The photophysics of nitrocarbazoles used as UV-MALDI matrices: Comparative spectroscopic and optoacoustic studies of mononitro- and dinitrocarbazoles

The photophysical behaviour of 1-nitrocarbazole, 3-nitrocarbazole, 1,6-dinitrocarbazole and 3,6-dinitrocarbazole in acetonitrile was studied by using spectroscopic, luminescence and photoacoustic techniques. Absorption spectra and triplet state transient spectra were recorded and the φ{symbol}T and...

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Detalles Bibliográficos
Autor principal: Bonesi, S.M
Otros Autores: Mesaros, M., Cabrerizo, F.M, Ponce, M.A, Bilmes, Gabriel Mario, Erra-Balsells, R.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2007
Acceso en línea:Registro en Scopus
DOI
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
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100 1 |a Bonesi, S.M. 
245 1 4 |a The photophysics of nitrocarbazoles used as UV-MALDI matrices: Comparative spectroscopic and optoacoustic studies of mononitro- and dinitrocarbazoles 
260 |c 2007 
270 1 0 |m Erra-Balsells, R.; CIHIDECAR-CONICET. Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, UBA. Pabellón II, 3er Piso, Ciudad Universitaria, 1428 Buenos Aires, Argentina; email: erra@qo.fcen.uba.ar 
504 |a Mesaros, M., Tarzi, O.I., Erra-Balsells, R., Bilmes, G.M., (2006) Chem. Phys. Lett., 426, p. 334 
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504 |a Biondic, M.C., Erra-Balsells, R., (1997) J. Chem. Soc., Perkin Trans., 2, p. 1323 
504 |a Biondic, M.C., Erra-Balsells, R., (1998) J. Chem. Res., (SUPPL), p. 114 
504 |a Tarzi, O.I., Erra-Balsells, R., (2005) J. Photochem. Photobiol. B: Biol., 80, p. 29 
504 |a Tarzi, O.I., Erra-Balsells, R., (2006) J. Photochem. Photobiol. B: Biol., 82, p. 79 
504 |a Erra-Balsells, R., Frasca, A.R., (1984) Tetrahedron Lett., 25, p. 5363 
504 |a Bonesi, S.M., Erra-Balsells, R., (1991) J. Photochem. Photobiol., A: Chem., 56, p. 55 
504 |a Bonesi, S.M., Erra-Balsells, R., (2000) J. Chem. Soc., Perkin Trans., 2, p. 1583 
504 |a Ponce, M.B., Cabrerizo, F.M., Bonesi, S.M., Erra-Balsells, R., (2006) Helv. Chim. Acta, 89, p. 1123 
504 |a Nonami, H., Fukui, S., Erra-Balsells, R., (1997) J. Mass Spectrom., 32, p. 287 
504 |a Nonami, H., Tanaka, K., Fukuyama, Y., Erra-Balsells, R., (1998) Rapid Commun. Mass Spectrom., 12, p. 285 
504 |a Bonesi, S.M., Erra-Balsells, R., (2001) J. Luminesc., 93, p. 51 
504 |a Bonesi, S.M., Erra-Balsells, R., (2002) J. Luminesc., 97, p. 83 
504 |a Turro, N.J., (1978) Modern Molecular Photochemistry, , The Benjamin Cummings Publishing Company, Inc., California 
504 |a Birks, J.B., (1970) Photophysics of Aromatic Molecules, , Wiley Interscience, New York 
504 |a Ponce, M.A., Erra-Balsells, R., (2001) J. Heterocycl. Chem., 38, p. 1071 
504 |a Mesaros, M., Bonesi, S.M., Ponce, M.A., Erra-Balsells, R., Bilmes, G.M., (2003) Photochem. Photobiol. Sci., 2, p. 808 
504 |a Van Haver, Ph., Viaene, L., Van der Auweraes, M., De Schyver, F.C., (1990) J. Photochem. Photobiol., A: Chem., 63, p. 265 
504 |a Small, J.R., Libertini, L.J., Small, E.W., (1992) Biophys. Chem., 41, p. 29 
