Glyphosate behavior at soil and mineral-water interfaces
Adsorption isotherms and surface coverage of glyphosate, N-phosphonomethylglycine (PMG), in aqueous suspensions of three Argentine soils with different mineralogical composition were measured as a function of PMG concentration and pH. Zeta potential curves for PMG/soils system were also determined....
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2008
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| LEADER | 14126caa a22015257a 4500 | ||
|---|---|---|---|
| 001 | PAPER-5935 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203537.0 | ||
| 008 | 190411s2008 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-41949137459 | |
| 024 | 7 | |2 cas |a glyphosate, 1071-83-6; iron, 14093-02-8, 53858-86-9, 7439-89-6; montmorillonite, 1318-93-0, 61029-13-8; Bentonite, 1302-78-9; Glycine, 56-40-6; Herbicides; Humic Substances; Iron, 7439-89-6; Soil Pollutants; Water Pollutants; glyphosate, 1071-83-6 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a ENPOE | ||
| 100 | 1 | |a Pessagno, R.C. | |
| 245 | 1 | 0 | |a Glyphosate behavior at soil and mineral-water interfaces |
| 260 | |c 2008 | ||
| 270 | 1 | 0 | |m dos Santos Afonso, M.; INQUIMAE, Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria Pabellon II, C1428EHA Buenos Aires, Argentina; email: dosantos@qi.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a Adsorption isotherms and surface coverage of glyphosate, N-phosphonomethylglycine (PMG), in aqueous suspensions of three Argentine soils with different mineralogical composition were measured as a function of PMG concentration and pH. Zeta potential curves for PMG/soils system were also determined. Montmorillonite and soil sample surface charges were negative and increased as the amount of adsorbed PMG increased, showing that the surface complexes are more negative than those formed during the surface protonation. PMG adsorption on soils were described using Langmuir isotherms and the affinity constants, and the maximum surface coverage was estimated at pH 4 and 7 using a two-term Langmuir isotherm, the mineralogical composition percentages, and maximum surface coverage and Langmuir constants for pure minerals. The influence of organic matter (OM) and iron content of soils on the PMG adsorption was evaluated. The surface coverage of PMG decreased when the OM and iron content decreased for minerals and soils. © 2007 Elsevier Ltd. All rights reserved. |l eng | |
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires | ||
| 536 | |a Detalles de la financiación: Secretaría de Ciencia y Técnica, Universidad de Buenos Aires, UBACyT X043, PICT 13-08893 | ||
| 536 | |a Detalles de la financiación: The authors thank Lic S. Conconi for determining the quantitative mineralogical composition of soils. The authors also acknowledge the Universidad de Buenos Aires, Secretaría de Ciencia y Técnica and ANPCyT-FONCyT for financial support through UBACyT X043 and PICT 13-08893 projects respectively. | ||
| 593 | |a INQUIMAE, Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria Pabellon II, C1428EHA Buenos Aires, Argentina | ||
| 593 | |a CETMIC, CC 49, B1896ZCA M.B. Gonnet, Buenos Aires Province, Argentina | ||
| 690 | 1 | 0 | |a ADSORPTION |
| 690 | 1 | 0 | |a CLAYS |
| 690 | 1 | 0 | |a GLYPHOSATE |
| 690 | 1 | 0 | |a SOILS |
| 690 | 1 | 0 | |a SURFACE COMPLEXES |
| 690 | 1 | 0 | |a GLYPHOSATE BEHAVIOR |
| 690 | 1 | 0 | |a SURFACE COMPLEXES |
| 690 | 1 | 0 | |a BIOLOGICAL MATERIALS |
| 690 | 1 | 0 | |a ISOTHERMS |
| 690 | 1 | 0 | |a MINERALS |
| 690 | 1 | 0 | |a PH EFFECTS |
| 690 | 1 | 0 | |a WATER |
| 690 | 1 | 0 | |a SOILS |
| 690 | 1 | 0 | |a GLYPHOSATE |
| 690 | 1 | 0 | |a IRON |
| 690 | 1 | 0 | |a MINERAL |
| 690 | 1 | 0 | |a MONTMORILLONITE |
| 690 | 1 | 0 | |a N PHOSPHONOMETHYLGLYCINE |
| 690 | 1 | 0 | |a ORGANIC MATTER |
| 690 | 1 | 0 | |a UNCLASSIFIED DRUG |
| 690 | 1 | 0 | |a ADSORPTION |
| 690 | 1 | 0 | |a CHEMICAL COMPOSITION |
| 690 | 1 | 0 | |a CLAY |
| 690 | 1 | 0 | |a GLYPHOSATE |
| 690 | 1 | 0 | |a IRON |
| 690 | 1 | 0 | |a ISOTHERM |
| 690 | 1 | 0 | |a MONTMORILLONITE |
| 690 | 1 | 0 | |a ORGANIC MATTER |
| 690 | 1 | 0 | |a SOIL |
| 690 | 1 | 0 | |a ADSORPTION |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a ISOTHERM |
| 690 | 1 | 0 | |a LANGMUIR ISOTHERM |
| 690 | 1 | 0 | |a PROTON TRANSPORT |
| 690 | 1 | 0 | |a SOIL |
| 690 | 1 | 0 | |a ZETA POTENTIAL |
| 690 | 1 | 0 | |a ADSORPTION |
| 690 | 1 | 0 | |a BENTONITE |
| 690 | 1 | 0 | |a ENVIRONMENTAL MONITORING |
| 690 | 1 | 0 | |a GLYCINE |
| 690 | 1 | 0 | |a HERBICIDES |
| 690 | 1 | 0 | |a HUMIC SUBSTANCES |
| 690 | 1 | 0 | |a HYDROGEN-ION CONCENTRATION |
| 690 | 1 | 0 | |a IRON |
| 690 | 1 | 0 | |a SOIL POLLUTANTS |
| 690 | 1 | 0 | |a WATER POLLUTANTS |
| 650 | 1 | 7 | |2 spines |a PH |
| 651 | 4 | |a ARGENTINA | |
| 651 | 4 | |a ARGENTINA | |
| 651 | 4 | |a SOUTH AMERICA | |
| 700 | 1 | |a Torres Sánchez, R.M. | |
| 700 | 1 | |a dos Santos Afonso, M. | |
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