Modeling temperature dependence of honey viscosity and of related supersaturated model carbohydrate systems

The viscosities of a unifloral honey and supersaturated sugar solutions were measured between -5 and 70 °C. All systems exhibited Newtonian behavior with reducing viscosity as increasing temperature. Four models (Arrhenius, VTF, WLF and Power Law) were investigated to describe the temperature depend...

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Autor principal: Recondo, M.P
Otros Autores: Elizalde, B.E, Buera, M.P
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2006
Acceso en línea:Registro en Scopus
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030 |a JFOED 
100 1 |a Recondo, M.P. 
245 1 0 |a Modeling temperature dependence of honey viscosity and of related supersaturated model carbohydrate systems 
260 |c 2006 
270 1 0 |m Buera, M.P.; Departamento de Industrias, Facultad Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Ciudad Universitaria, Buenos Aires, Argentina; email: pilar@di.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
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504 |a Bhandari, B., D'Arcy, B., Kelly, C., Rheology and crystallization kinetics of honeys (1999) International Journal Food Properties, 2, pp. 217-226 
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504 |a Mazzobre, M.F., Soto, G., Aguilera, J.M., Buera, P., Crystallization kinetics of lactose in systems co-lyophilized with trehalose. Analysis by differential scanning calorimetry (2001) Food Research International, pp. 1-9 
504 |a Mossel, B., Bhandari, B., D'Arcy, B., Caffin, N., Arrhenius model to predict rheological behavior in some Australian honeys (2000) Lebensmittel-Wissenchaft und-Technologie, 33, pp. 545-552 
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504 |a Rubin, C.E., Wasylyk, J.M., Baust, J.G., Investigation of vitrification by nuclear magnetic resonance and differential magnetic resonance and differential scanning calorimetry in honey and model carbohydrate systems (1990) Journal of Agriculture and Food Chemistry, 38, pp. 1824-1827 
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520 3 |a The viscosities of a unifloral honey and supersaturated sugar solutions were measured between -5 and 70 °C. All systems exhibited Newtonian behavior with reducing viscosity as increasing temperature. Four models (Arrhenius, VTF, WLF and Power Law) were investigated to describe the temperature dependence of viscosity. Among the different ways of using the WLF model, the method of reduced variables was the most suitable way to calculate coefficients. Oppositely, the WLF with "universal coefficients" badly predicted the temperature dependence of viscosity. When the calculated and experimental points were plotted as a function of (T - Tg), WLF (with coefficients calculated by the reduced variables method), VTF and power law models fitted the experimental data in a better trend than the Arrhenius equation. Also, the extrapolation of fitted curves into the glass transition region, showed that the Arrhenius model predicts the lowest viscosity values, while the WLF model (with coefficients calculated by the reduced model method) predicts the highest viscosity values in that region. VTF and Power Law models provided curves with intermediate solutions between Arrhenius and WLF model. © 2005 Elsevier Ltd. All rights reserved.  |l eng 
536 |a Detalles de la financiación: Universidad de Buenos Aires, EX 226, EX 274, Project 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas, PIP 2734 
536 |a Detalles de la financiación: The authors acknowledge financial support from Universidad de Buenos Aires (Project EX 274 and EX 226), CONICET (PIP 2734). 
593 |a Departamento de Industrias, Facultad Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Ciudad Universitaria, Buenos Aires, Argentina 
690 1 0 |a ARRHENIUS 
690 1 0 |a GLASS TRANSITION 
690 1 0 |a HONEY 
690 1 0 |a POWER LAW MODELS 
690 1 0 |a SUGAR SYSTEMS 
690 1 0 |a VISCOSITY 
690 1 0 |a VTF 
690 1 0 |a WLF 
690 1 0 |a GLASS TRANSITION 
690 1 0 |a MATHEMATICAL MODELS 
690 1 0 |a SUGAR (SUCROSE) 
690 1 0 |a THERMAL EFFECTS 
690 1 0 |a VISCOSITY 
690 1 0 |a VISCOUS FLOW 
690 1 0 |a ARRHENIUS 
690 1 0 |a HONEY 
690 1 0 |a POWER LAW MODELS 
690 1 0 |a SUGAR SYSTEMS 
690 1 0 |a VTF 
690 1 0 |a NEWTONIAN FLOW 
700 1 |a Elizalde, B.E. 
700 1 |a Buera, M.P. 
773 0 |d 2006  |g v. 77  |h pp. 126-134  |k n. 1  |p J Food Eng  |x 02608774  |w (AR-BaUEN)CENRE-5580  |t Journal of Food Engineering 
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