504 |a Mataga, N., Toriashi, Y., Ezumi, K., (1964) Theor. Chim. Acta, 2, p. 158 
504 |a Huber, J.R., Adams, J.E., (1974) Ber. Bunsenges. Phys. Chem., 78, p. 217 
504 |a Chakravorty, S.C., Ganguly, S.C., (1970) J. Chem. Phys., 52, p. 2760 
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504 |a Terazima, M., Azumi, T., (1990) Bull. Chem. Soc. Jpn., 63, p. 741 
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506 |2 openaire  |e Política editorial 
520 3 |a The photophysical behaviour of 1-nitrocarbazole, 3-nitrocarbazole, 1,6-dinitrocarbazole and 3,6-dinitrocarbazole in acetonitrile was studied by using spectroscopic, luminescence and photoacoustic techniques. Absorption spectra and triplet state transient spectra were recorded and the φ{symbol}T and τT values were determined. Phosphorescence emission at 77 K and the dynamic properties in terms of φ{symbol}p, kp o and knr for the mono and dinitrocarbazoles were derived. Results are discussed in terms of the optimised structure of 1-nitrocarbazole, 3-nitrocarbazole, 1,6-dinitrocarbazole and 3,6-dinitrocarbazole and are compared with that of carbazole. The nitro group attached to the carbazole moiety induces important changes in the photophysical behaviour of these compounds. © 2007 Elsevier B.V. All rights reserved.  |l eng 
536 |a Detalles de la financiación: Umweltbundesamt, X022 
536 |a Detalles de la financiación: Universidad Nacional de La Plata, UNLP, I111 
536 |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, PICT 6-12312 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas, PIP1060, PIP 5443 
536 |a Detalles de la financiación: The authors are indebted with Dr. S. Braslavsky (Max-Planck Institut für Bioanorganischechemie (formarly Strahlenchemie), Mülheim an der Ruhr, Germany) and Dr. F. Quina (Federal University of San Pablo, Brasil) for the use of the Edinburgh OB900 fluorometer, the Hitachi F-500 spectrofluorometer, the Cary Eclipse (Varian) spectrofluorometer and their generous hospitality. This project was partially financial supported by UBA (X022), CONICET (PIP 5443 and PIP1060); CIC-BA, UNLP (I111) and ANPCyT (PICT 6-12312). RE-B, FMC and SMB are research members of CONICET. GMB is research member of CIC and UNLP. 
593 |a CIHIDECAR-CONICET. Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, UBA. Pabellón II, 3er Piso, Ciudad Universitaria, 1428 Buenos Aires, Argentina 
593 |a Centro de Investigaciones Opticas (CIOp), Universidad Nacional de La Plata, Casilla de Correo 124, 1900 La Plata, Argentina 
690 1 0 |a ABSORPTION SPECTRA 
690 1 0 |a ACETONITRILE 
690 1 0 |a FUNCTIONAL GROUPS 
690 1 0 |a PHOSPHORESCENCE 
690 1 0 |a PHOTOACOUSTIC EFFECT 
690 1 0 |a NITRO GROUPS 
690 1 0 |a PHOSPHORESCENCE EMISSION 
690 1 0 |a PHOTOPHYSICS 
690 1 0 |a TRIPLET STATE TRANSIENT SPECTRA 
690 1 0 |a CRYSTALLINE MATERIALS 
700 1 |a Mesaros, M. 
700 1 |a Cabrerizo, F.M. 
700 1 |a Ponce, M.A. 
700 1 |a Bilmes, Gabriel Mario 
700 1 |a Erra-Balsells, R. 
773 0 |d 2007  |g v. 446  |h pp. 49-55  |k n. 1-3  |p Chem. Phys. Lett.  |x 00092614  |w (AR-BaUEN)CENRE-69  |t Chemical Physics Letters 
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