Detection and discrimination of phenol and primary alcohols in water using electronic noses
Electronic nose methodology was used for discriminating between samples of n-primary alcohols and phenol in water. An electronic nose device developed at our laboratory was applied to detect the vapors from the samples. The device consists of 10 nonspecific gas sensors based on tin-dioxide, whose el...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
2006
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 09979caa a22011897a 4500 | ||
|---|---|---|---|
| 001 | PAPER-6967 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203641.0 | ||
| 008 | 190411s2006 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-33749417294 | |
| 024 | 7 | |2 cas |a alcohol, 64-17-5; butanol, 35296-72-1, 71-36-3; decanol, 112-30-1, 36729-58-5; octanol, 111-87-5, 29063-28-3; oxide, 16833-27-5; phenol, 108-95-2, 3229-70-7; tin, 14314-35-3, 7440-31-5; water, 7732-18-5; Alcohols; Phenol, 108-95-2; Water Pollutants, Chemical | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a ESTHA | ||
| 100 | 1 | |a Diz, V. | |
| 245 | 1 | 0 | |a Detection and discrimination of phenol and primary alcohols in water using electronic noses |
| 260 | |c 2006 | ||
| 270 | 1 | 0 | |m Negri, R.M.; Instituto de Química Física de Materiales, Ambiente y Energía (INQUIMAE), Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Buenos Aires, Argentina; email: rmn@qi.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
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| 504 | |a Jiang, H., Fang, Y., Fu, Y., Guo, Q.-X., Studies on the extraction of phenol in wastewater (2003) J. Hazard. Mater., B, 101, pp. 179-190 | ||
| 504 | |a Poulopoulos, S.G., Voutsas, E.C., Grigoropoulou, H.P., Philippopoulos, C.J., Stripping as a preatreatment process of industrial oily wastewater (2005) J. Hazard. Mater., B, 117, pp. 135-139 | ||
| 504 | |a Gardner, J.W., Bartlett, P., (1999) Electronic Noses: Principles and Applications, , Oxford University Press: Oxford | ||
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| 504 | |a Stuetz, R.M., Fenner, R.A., Engin, G., Characterisation of waste-water using an electronic nose (1999) Water Res., 33, pp. 442-452 | ||
| 504 | |a Dewettinck, T., Van Hege, K., Verstraete, W., The electronic nose as a rapid sensor for volatile compounds in treated domestic wastewater (2001) Water Res., 35, pp. 2475-2483 | ||
| 504 | |a Patel, S.V., Mlsna, T.E., Fruhberger, B., Klaassen, E., Cemalovic, S., Baselt, D.R., Chemicapacitive microsensors for volatile organic compound detection (2003) Sens. Actuators, B, 96, pp. 541-553 | ||
| 504 | |a Wanekaya, A.K., Uematsu, M., Breimer, M., Sadik, O.A., Multicomponent analysis of alcohol vapors using integrated gas chromatography with sensor arrays (2005) Sens. Actuators, B, 110, pp. 41-48 | ||
| 504 | |a McCorkle, D.L., Warmack, R.J., Patel, S.V., Mlsna, T., Hunter, S.R., Ferrell, T.L., Ethanol vapor detection in aqueous environments using micro-capacitors and dielectric polymers (2005) Sens. Actuators, B, 107, pp. 892-903 | ||
| 504 | |a Teja, A.S., Gupta, A.K., Bullock, K.R., Chai, X.-S., Zhu, J.Y., Henry's constants of methanol in aqueous systems containing salts (2001) Fluid Phase Equilib., 185, pp. 265-274 | ||
| 504 | |a O'Connell, M., Valdora, G., Peltzer, G., Negri, R.M., A practical approach for fish freshness determinations using a portable electronic nose (2001) Sens. Actuators B, 80, pp. 149-154 | ||
| 504 | |a Branca, A., Simonian, P., Ferrante, M., Novas, E., Negri, R.M., Electronic nose based discrimination of a perfumery compound in a fragrance (2003) Sens. Actuators, B, 92, pp. 222-227 | ||
| 504 | |a Monge, M.E., Bullone, D., Giacomazza, D., Bernik, D.L., Negri, R.M., Detection of flavour release from pectin gels using e-noses (2004) Sens. Actuators, B, 101, pp. 28-38 | ||
| 504 | |a Lovino, M., Cardinal, M.F., Zubiri, D.B.V., Bernik, D.L., Electronic nose screening of ethanol release during sol-gel encapsulation. A novel noninvasive method to test silica polymerisation (2005) Biosens. Bioelectron., 21, pp. 857-862 | ||
