Simultaneous incorporation of Mn and Al in the goethite structure
Two series of (Al,Mn)-substituted goethites were synthesized from ferrihydrite made in alkaline media, with different Al/Mn mole ratios ([Al + Mn]/Fe molar ratio up to 0.12). Powder X-ray diffraction and extended X-ray absorption fine structure (EXAFS) techniques were used to assess the structural c...
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2007
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| LEADER | 14572caa a22010457a 4500 | ||
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| 001 | PAPER-6718 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203625.0 | ||
| 008 | 190411s2007 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-33846794213 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Alvarez, M. | |
| 245 | 1 | 0 | |a Simultaneous incorporation of Mn and Al in the goethite structure |
| 260 | |c 2007 | ||
| 270 | 1 | 0 | |m Rueda, E.H.; Departamento de Química, Universidad Nacional del Sur, Av. Alem 1253, B8000CPB Bahía Blanca, Argentina; email: erueda@uns.edu.ar |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a Two series of (Al,Mn)-substituted goethites were synthesized from ferrihydrite made in alkaline media, with different Al/Mn mole ratios ([Al + Mn]/Fe molar ratio up to 0.12). Powder X-ray diffraction and extended X-ray absorption fine structure (EXAFS) techniques were used to assess the structural characteristics of the simultaneous substitution in goethite. XRD patterns revealed that all the obtained solids remain in a goethite-like structure. Rietveld refinement of X-ray diffraction data indicates that the increasing Mn substitution and consequent decrease of Al substitution causes an increase in the unit cell volume. This change is accompanied by the increment of the various Me-Me distances. XANES spectra at the Al and Mn K-edge confirm the octahedral coordination of Al and the trivalent oxidation state of the Mn ion in all the synthesized samples. EXAFS spectra at the Fe K-edge indicate that the local order around the Fe atom remains practically constant upon (Mn,Al) substitution. Measurements in the Mn K-edge show that distances Mn-Me suffer different changes with the increase in Mn substitution: a marked decrease in E and a slight decrease in E′, while DC remains constant. E and E′ values correspond to the distance between one Mn and one neighboring Me (Fe, Mn, Al) atom, both situated in two polyhedra linked by an edge. These polyhedra belong to the same double row of the goethite structure. DC value corresponds to the distance between one Mn and one Me (Fe, Mn, Al) atom, situated in two octahedral linked by one corner and belonging to two adjacent double chains. All the intermetallic distances are minor than the corresponding singly substituted goethites, this fact is attributed to the structure contraction due to the presence of Al(III) which restrains the axial distortion of Mn. Dissolution-time curves, resulting from exposure to 6 M HCl at 318 K, show that the dissolution rate slows with increasing Al substitution and consequent decrease of Mn substitution, and the shape of the curve becomes increasingly sigmoidal for mixed goethite with large Al content and Al-goethite. Dissolution kinetics of most samples are well described by the Kabai equation. Al dissolves almost congruently with respect to Fe, implying that it is homogeneously distributed in the structure. However, the convex χMn:χFe curve indicates that Mn tends to be concentrated in the outer layers of the goethite particles. © 2006 Elsevier Inc. All rights reserved. |l eng | |
| 536 | |a Detalles de la financiación: Universidad Nacional del Sur | ||
| 536 | |a Detalles de la financiación: Laboratório Nacional de Luz Síncrotron, LNLS, SXS 2351/04, UBACYT X800, XAS 2804/04 | ||
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires, SGCyT 24/Q005 | ||
| 536 | |a Detalles de la financiación: This work was partially supported by LNLS (proposals XAS 2804/04 and SXS 2351/04), and by Grants UBACYT X800 from Universidad de Buenos Aires and SGCyT 24/Q005 from Universidad Nacional del Sur. The authors thank the reviewers for their insightful comments. | ||
| 593 | |a Departamento de Química, Universidad Nacional del Sur, Av. Alem 1253, B8000CPB Bahía Blanca, Argentina | ||
| 593 | |a INQUIMAE, Dpto. de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon II, C1428EHA, Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a ALUMINUM |
| 690 | 1 | 0 | |a CRYSTAL STRUCTURE |
| 690 | 1 | 0 | |a GOETHITE |
| 690 | 1 | 0 | |a MANGANESE |
| 690 | 1 | 0 | |a RIETVELD ANALYSIS |
| 690 | 1 | 0 | |a X-RAY DIFFRACTION |
| 700 | 1 | |a Rueda, E.H. | |
| 700 | 1 | |a Sileo, E.E. | |
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