RADICALS 
690 1 0 |a THERMAL DECOMPOSITIONS 
690 1 0 |a THERMAL INITIATIONS 
690 1 0 |a TRIS(TRIMETHYLSILYL)SILANE 
690 1 0 |a CHEMICAL COMPOUNDS 
690 1 0 |a HYDROSILYLATION 
690 1 0 |a ORGANIC SOLVENTS 
690 1 0 |a PYROLYSIS 
690 1 0 |a REACTION KINETICS 
690 1 0 |a PHOTOCHEMICAL REACTIONS 
700 1 |a Postigo, A. 
700 1 |a Russo, Diana 
700 1 |a Nudelman, N.S. 
700 1 |a Tereñas, J.J. 
773 0 |d 2010  |g v. 23  |h pp. 944-949  |k n. 10  |p J Phys Org Chem  |x 08943230  |w (AR-BaUEN)CENRE-576  |t Journal of Physical Organic Chemistry 
856 4 1 |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-78649651811&doi=10.1002%2fpoc.1732&partnerID=40&md5=ddae54e4074238aa8e598a44876f4409  |y Registro en Scopus 
856 4 0 |u https://doi.org/10.1002/poc.1732  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_08943230_v23_n10_p944_Calandra  |y Handle 
856 4 0 |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08943230_v23_n10_p944_Calandra  |y Registro en la Biblioteca Digital 
961 |a paper_08943230_v23_n10_p944_Calandra  |b paper  |c PE 
962 |a info:eu-repo/semantics/article  |a info:ar-repo/semantics/artículo  |b info:eu-repo/semantics/publishedVersion 
963 |a VARI 
999 |c 68578 

Ejemplares similares