| 504 | |a Langenheim, M., Lovino, M., Monge, M.E., Mizrahi, D., Negri, R.M., Trends towards an electronic nose-electronic tongue fusion applied to discrimination of wines (2005) 6 Czech-Argentine Biennale, "Interdisciplinary Aspects of Human-Machine Co-existence and Co-operation", , Prague, July 2-5 | ||
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| 520 | 3 | |a Electronic nose methodology was used for discriminating between samples of n-primary alcohols and phenol in water. An electronic nose device developed at our laboratory was applied to detect the vapors from the samples. The device consists of 10 nonspecific gas sensors based on tin-dioxide, whose electrical conductivity change when exposed to the vapors. The whole set of responses constitutes a fingerprint associated with the sample for the particular array of sensors. Using this method, we could differentiate among n-primary alcohols, pure phenol, and aqueous dilutions of phenol. Dilutions of primary alcohols and phenol of 1, 3, 5, and 10% (v/v) were assayed. The fingerprints of the dilutions are similar to that of the respective pure (not diluted) alcohol, but with lower signal intensities. Principal component analysis and cluster analysis were performed in order to explore the feasibility of discriminating among the samples. Dilutions of phenol were successfully discriminated from those of primary alcohols. Discrimination of n-octanol and n-decanol from the other alcohols, including phenol, was also achieved. The results suggest that it is possible to discriminate among dilutions of phenol in water and to give an approximate gross estimation of phenol concentration in water. © 2006 American Chemical Society. |l eng | |
| 593 | |a Instituto de Química Física de Materiales, Ambiente y Energía (INQUIMAE), Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Buenos Aires, Argentina | ||
| 593 | |a PINMATE-Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a AQUEOUS DILUTIONS |
| 690 | 1 | 0 | |a CLUSTER ANALYSIS |
| 690 | 1 | 0 | |a FINGERPRINTS |
| 690 | 1 | 0 | |a ALCOHOLS |
| 690 | 1 | 0 | |a CONCENTRATION (PROCESS) |
| 690 | 1 | 0 | |a PHENOLS |
| 690 | 1 | 0 | |a PRINCIPAL COMPONENT ANALYSIS |
| 690 | 1 | 0 | |a WATER POLLUTION |
| 690 | 1 | 0 | |a WATER ANALYSIS |
| 690 | 1 | 0 | |a ALCOHOL |
| 690 | 1 | 0 | |a BUTANOL |
| 690 | 1 | 0 | |a DECANOL |
| 690 | 1 | 0 | |a OCTANOL |
| 690 | 1 | 0 | |a OXIDE |
| 690 | 1 | 0 | |a PHENOL |
| 690 | 1 | 0 | |a TIN |
| 690 | 1 | 0 | |a WATER |
| 690 | 1 | 0 | |a ALCOHOLS |
| 690 | 1 | 0 | |a CONCENTRATION (PROCESS) |
| 690 | 1 | 0 | |a PHENOLS |
| 690 | 1 | 0 | |a PRINCIPAL COMPONENT ANALYSIS |
| 690 | 1 | 0 | |a WATER ANALYSIS |
| 690 | 1 | 0 | |a WATER POLLUTION |
| 690 | 1 | 0 | |a ALCOHOL |
| 690 | 1 | 0 | |a CLUSTER ANALYSIS |
| 690 | 1 | 0 | |a ELECTRONIC EQUIPMENT |
| 690 | 1 | 0 | |a LABORATORY METHOD |
| 690 | 1 | 0 | |a PHENOL |
| 690 | 1 | 0 | |a PRINCIPAL COMPONENT ANALYSIS |
| 690 | 1 | 0 | |a WATER QUALITY |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a CLUSTER ANALYSIS |
| 690 | 1 | 0 | |a DILUTION |
| 690 | 1 | 0 | |a ELECTRIC CONDUCTIVITY |
| 690 | 1 | 0 | |a ELECTRONIC SENSOR |
| 690 | 1 | 0 | |a PRINCIPAL COMPONENT ANALYSIS |
| 690 | 1 | 0 | |a SIGNAL NOISE RATIO |
| 690 | 1 | 0 | |a VAPOR |
| 690 | 1 | 0 | |a VAPOR PRESSURE |
| 690 | 1 | 0 | |a VOLATILIZATION |
| 690 | 1 | 0 | |a ALCOHOLS |
| 690 | 1 | 0 | |a CLUSTER ANALYSIS |
| 690 | 1 | 0 | |a ELECTRONICS |
| 690 | 1 | 0 | |a PHENOL |
| 690 | 1 | 0 | |a PRINCIPAL COMPONENT ANALYSIS |
| 690 | 1 | 0 | |a WASTE DISPOSAL, FLUID |
| 690 | 1 | 0 | |a WATER POLLUTANTS, CHEMICAL |
| 700 | 1 | |a Cassanello, M. | |
| 700 | 1 | |a Negri, R.M. | |
| 773 | 0 | |d 2006 |g v. 40 |h pp. 6058-6063 |k n. 19 |p Environ. Sci. Technol. |x 0013936X |w (AR-BaUEN)CENRE-14 |t Environmental Science and Technology | |
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| 856 | 4 | 0 | |u https://doi.org/10.1021/es052322e |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_0013936X_v40_n19_p6058_Diz |y Handle |
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| 961 | |a paper_0013936X_v40_n19_p6058_Diz |b paper |c PE | ||
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