Some aspects of the glyphosate adsorption on montmorillonite and its calcined form

Influences of pH and ionic strength on the aggregation of montmorillonite particles in the presence or absence of glyphosate (PMG) were studied. Adsorption isotherms and X-ray diffraction indicated that ligand exchange is the main mechanism of PMG adsorption. The surface coverage increased with the...

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Autor principal: Damonte, M.
Otros Autores: Torres Sánchez, R.M, dos Santos Afonso, M.
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Lenguaje:Inglés
Publicado: 2007
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100 1 |a Damonte, M. 
245 1 0 |a Some aspects of the glyphosate adsorption on montmorillonite and its calcined form 
260 |c 2007 
270 1 0 |m dos Santos Afonso, M.; Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellon II, C1428EHA Buenos Aires, Argentina; email: dosantos@qi.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
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520 3 |a Influences of pH and ionic strength on the aggregation of montmorillonite particles in the presence or absence of glyphosate (PMG) were studied. Adsorption isotherms and X-ray diffraction indicated that ligand exchange is the main mechanism of PMG adsorption. The surface coverage increased with the ionic strength and was more noticeable at high PMG concentration indicating inner-sphere surface complexation. At low PMG concentration the inner-sphere surface complexes are located of the external clay mineral surface while at high PMG concentration the surface complexes are also formed in the interlayer space. © 2006 Elsevier B.V. All rights reserved.  |l eng 
536 |a Detalles de la financiación: Universidad de Buenos Aires 
536 |a Detalles de la financiación: Secretaría de Ciencia y Técnica, Universidad de Buenos Aires, UBACyT X043, PICT 13-08893 
536 |a Detalles de la financiación: Authors acknowledge Universidad de Buenos Aires, Secretaría de Ciencia y Técnica and ANPCyT-FONCyT for financial support through UBACyT X043 and PICT 13-08893 projects respectively. Dr. Rosa M Torres Sánchez is a member of CONICET. Authors also acknowledge thereviewers for their comments that improve the discussion. 
593 |a Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellon II, C1428EHA Buenos Aires, Argentina 
593 |a CETMIC, Camino Centenario y 506, (b1897ZCA) M.B. Gonnet, Argentina 
690 1 0 |a ADSORPTION 
690 1 0 |a GLYPHOSATE 
690 1 0 |a MONTMORILLONITE 
690 1 0 |a THERMAL REACTION 
690 1 0 |a ADSORPTION 
690 1 0 |a ADSORPTION ISOTHERMS 
690 1 0 |a AGGLOMERATION 
690 1 0 |a COMPLEXATION 
690 1 0 |a IONIC STRENGTH 
690 1 0 |a PARTICLES (PARTICULATE MATTER) 
690 1 0 |a PH EFFECTS 
690 1 0 |a X RAY DIFFRACTION ANALYSIS 
690 1 0 |a CALCINED FORM 
690 1 0 |a GLYPHOSATE 
690 1 0 |a SURFACE COMPLEXATION 
690 1 0 |a THERMAL REACTION 
690 1 0 |a CLAY MINERALS 
690 1 0 |a ADSORPTION 
690 1 0 |a AGGREGATION 
690 1 0 |a CONCENTRATION (COMPOSITION) 
690 1 0 |a GLYPHOSATE 
690 1 0 |a IONIC COMPOSITION 
690 1 0 |a ISOTHERM 
690 1 0 |a LIGAND 
690 1 0 |a MONTMORILLONITE 
690 1 0 |a X-RAY DIFFRACTION 
650 1 7 |2 spines  |a PH 
700 1 |a Torres Sánchez, R.M. 
700 1 |a dos Santos Afonso, M. 
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