Evaluation of the polymer-solvent interaction parameter χ for the system cured styrene butadiene rubber and toluene
One of the most popular cured rubbers used in industrial applications is styrene butadiene rubber (SBR) and frequently its network structure is studied by means of swelling techniques in solvent. Normally, toluene is used as solvent in this test. In order to estimate the crosslink density from the e...
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2007
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 10821caa a22009977a 4500 | ||
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| 001 | PAPER-6586 | ||
| 003 | AR-BaUEN | ||
| 005 | 20250723105543.0 | ||
| 008 | 190411s2007 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-34249895928 | |
| 030 | |a EUPJA | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Marzocca, Angel José | |
| 245 | 1 | 0 | |a Evaluation of the polymer-solvent interaction parameter χ for the system cured styrene butadiene rubber and toluene |
| 260 | |c 2007 | ||
| 270 | 1 | 0 | |m Marzocca, A.J.; Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Física, Pabellón 1, Buenos Aires (1428), Argentina; email: marzo@df.uba.ar |
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| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a One of the most popular cured rubbers used in industrial applications is styrene butadiene rubber (SBR) and frequently its network structure is studied by means of swelling techniques in solvent. Normally, toluene is used as solvent in this test. In order to estimate the crosslink density from the equilibrium volume fraction of rubber in the swollen state, the correct evaluation of the Flory-Huggins interaction parameter χ is necessary. This work covers the swelling behavior of cured SBR in toluene. The rubber was vulcanized with different amounts sulfur and accelerator at 433 K in order to obtain several network structures and crosslink densities. Network characterisations of the compounds were made by swelling measurements in the frame of the Flory-Rehner relationship using the molecular weight of the network chain between chemical crosslinks obtained previously by mechanical tests. A relationship between χ and vr, the polymer volume fraction at equilibrium (maximum) degree of swelling, was established for the cured SBR/toluene system. It was found that χ is not a constant but depends on the crosslink density in the sample. The types of crosslinks in these samples where estimated applying this function to the swelling behavior of the compounds previously treated with the thiol probe method. © 2007 Elsevier Ltd. All rights reserved. |l eng | |
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires | ||
| 536 | |a Detalles de la financiación: X808 | ||
| 536 | |a Detalles de la financiación: The present work was supported in by the University of Buenos Aires (Research Proyect X808). The author wish to thank FATE SAICI (Argentina) for the cooperation in the development of this research. | ||
| 593 | |a Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Física, Pabellón 1, Buenos Aires (1428), Argentina | ||
| 690 | 1 | 0 | |a CROSSLINKING |
| 690 | 1 | 0 | |a FLORY-HUGGINS INTERACTION PARAMETER |
| 690 | 1 | 0 | |a STYRENE BUTADINE RUBBER |
| 690 | 1 | 0 | |a SWELLING |
| 690 | 1 | 0 | |a TOLUENE |
| 690 | 1 | 0 | |a BUTADIENE |
| 690 | 1 | 0 | |a CROSSLINKING |
| 690 | 1 | 0 | |a SOLVENTS |
| 690 | 1 | 0 | |a STYRENE |
| 690 | 1 | 0 | |a SWELLING |
| 690 | 1 | 0 | |a TOLUENE |
| 690 | 1 | 0 | |a VOLUME FRACTION |
| 690 | 1 | 0 | |a VULCANIZATION |
| 690 | 1 | 0 | |a CROSSLINK DENSITY |
| 690 | 1 | 0 | |a FLORY-HUGGINS INTERACTION PARAMETERS |
| 690 | 1 | 0 | |a STYRENE BUTADIENE RUBBER |
| 690 | 1 | 0 | |a RUBBER |
| 773 | 0 | |d 2007 |g v. 43 |h pp. 2682-2689 |k n. 6 |p Eur Polym J |x 00143057 |w (AR-BaUEN)CENRE-4697 |t European Polymer Journal | |
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| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00143057_v43_n6_p2682_Marzocca |y Handle |
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