Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system

Samples of cured medium cis polybutadiene compound, formulated with sulphur and accelerator and vulcanized at 433 K, were prepared at different cure times in order to obtain different network structures. Uniaxial stress strain tests were performed at room temperature and analyzed in the frame of the...

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Autor principal: Marzocca, Angel José
Otros Autores: Goyanes, Silvia Nair, Garraza, A.L.R
Formato: Capítulo de libro
Lenguaje:Español
Publicado: 2010
Acceso en línea:Registro en Scopus
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100 1 |a Marzocca, Angel José 
245 1 0 |a Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system 
246 3 1 |a Influencia de la estructura de reticulación en el coeficiente de interaccion de Flory en el sistema polibutadieno/tolueno 
260 |c 2010 
270 1 0 |m Marzocca, A. J.; Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Física, LPMPyMC, Pabellón 1, Buenos Aires (C1428EGA), Argentina; email: marzo@df.uba.ar 
504 |a Marzocca, A.J., (2007) European Polym. J., 43, pp. 2682-2689 
504 |a Flory, P.J., Rehner, J., (1943) J. Chem. Phys., 11, pp. 512-520 
504 |a Hergenrother, W.T., (1972) J. Appl. Polym. Sci., 16, pp. 2611-2622 
504 |a Scott, R.L., Magat, M., (1949) J. Polym. Sci., 4, pp. 555-571 
504 |a Short, J., Thornton, V., Kraus, G., (1957) Rubber Chem. Technol., 30, pp. 1118-1141 
504 |a Kraus, G., (1963) J. Appl. Polym. Sci., 7, pp. 1257-1263 
504 |a Gavrilov, V.M., Shvarts, A.G., (1974) Rubber Chem. Technol., 47, pp. 303-306 
504 |a Heinrich, G., Straube, E., Helmis, G., (1988) Adv. Polym. Sci., 85, pp. 33-87 
504 |a Heinrich, G., Vilgis, T.A., (1993) Macromolecules, 26, pp. 1109-1119 
504 |a Marzocca, A.J., Goyanes, S., (2004) J. Appl. Polym. Sci., 91, pp. 2601-2609 
504 |a Marzocca, A.J., (1995) J. Appl. Polym. Sci., 58, pp. 1839-1845 
504 |a Marzocca, A.J., Cerveny, S., Raimondo, R.B., (1997) J. Appl. Polym. Sci., 66, pp. 1085-1092 
504 |a Cerveny, S., Marzocca, A.J., (1999) J. Appl. Polym. Sci., 74, pp. 2747-2755 
504 |a (1997) CRC Handbook of Chemistry and Physics, pp. 3-55. , Lide DR, editor, 78th ed., New York, CRC Press 
504 |a Gronski, W., Hoffmann, V., Simon, G., Wutzler, A., Straube, E., (1991) Rubber Chem. Technol., 65, pp. 63-77 
504 |a Clough, R.S., Koenig, J.L., (1989) Rubber Chem. Technol., 62, pp. 908-927 
504 |a Posh, B.T., Adachi, K., Kotaka, T., (1987) Macromolecules, 20, pp. 2574-2579 
506 |2 openaire  |e Política editorial 
520 3 |a Samples of cured medium cis polybutadiene compound, formulated with sulphur and accelerator and vulcanized at 433 K, were prepared at different cure times in order to obtain different network structures. Uniaxial stress strain tests were performed at room temperature and analyzed in the frame of the tube model and the molecular weight between crosslinks was obtained. Swelling tests in toluene at room temperature were made in the same samples and the volume fraction of rubber was calculated in each case. By means of the Flory-Rehner relationship and using the molecular weight between crosslinks, the Flory's parameter χ was estimated for the polybutadiene/toluene system. © 2010 Universidad Simón Bolívar (Venezuela).  |l eng 
593 |a Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Física, LPMPyMC, Pabellón 1, Buenos Aires (C1428EGA), Argentina 
593 |a Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Argentina 
690 1 0 |a POLYBUTADIENE RUBBER 
690 1 0 |a SWELLING 
690 1 0 |a TOLUENE 
690 1 0 |a VULCANIZATION 
700 1 |a Goyanes, Silvia Nair 
700 1 |a Garraza, A.L.R. 
773 0 |d 2010  |g v. 30  |h pp. 67-72  |k n. 1  |p Rev. Latinoam. Met. Materiales  |x 02556952  |w (AR-BaUEN)CENRE-8720  |t Revista Latinoamericana de Metalurgia y Materiales 
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